甲醇氧化电催化剂是决定直接甲醇燃料电池性能、寿命和成本的关键材料之一.近年来人们从提高阳极催化剂活性和降低催化剂成本两个方面出发进行了大量的研究,有力推动了直接甲醇燃料电池的发展.在简要介绍电催化剂上甲醇氧化反应机理的基础上,综述了近年来直接甲醇燃料电池阳极催化剂的研究进展,从铂基催化剂、非铂基催化剂和催化剂载体三个方面进行了详细的介绍(附有58篇参考文献).并展望了甲醇电催化剂的发展趋势.
The electrocatalyst for methanol oxidation is one of the heart components in direct methanol fuel cells. Much work has been de-voted to the improvement of the catalytic activity and the decrease of the electrocatalyst cost. The recent development of electrocatalysts focusing on Pt-based catalysts, non-Pt catalysts, and catalyst supports was summarized with 58 references. The directions in this field were also suggested for future research.
参考文献
| [1] | 衣宝廉.燃料电池-高效、环境友好的发电方式[M].北京:化学工业出版社,2000 |
| [2] | Baldauf M;Preidel W .[J].Journal of Power Sources,1999,84:161. |
| [3] | Watanabe M;Uchida M;Motoo S .[J].Journal of Electroanalytical Chemistry,1987,229:395. |
| [4] | Hsieh C T;Lin J Y .[J].Journal of Power Sources,2009,188:347. |
| [5] | Xu C W;Su Y Z;Tan L L;Liu Z L Zhang J H Chen S Ji ang S P .[J].Electrochimica Acta,2009,54:6322. |
| [6] | Liang Z X;Zhao T S .[J].Journal of Physical Chemistry C,2007,111:8128. |
| [7] | 孙世国,徐恒泳,唐水花,郭军松,李焕巧,曹雷,周冰,辛勤,孙公权.PtRu纳米线的合成及其在直接甲醇燃料电池阳极中的催化活性[J].催化学报,2006(10):932-936. |
| [8] | Guo S J;Fang Y X;Dong S J;Wang E K .[J].Journal of Phéys Chem C,2007,111:17104. |
| [9] | Zeng J H;Yang J;Lee J Y;Zhou W J .[J].Journal of Physical Chemistry B,2006,111:24606. |
| [10] | Wu Y N;Liao S J;Liang Z X;Yang L J Wang R F .[J].Journal of Power Sources,2009,194:805. |
| [11] | Wang H;Xu CW;Cheng FL;Zhang M;Wang SY;Jiang SP .Pd/Pt core-shell nanowire arrays as highly effective electrocatalysts for methanol electrooxidation in direct methanol fuel cells[J].Electrochemistry communications,2008(10):1575-1578. |
| [12] | Hyun M S;Kim S K;Lee B;Peck D Shul Y Jung D .[J].Catalysis Today,2008,132:138. |
| [13] | Cui Z M;Liu C P;Liao J H;Xing W .[J].Electrochimica Acta,2008,53:7807. |
| [14] | Gan L;Du H D;Li B H;Kang F Y .[J].Journal of Power Sources,2009,191:233. |
| [15] | Guo X;Guo DJ;Qiu XP;Chen LQ;Zhu WT .A simple one-step preparation of high utilization AuPt nanoparticles supported on MWCNTs for methanol oxidation in alkaline medium[J].Electrochemistry communications,2008(11):1748-1751. |
| [16] | Kadirgan F;Beyhan S;Atilan T .[J].International Journal of Hydrogen Energy,2009,34:4312. |
| [17] | Liao S J;Holmes K A;Tsaprailis H;Birss V I .[J].Journal of the American Chemical Society,2006,128:3504. |
| [18] | Zhao Y C;Cai Y;Tian J N;Lan H X .[J].Materials Chemistry and Physics,2009,115:831. |
| [19] | Liu J Y;Cao J Y;Huang Q H;Li X W Zou Z Q Yang H .[J].Journal of Power Sources,2008,175:159. |
| [20] | Jeon MK;Won JY;Lee KR;Woo SI .Highly active PtRuFe/C catalyst for methanol electro-oxidation[J].Electrochemistry communications,2007(9):2163-2166. |
| [21] | Umeda M;Ojima H;Mohamedi M;Uchida I .[J].Journal of Power Sources,2004,136:10. |
| [22] | Cooper J S;McGinn P J .[J].Journal of Power Sources,2006,163:330. |
| [23] | Chen W M;Sun G Q;Liang Z X;Mao Q Li H Q Wang G X Xin Q Chang H Pak C Seung D .[J].Journal of Power Sources,2006,160:933. |
| [24] | Liang Z X;Zhao T S;Xu J B .[J].Journal of Power Sources,2008,185:166. |
| [25] | Cooper JS;Jeon MK;McGinn PJ .Combinatorial screening of ternary Pt-Ni-Cr catalysts for methanol electro-oxidation[J].Electrochemistry communications,2008(10):1545-1547. |
| [26] | Jeon M K;Zhang Y;McGinn P J .[J].Electrochimica Acta,2009,54:2837. |
| [27] | Jeon M K;McGinn P J .[J].Journal of Power Sources,2009,188:427. |
| [28] | Chen M;Wang ZB;Ding Y;Yin GP .Investigation of the Pt-Ni-Pb/C ternary alloy catalysts for methanol electrooxidation[J].Electrochemistry communications,2008(3):443-446. |
| [29] | Toshima N;Ito R;Matsushita T;Shiraishi Y .[J].Catalysis Today,2007,122:239. |
