近十年固体超强碱催化剂的研究进展

催化学报 , 2011, 32(6): 891-898. doi: 10.3724/SP.J.1088.2011.10206

近十年固体超强碱催化剂的研究进展

韦玉丹 ^1, , 张树国 ^2, , 李贵生 ^3, , 尹双凤 ^4, , 区泽棠 ^5,

1.湖南大学化学化工学院,湖南长沙410082

2.湖南大学化学化工学院,湖南长沙410082

3.湖南大学化学化工学院,湖南长沙410082

4.湖南大学化学化工学院,湖南长沙410082

5.湖南大学化学化工学院,湖南长沙410082;香港浸会大学化学系,香港九龙塘

基金项目: 国家自然科学基金(20873038;J0830415) 高等学校博士学科点专项科研基金(200805320001)

关键词：固体超强碱 , 氧化钙 , 硝酸钾 , 氧化铝 , 氧化锆 , 氢氧化钾 , 硝酸钙 , SBA-15分子筛

Research Progress on Solid Superbase Catalysts in the Last Decade

综述了近十年米固体超强碱催化剂的研究进展,主要包括超强碱的类型、制备方法及其应用,以及碱性位的产生机理.迄今为止,已报道的超强碱种类少,大部分是以金属氧化物为载体制得,且需在苛刻条件下制备和使用,从而限制了其发展和应用.此外,有关超强碱位形成机理的研究也鲜见报道.该领域的发展趋势在于开发出可用于制备固体超强碱的新型载体材料和新的修饰组分,以及拓展超强碱在催化反应尤其是高温催化反应中的应用.

