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以脱脂棉为模板,以四水乙酸镁和九水硝酸铝为前驱物,采用外模板法制备了一系列Al2O3-MgO混合氧化物,并用X射线衍射、扫描电镜、低温N2吸附等手段对其进行了表征.结果表明,所制样品显示出棉纤维的生物形态,且具有较高的比表面积(可达206 m2/g).Mg含量较低时Al2O3-MgO混合氧化物为无定形结构,当Mg/Al=1时开始出现MgO的纳米晶相.在环戊二烯甲醇烷基化反应中,具有生物形态和酸碱双功能的Al2O3-MgO混合氧化物表现出较高的催化活性,明显高于未使用模板制得的固体碱,并当Mg/Al=20时样品催化性能最佳.

参考文献

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