| [30] | Reddington E;Sapienza A;Gurau B;Viswarathan R Sarangapansi S Smotkin E S Mallouk T E .[J].Science,1998,280:1735. |
| [31] | Jiang J H;Kucemak A .[J].Electrochemistry Communications,2009,11:1005. |
| [32] | Neburchilov V;Wang HJ;Zhang JJ .Low Pt content Pt-Ru-Ir-Sn quaternary catalysts for anodic methanol oxidation in DMFC[J].Electrochemistry communications,2007(7):1788-1792. |
| [33] | Song H Q;Qiu X P;Li F S .[J].Electrochimica Acta,2008,53:3708. |
| [34] | Wang J S;Deng X Z;Xi J Y;Chen L Q,Zhu W T,Qiu X P .[J].Journal of Power Sources,2007,170:297. |
| [35] | Liu ZL;Hong L;Tay SW .Preparation and characterization of carbon-supported Pt, PtSnO2 and PtRu nanoparticles for direct methanol fuel cells[J].Materials Chemistry and Physics,2007(2/3):222-228. |
| [36] | Xue XZ;Ge JJ;Liu CP;Xing W;Lu TH .Novel chemical synthesis of Pt-Ru-P electrocatalysts by hypophosphite deposition for enhanced methanol oxidation and CO tolerance in direct methanol fuel cell[J].Electrochemistry communications,2006(8):1280-1286. |
| [37] | Shimazaki Y;Kobayashi Y;Sugimasa M;Yamada S;Itabashi T;Miwa T;Konno M .Preparation and characterization of long-lived anode catalyst for direct methanol fuel cells[J].Journal of Colloid and Interface Science,2006(1):253-258. |
| [38] | McIntyre D R;Burstein G T;Vossen A .[J].Journal of Power Sources,2002,107:67. |
| [39] | Mclntyre D R;Vossen A;Wilde J R;Burstein G T .[J].Journal of Power Sources,2002,108:1. |
| [40] | Rebello J S;Samant P V;Figueiredo J L;Fernandes J B .[J].Journal of Power Sources,2006,153:36. |
| [41] | Lu X F;Wang H J;Zhang S Y;Cui D L Wang Q L .[J].Solid State Sciences,2009,11:428. |
| [42] | Liu J M;Meng H;Li J I;Liao S J Bu J H .[J].Fuel Cells,2007,7:402. |
| [43] | Yoo E;Okada T;Kizuka T;Nakamura J .[J].Journal of Power Sources,2008,180:221. |
| [44] | Prabhuram J;Zhao T S;Tang Z K;Chen R Liang Z X .[J].Journal of Physical Chemistry B,2006,110:5245. |
| [45] | Girishkumar G;Hall T D;Vinodgopal K;Kamat P V .[J].Journal of Physical Chemistry B,2006,110:107. |
| [46] | Wang X;Li W Z;Chen Z W;Waje M Yan Y S .[J].Journal of Power Sources,2006,158:154. |
| [47] | Wu G;Li L;Li J H;Xu B Q .[J].Journal of Power Sources,2006,155:118. |
| [48] | Zhao H B;Yang J;Li L;Li H Wang J L Zhang Y M .[J].International Journal of Hydrogen Energy,2009,34:3908. |
| [49] | Bessel C A;Laubernds K;Rodriguez N M;Baker R T K .[J].Journal of Physical Chemistry B,2001,105:1115. |
| [50] | Maiyalagan T .[J].International Journal of Hydrogen Energy,2009,34:2874. |
| [51] | Joo J B;Kim P;Kim W;Yi J .[J].Catalysis Today,2008,131:219. |
| [52] | Vengatesan S;Kim H J;Kim S K;Oh I H,Lee S Y,Cho E,Ha H Y,Lim T H .[J].Electrochimica Acta,2008,54:856. |
| [53] | Marie J;Berthon-Fabry S;Achard P;Chatenet M;Pradourat A;Chainet E .Highly dispersed platinum on carbon aerogels as supported catalysts for PEM fuel cell-electrodes: comparison of two different synthesis paths[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2004(0):88-96. |
| [54] | Wei S L;Wu D C;Shang X L;Fu R W .[J].Energy and Fuels,2009,23:908. |
| [55] | Nitani H;Nakagawa T;Daimon H;Kurobe Y,Ono T,Honda Y,Koizumi A,Seino S,Yamamoto T A .[J].Applied Catalysis A:General,2007,326:194. |
| [56] | Chhina H;Campbell S;Kesler O .[J].Journal of Power Sources,2006,161:893. |
| [57] | Sun, CL;Chen, LC;Su, MC;Hong, LS;Chyan, O;Hsu, CY;Chen, KH;Chang, TF;Chang, L .Ultrarine platinum nanoparticles uniformly dispersed on arrayed CNx nanotubes with high electrochemical activity[J].Chemistry of Materials,2005(14):3749-3753. |
| [58] | Jeon M K;Lee K R;Lee W S;Daimon H Nakahara A Woo S I .[J].Journal of Power Sources,2008,185:927. |
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