参考文献

[1]	Tanabe K;Misono M;Ono Y;Hattori H .[J].Studies in Surface Science and Catalysis,1989,51:1.
[2]	Hattori H .[J].Applied Catalysis A:General,2001,222:247.
[3]	Suzukamo G;Fukao M;Minobe M;Sakamoto A .[P].EP 0 211 448,1990.
[4]	王亚红,曲小姝,祝波,刘立业,崔昌亿.新型固体超强碱催化剂的制备及其结构表征[J].化学世界,2004(11):563-565.
[5]	丁元生,罗志臣,王浔,韩笑言.Na-Na2CO3/γ-Al2O3型固体超强碱催化剂的制备及表征[J].精细石油化工,2004(01):31-34.
[6]	Kije(n)ski J;Radomski P;Fedory(n)ska E .[J].Journal of Catalysis,2001,203:407.
[7]	Sun N J;Klabunde K J .[J].Journal of Catalysis,1999,185:506.
[8]	Gorzawski H;Hoelderich W F .[J].Journal of Molecular Catalysis A:Chemical,1999,144:181.
[9]	魏彤,王谋华,魏伟,孙予罕,钟炳.固体碱催化剂[J].化学通报,2002(09):594-600.
[10]	Ono Y. .Solid base catalysts for the synthesis of fine chemicals[J].Journal of Catalysis,2003(1/2):406-415.
[11]	高智勤,江琦,李向召.固体碱催化剂及其催化机理[J].精细石油化工,2006(04):62-66.
[12]	肖晓明 .[J].石油化工,1994,23:342.
[13]	林棋;林瑜;陈伟松 .[J].福州师专学报,1998,18:43.
[14]	袁传敏,王亚明.固体超强碱催化剂的研究进展及应用[J].云南化工,2000(02):20-22.
[15]	朱华平,吴宗斌,陈元雄,张萍,段世杰,刘晓华,毛宗强.固体超强碱氧化钙催化制备生物柴油及其精制工艺[J].催化学报,2006(05):391-396.
[16]	Wang Y.;Huang WY.;Zhu JH. .Synthesis and characterization of potassium-modified alumina superbases[J].Physical chemistry chemical physics: PCCP,2001(12):2537-2543.
[17]	Sun L B;Yang J;Kou J H;Gu F N,Chun Y,Wang Y,Zhu J H,Zou Z G .[J].Angewandte Chemie International Edition,2008,47:3418.
[18]	Li X;Lu G Z;Guo Y L;Guo Y Wang Y Q Zhang Z G Liu X H Wang Y S .[J].Catalyst Communication,2007,8:1969.
[19]	Kabashima H.;Nakata S.;Tanaka Y.;Hattori H.;Tsuji H. .Activity for base-catalyzed reactions and characterization of alumina-supported KF catalysts[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2000(Special Issue SI):227-240.
[20]	Bota R M;Houthoofd K;Grobet P J;Jacobs P A .[J].Catalysis Today,2010,152:99.
[21]	Wang Y.;Huang W.Y. .Superbase derived from zirconia-supported potassium nitrate[J].Materials Letters,2000(4):198-204.
[22]	Wang Y;Huang W Y;Chun Y;Xia J R Zhu J H .[J].Chemistry of Materials,2001,13:670.
[23]	王英,朱建华,淳远,吴振,何永刚.氧化锆负载含氧酸钾盐研制固体超强碱[J].石油学报(石油加工),2000(01):1-6.
[24]	Kaskel S;Schlichte K .[J].Journal of Catalysis,2001,201:270.
[25]	Wu ZY;Jiang Q;Wang YM;Wang HJ;Sun LB;Shi LY;Xu JH;Wang Y;Chun Y;Zhu JH .Generating superbasic sites on mesoporous silica SBA-15[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(19):4600-4608.
[26]	Sun Y H;Sun L B;Li T T;Liu X Q .[J].Journal of Physical Chemistry C,2010,114:18988.
[27]	Sun LB;Kou JH;Chun Y;Yang J;Gu FN;Wang Y;Zhu JH;Zou ZG .New attempt at directly generating superbasicity on mesoporous silica SBA-15[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2008(10):4199-4208.
[28]	Zahouilya M;Mounira B;Rayadha A;Bahlaouib M A Sebtic S .[J].Arabian J Chem,2008,1:145.
[29]	Yin S F;Xu B Q;Wang S J;Au C T .[J].Applied Catalysis A:General,2006,301:202.
[30]	Zhang S G;Wei Y D;Yin S F;Au C T .[J].Catalyst Communication,2011,12:12.
[31]	Matsuhashi H.;Arata K.;Oikawa M. .Formation of superbase sites on alkaline earth metal oxides by doping of alkali metals[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(21):8201-8205.
[32]	Gorzawski H;Hoelderich W F .[J].Applied Catalysis A:General,1999,179:131.
[33]	Zhu J H;Wang Y;Chun Y;Wang X S .[J].Journal of the Chemical Society,Faraday Transactions,1998,94:1163.
[34]	Wang Y;Ji A;Han X W;Huang W Y Liu J Zhou Z P .[J].Studies in Surface Science and Catalysis,2004,154:2899.
[35]	Zhu J H;Chun Y;Wang Y;Xu Q H .[J].Materials Letters,1997,33:207.
[36]	Baba T;Handa H;Ono Y .[J].Journal of the Chemical Society,Faraday Transactions,1994,90:187.
[37]	Meyer U.;Gorzawski,H. .Michael addition of ethyl acrylate and acetone over solid bases[J].Catalysis Letters,1999(2/4):201-206.
[38]	Kabashima H.;Shibuya T.;Hattori H.;Tsuji H. .Michael addition of nitromethane to alpha,beta-unsaturated carbonyl compounds over solid base catalysts[J].Journal of molecular catalysis, A. Chemical,2000(1/2):23-29.
[39]	周玉杰,张建安,武海棠,刘宏娟,程可可,戴玲妹,刘德华,刘建.分子筛微波辐射负载CaO催化合成生物柴油[J].化学工程,2009(07):59-61.
[40]	Ma H B;Li S F;Wang B Y;Wang R H Tian S J .[J].Journal of the American Oil Chemists' Society,2008,85:263.
[41]	刘洪润,顾珊珊,李修刚,高根之.固体超强碱催化环己酮羟醛缩合反应的研究[J].化学试剂,2009(01):55-58,62.
[42]	Handa H.;Sugisawa H.;Ono Y.;Baba T. .Highly efficient self-condensation of benzaldehyde to benzyl benzoate over KF-loaded alumina[J].Journal of molecular catalysis, A. Chemical,1998(1/3):171-177.

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近十年固体超强碱催化剂的研究进展

Research Progress on Solid Superbase Catalysts in the Last Decade

参考文献