富氧条件下氢气选择催化还原氮氧化物研究的进展

催化学报 , 2010, 31(8): 912-918. doi: 10.3724/SP.J.1088.2010.00461

富氧条件下氢气选择催化还原氮氧化物研究的进展

武鹏 ^1, , 于青 ^2, , 严晶晶 ^3, , 武光军 ^4, , 李兰冬 ^5, , 关乃佳 ^6,

1.中国神华煤制油化工有限公司北京研究院,北京,100011

2.南开大学化学学院新催化材料科学研究所,天津,300071

3.南开大学化学学院新催化材料科学研究所,天津,300071

4.南开大学化学学院新催化材料科学研究所,天津,300071

5.南开大学化学学院新催化材料科学研究所,天津,300071

6.南开大学化学学院新催化材料科学研究所,天津,300071

基金项目: 科技部国际科技合作项目(2007DFA90720) 国家自然科学基金(20973094;20703057)

关键词：氢气 , 选择催化还原 , 氮氧化物 , 反应机理

Progress in Selective Catalytic Reduction of NOx by Hydrogen in Excess Oxygen

富氧条件下,氢气选择催化还原(H2-SCR)是消除氮氧化物的有效方法.本文介绍了H2-SCR反应特点及其研究现状,重点总结和评述了应用于H2-SCR反应的氧化物和分子筛负载的Pt或Pd催化剂,以及H2-SCR反应机理,并展望了今后H2-SCR研究的方向.

