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  4. 具有MWW结构钛硅分子筛的研究进展

催化学报 , 2010, 31(5): 502-513. doi: 10.3724/SP.J.1088.2010.91205

具有MWW结构钛硅分子筛的研究进展

谢伟 1, , 刘月明 2, , 汪玲玲 3, , 吴鹏 4,

1.华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室,上海,200062

2.华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室,上海,200062

3.华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室,上海,200062

4.华东师范大学化学系上海市绿色化学与化工过程绿色化重点实验室,上海,200062

基金项目:   上海市重点学科建设项目(B409)   国家自然科学基金(20873043;20925310)   国家高技术研究发展计划(863计划)(863计划;2007AA032342;2008AA030801)   国家重点基础研究发展规划(973计划)(973计划;2006CB202508)  

关键词： 钛硅分子筛 , Ti-MWW分子筛 , TS-1分子筛 , 过氧化氢 , 液相氧化

Recent Advances in MWW-Type Titanosilicates

综述了具有MWW结构钛硅分子筛的制备方法、孔道和晶体结构的调变和修饰以及催化应用三个方面的研究进展.与TS-1相比,具有MWW结构钛硅分子筛的制备方法多种多样;其孔道结构可塑性强,通过采用层间剥离、柱撑以及分子水平硅烷化插硅扩孔技术,可以增大和暴露孔道和外表面,满足不同选择氧化反应的要求.由于MWW结构钛硅分子筛拥有复杂而独特的孔道结构,所以在小分子(如直链烯烃等)的环氧化反应,和大分子(环状烯烃,二苯并噻吩等)氧化反应中都表现出优异的催化性能.此外,该钛硅分子筛表现出与TS-1完全不同的溶剂效应,用于烯丙基氯液相环氧化与酮类氨氧化反应主产物选择性更高.

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