采用硝酸盐溶液共浸渍薄水铝石制备了不同Ni含量的Ni/CeO2/Al2O3催化剂,并采用X射线衍射、N2物理吸附和程序升温还原等手段对其进行了表征.结果表明,Ni和CeO2物种之间存在较强的相瓦作用,CeO2的加入有利于NiAl2O4还原成金属Ni,而金属Ni又促进了CeO2还原并与Al2O3反应形成CeAlO3.详细研究了Ni/CeO2/Al2O3催化剂在低水碳摩尔比条件下催化预重整液化石油气(LPG)的反应性能,考察了Ni含量、反应温度和水碳摩尔比对催化剂性能的影响.结果表明,在275~375℃的条件下,催化剂表现出很高的LPG预重整反应活性.较高的Ni含量和水碳摩尔比不仪有利于LPG重整为H2和碳氧化物,也有利于碳氧化物和H2的甲烷化反应.Ni/CeO2/Al2O3催化剂在低水碳摩尔比条件下表现出较高的稳定性和优良的抗积炭性能.提出了在低水碳摩尔比条件下高碳烷烃预重整的反应机理.
参考文献
[1] | Trimm D L;Onsan Z I .[J].Catalysis Review:Science and Engineering,2001,43:31. |
[2] | Chen H Q;Yu H;Peng F;Yang G X Wang H J Yang J Tang Y .[J].Chemical Engineering Journal,2010,160:333. |
[3] | Seo J G;Youn M H;Park S;Chung J S Song I K .[J].International Journal of Hydrogen Energy,2009,34:3755. |
[4] | Nikolla, E.;Schwank, J.;Linic, S. .Comparative study of the kinetics of methane steam reforming on supported Ni and Sn/Ni alloy catalysts: The impact of the formation of Ni alloy on chemistry[J].Journal of Catalysis,2009(2):220-227. |
[5] | Yang Z B;Zhang Y Y;Wang X G;Zhang Y W Lu X G Ding W Zh .[J].Energy & Fuels,2010,24:785. |
[6] | Chen S Q;Wang H;Liu Y .[J].International Journal of Hydrogen Energy,2009,34:7995. |
[7] | Lu Y;Chen J C;Liu Y;Xue Q S He M Y .[J].Journal of Catalysis,2008,254:39. |
[8] | Liu Z X;Mao Z Q;Xu J M;Hess-Mohr N Schmidt V M .[J].Chinese Journal of Chemical Engineering,2006,14:259. |
[9] | Nagaoka K;Sato K;Nishiguchi H;Takita Y .[J].Catalyst Communication,2007,8:1807. |
[10] | Sperle T;Chen D;Lodeng R;Holmen A .[J].Applied Catalysis A:General,2005,282:195. |
[11] | Christensen T S .[J].Applied Catalysis A:General,1996,138:285. |
[12] | Song C S .[J].Catalysis Today,2002,77:17. |
[13] | Suzuki T;Iwanami H I;Iwamoto O;Kitahara T .[J].International Journal of Hydrogen Energy,2001,26:935. |
[14] | Chen FZ;Zha SW;Dong J;Liu ML .Pre-reforming of propane for low-temperature SOFCs[J].Solid state ionics,2004(3/4):269-273. |
[15] | Seo J G;Youn M H;Song I K .[J].International Journal of Hydrogen Energy,2009,34:1809. |
[16] | Nikolla E;Schwank J;Linic S .[J].Journal of Catalysis,2007,250:85. |
[17] | Prakash A S;Shivakumara C;Hegde M S .[J].Materials Science and Engineering B:Solid-state materials for advanced technology,2007,139:55. |
[18] | Trovarelli A.;Dolcetti G.;Lorca JL.;Deleitenburg C. .CO2 METHANATION UNDER TRANSIENT AND STEADY-STATE CONDITIONS OVER RH/CEO2 AND CEO2-PROMOTED RH/SIO2 - THE ROLE OF SURFACE AND BULK CERIA[J].Journal of Catalysis,1995(1):111-124. |
[19] | 于飞,岳宝华,汪学广,耿淑华,鲁雄刚,丁伟中.Ni/Ce-ZrO2/γ-Al2O3催化剂上高温焦炉煤气中焦油组分的常压加氢裂解[J].催化学报,2009(07):690-696. |
[20] | Wang S B;Lu G Q .[J].Applied Catalysis B:Environmental,1998,19:267. |
[21] | Srisiriwat N;Therdthianwong S;Therdthianwong A .[J].International Journal of Hydrogen Energy,2009,34:2224. |
[22] | Jin T;Okuhara T;Mains G J;White J M .[J].Journal of Physical Chemistry,1987,91:3310. |
[23] | Feio LSF;Hori CE;Damyanova S;Noronha FB;Cassinelli WH;Marques CMP;Bueno JMC .The effect of ceria content on the properties of Pd/CeO2/Al2O3 catalysts for steam reforming of methane[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2007(1):107-116. |
[24] | 李林,汪学广,沈葵,邹秀晶,鲁雄钢,丁伟中.低水碳摩尔比条件下液化石油气高效预重整的Ni/CeO2/Al2O3催化剂[J].催化学报,2010(05):525-527. |
[25] | Pena JA.;Guimon C.;Monzon A.;Santamaria J.;Herguido J. .HYDROGENATION OF ACETYLENE OVER NI/NIAL2O4 CATALYST - CHARACTERIZATION, COKING, AND REACTION STUDIES[J].Journal of Catalysis,1996(2):313-322. |
[26] | 张玉红;熊国兴;盛世善;刘盛林 杨维慎 .[J].物理化学学报,1999,15:735. |
[27] | Chen J X;Wang R J;Zhang J Y;He F Han S .[J].Journal of Molecular Catalysis A:Chemical,2005,235:302. |
[28] | Koo K Y;Roh H S;Seo Y T;Seo D J Yoon W L Park S B .[J].International Journal of Hydrogen Energy,2008,33:2036. |
[29] | Roh H S;Jun K W;Park S E .[J].Applied Catalysis A:General,2003,251:275. |
[30] | Zheng C;Apeloig Y;Hoffmann R .[J].Journal of the American Chemical Society,1988,110:749. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%