参考文献

[1]	吴忠标.大气污染控制技术[M].北京:化学工业出版社,2002:244.
[2]	滕加伟;宋庆英;于岚;卢文奎陈庆龄 .[J].环境污染治理技术与设备,2000,1:38.
[3]	Speronello B;Chen J;Heck R M.[A].,1992:21.
[4]	Heck R M .[J].Catalysis Today,1999,53:519.
[5]	Zhu Z P;Liu Z Y;Liu S J;Niu H X Hu T D Liu T Xie YN .[J].Applied Catalysis B:Environmental,2000,26:25.
[6]	Choo ST.;Yim SD.;Nam IS.;Ham SW.;Lee JB. .Effect of promoters includingWO(3) and BaO on the activity and durability of V2O5/sulfated TiO2 catalyst for NO reduction by NH3[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(3):237-252.
[7]	Parvulescu VI.;Boghosian S.;Parvulescu V.;Jung SM.;Grange P. .Selective catalytic reduction of NO with NH3 over mesoporous V2O5-TiO2-SiO2 catalysts[J].Journal of Catalysis,2003(1):172-185.
[8]	Qi G S;Yang R T;Chang R .[J].Applied Catalysis B:Environmental,2004,51:93.
[9]	Smirniotis P G;Pena D A;Uphade B S .[J].Angewandte Chemie International Edition,2001,40:2479.
[10]	Long R Q;Yang R T .[J].Journal of the American Chemical Society,1999,121:5595.
[11]	Richter M;Trunschke A;Bentrup U;Brzezinka K W Schreier E Schneider M Pohl M M Fricke R .[J].Journal of Catalysis,2002,206:98.
[12]	Shibata J;Takada Y;Shichi A;Satokawa S Satsuma A Hattori T .[J].Journal of Catalysis,2004,222:368.
[13]	Iwasaki M;Yamazaki K;Banno K;Shinjoh H .Characterization of Fe/ZSM-5 DeNO(x) catalysts prepared by different methods: Relationships between active Fe sites and NH3-SCR performance[J].Journal of Catalysis,2008(2):205-216.
[14]	Iwamoto M;Yahiro H;Yu-u Y;Shundo S Mizuno N .[J].Shokubai(Catalysts & Catalysis),1990,32:430.
[15]	Held W;Koening A;Richter T;Puppe L .[R].,1990.
[16]	Armor J N .[J].Applied Catalysis B:Environmental,1992,1:221.
[17]	Burch R.;Breen JP.;Meunier FC. .A review of the selective reduction of NOx, with hydrocarbons under lean-burn conditions with non-zeolitic oxide and platinum group metal catalysts [Review][J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2002(4):283-303.
[18]	Shen S C;Kawi S .[J].Applied Catalysis B:Environmental,2003,45:63.
[19]	Jeon JY.;Kim HY.;Woo SI. .Selective catalytic reduction of NOx in lean-burn engine exhaust over a Pt/V/MCM-41 catalyst[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2003(4):311-323.
[20]	Shimizu K;Satsuma A;Hatorri T .[J].Applied Catalysis B:Environmental,2000,25:239.
[21]	Marnellos G E;Efthimiadis E A;Vasalos I A .[J].Applied Catalysis B:Environmental,2004,48:1.
[22]	Liu Z M;Hao J M;Fu L X;Zhu T L Li J H Cui X Y .[J].Applied Catalysis B:Environmental,2004,48:37.
[23]	Chen H Y;Sachtler W M H .[J].Catalysis Today,1998,42:73.
[24]	Traa Y;Burger B;Weitkamp J .[J].Microporous and Mesoporous Materials,1999,30:3.
[25]	Heinrich F;Schmidt C;L(o)ffler E;Menzel M Grünert W .[J].Journal of Catalysis,2002,212:157.
[26]	Li LD;Chen JX;Zhang SJ;Guan NJ;Richter M;Eckelt R;Fricke R .Study on metal-MFI/cordierite as promising catalysts for selective catalytic reduction of nitric oxide by propane in excess oxygen[J].Journal of Catalysis,2004(1):12-22.
[27]	Li L D;Zhang F X;Guan N J;Richter M Fricke R .[J].Catalysis Communications,2007,8:583.
[28]	Li L D;Guan N J .[J].Microporous and Mesoporous Materials,2009,117:450.
[29]	Shelef M;Jones J H;Kummer J T;Otto K Weaver E E .[J].Environmental Science and Technology,1971,5:790.
[30]	Ueda A;Nakao T;Azuma M;Kobayashi T .[J].Catalysis Today,1998,45:135.
[31]	Burch R;Coleman M D .[J].Applied Catalysis B:Environmental,1999,23:115.
[32]	Machida M;Ikeda S;Kurogi D;Kijima T .[J].Applied Catalysis B:Environmental,2001,35:107.
[33]	Shibata J;Hashimoto M;Shimizu K;Yoshida H Hattori T Satsuma A .[J].Journal of Physical Chemistry B,2004,108:18327.
[34]	Macleod N;Lambert R M .[J].Applied Catalysis B:Environmental,2002,35:269.
[35]	Yokota K;Fukui M;Tanaka T .[J].Applied Surface Science,1997,121:273.
[36]	Burch R;Coleman M D .[J].Journal of Catalysis,2002,208:435.
[37]	Li L D;Zhang F X;Guan N J;Schreier E Richter M .[J].Catalysis Communications,2008,9:1827.
[38]	Schott F J P;Balle P;Adler J;Kureti S .[J].Applied Catalysis B:Environmental,2009,87:18.
[39]	Nanba T;Kohno C;Masukawa S;Uchisawa J Nakayama N Obuchi A .[J].Applied Catalysis B:Environmental,2003,46:353.
[40]	Nanba T;Sugawara K;Masukawa S;Uchisawa J,Obuchi A .[J].Industrial and Engineering Chemistry Research,2005,44:3426.
[41]	Costa N C;Efstathiou A M .[J].Applied Catalysis B:Environmental,2007,72:240.
[42]	Costa C N;Stathopoulos V N;Belessi V C;Efstathiou A M .[J].Journal of Catalysis,2001,197:350.
[43]	Costa C N;Savva P G;Andronikou C;Lambrou P S Polychronopoulou K Belessi V C Stathopoulos V N Pomonis P J Efstathiou A M .[J].Journal of Catalysis,2002,209:456.
[44]	Machida M;Watanabe T;Ikeda S;KijimaT .[J].Catalysis Communications,2002,3:233.
[45]	Machida M;Watanabe T .[J].Applied Catalysis B:Environmental,2004,52:281.
[46]	Wu P;Liu Y X;Zhang F X;Li L D Yang Y L Guan N J .[J].Acta Physico-Chimica Sinica,2008,24:369.
[47]	Wu P;Li L D;Yu Q;Wu G J Guan N J.[J].Catalysis Today,2010
[48]	Li L D;Wu P;Yu Q;Wu G J Guan N J .[J].Applied Catalysis B:Environmental,2010,94:254.
[49]	Satsuma A;Hashimoto M;Shibata J;Yoshida H,Hattori T.[J].Chemical Communications,2003:1698.
[50]	Burch R;Shestov A A;Sullivan J A .[J].Journal of Catalysis,1999,188:69.
[51]	Costa C N;Efstathiou A M .[J].Journal of Physical Chemistry B,2004,108:2620.
[52]	Marina OA.;Vayenas CG.;Palermo A.;Lambert RM.;Yentekakis IV. .IN SITU CONTROLLED PROMOTION OF CATALYST SURFACES VIA NEMCA - THE EFFECT OF NA ON THE PT-CATALYZED NO REDUCTION BY H-2[J].Journal of Catalysis,1997(2):218-228.
[53]	Frank B;Emig G;Renken A .[J].Applied Catalysis B:Environmental,1998,19:45.
[54]	Ge Q F;Kose R;King D A .[J].Advances in Catalysis,2000,45:207.

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材料期刊网

富氧条件下氢气选择催化还原氮氧化物研究的进展

Progress in Selective Catalytic Reduction of NOx by Hydrogen in Excess Oxygen

参考文献