以十六烷基三甲基溴化铵、醋酸镉和二氧化锗为前驱物,在优化的水热条件下制备了Cd2Ge2O6纳米棒.采用X射线粉末衍射、扫描电镜、透射电镜和紫外-可见漫反射光谱等手段对样品进行了表征,并以甲基橙和水杨酸为模拟污染物,考察了催化剂的液相光催化性能.结果表明,在弱碱性水热条件下可制得Cd2Ge2O6纳米棒,其液相光催化活性高于商用TiO2.在以Cd2Ge2O6为催化剂的光催化反应体系中,能生成大量的羟基自由基.
参考文献
| [1] | 向全军,余家国.暴露{001}面TiO2纳米片分等级花状结构的制备及其光催化活性[J].催化学报,2011(04):525-531. |
| [2] | 陈艳敏,钟晶,陈锋,张金龙.氟掺杂纳米TiO_2薄膜的低温制备及其光催化性能[J].催化学报,2010(01):120-125. |
| [3] | Yu JG;Liu W;Yu HG .A one-pot approach to hierarchically nanoporous titania hollow microspheres with high photocatalytic activity[J].Crystal growth & design,2008(3):930-934. |
| [4] | Ismail AA;Bahnemann D W .[J].Green Chemistry,2011,13:428. |
| [5] | Li XZ.;Li FB. .Study of Au/Au3+-TiO2 photocatalysts toward visible photooxidation for water and wastewater treatment[J].Environmental Science & Technology: ES&T,2001(11):2381-2387. |
| [6] | Yu J G;Xiong J F;Cheng B;Liu S W .[J].Applied Catalysis B:Environmental,2005,60:211. |
| [7] | Choi W K;Tremir A;Hoffmann M R .[J].Journal of Physical Chemistry,1994,98:13669. |
| [8] | Sakthivel S;Kisch H .[J].Angewandte Chemie International Edition,2003,42:4908. |
| [9] | Asahi R;Morikawa T;Ohwaki T;Aoki K Taga Y .[J].Science,2001,293:269. |
| [10] | Umebayashi T;Yamaki T;Tanaka S;Asai K .[J].Chemistry Letters,2003,32:330. |
| [11] | Vogel R;Hoyer P;Weller H .[J].Journal of Physical Chemistry,1994,98:3183. |
| [12] | Cao Y A;Zhang X T;Yang W S;Du H Bai Y B Li T J Yao J N .[J].Chemistry of Materials,2000,12:3445. |
| [13] | Papp J;Soled S;Dwight K;Wold A .[J].Chemistry of Materials,1994,6:496. |
| [14] | Huang J H;Wang X C;Hou Y D;Chen X F Wu L Wang X X Fu X Z .[J].Microporous and Mesoporous Materials,2008,110:543. |
| [15] | Muggli D S;Ding L .[J].Applied Catalysis B:Environmental,2001,32:181. |
| [16] | Li G S;Zhang D Q;Yu J C;Leung M K H .[J].Environmental Science and Technology,2010,44:4276. |
| [17] | Yi Z;Ye J;Kikugawa N;Kako T Ouyang S StuartWilliams H Yang H Cao J Luo W Li Z Liu Y Withers R L .[J].Nature Materials,2010,9:559. |
| [18] | Ai Z H;Zhang L Z;Lee S C .[J].Journal of Physical Chemistry C,2010,114:18594. |
| [19] | Hitoki G;Ishikawa A;Takata T;Kondo J N,Hara M,Domen K.[J].Chemistry Letters,2002:736. |
| [20] | Zhang J S;Chen X F;Takanabe K;Maeda K Domen K Epping J D Fu X Z Antonietti M Wang X C .[J].Angewandte Chemie International Edition,2009,49:441. |
| [21] | Lei Z;You W;Liu M;Zhou G,Takata T,Hara M,Domen K,Li C.[J].Chemical Communications,2003:2142. |
| [22] | 刘红旗;顾晓娜;陈锋;张金龙 .[J].催化学报,2010,32:129. |
| [23] | Sato J;Kobayashi H;Ikarashi K;Saito N Nishiyama H Inoue Y .[J].Journal of Physical Chemistry B,2004,108:4369. |
| [24] | Liu, Q.;Zhou, Y.;Kou, J.;Chen, X.;Tian, Z.;Gao, J.;Yan, S.;Zou, Z. .High-yield synthesis of ultralong and ultrathin Zn_2GeO _4 nanoribbons toward improved photocatalytic reduction of CO _2 into renewable hydrocarbon fuel[J].Journal of the American Chemical Society,2010(41):14385-14387. |
| [25] | Huang J H;Ding K N;Hou Y D;Wang X C Fu X Z .[J].Chemistry Sustainable Chemistry,2009,1:1011. |
| [26] | Huang J H;Wang X C;Hou Y D;Chen X F Wu L Fu X Z .[J].Environmental Science and Technology,2008,42:7387. |
| [27] | Li X;Ouyang S;Kikugawa N;Ye J .[J].Applied Catalysis A:General,2008,334:51. |
| [28] | Ouyang S;Kikugawa N;Zou Z;Ye J .[J].Applied Catalysis A:General,2009,366:309. |
| [29] | Huang, JH;Ding, KN;Wang, XC;Fu, XZ .Nanostructuring Cadmium Germanate Catalysts for Photocatalytic Oxidation of Benzene at Ambient Conditions[J].Langmuir: The ACS Journal of Surfaces and Colloids,2009(14):8313-8319. |
| [30] | Sato J;Nishiyama H;Inoue Y .[J].Journal of Physical Chemistry B,2003,107:7970. |
| [31] | Bi J H;Wu L;Zhang Y F;Li Z H Li J Q Fu X Z .[J].Applied Catalysis B:Environmental,2009,91:135. |
| [32] | Wang X C;Yu J C;Ho C;Hou Y D Fu X Z .[J].Langmuir,2005,21:2552. |
| [33] | Mrowetz M;Balcerski W;Colussi A J;Hoffman M R .[J].Journal of Physical Chemistry B,2004,108:17269. |
| [34] | Hirakawa T.;Nosaka Y. .Properties of O-2(center dot-) and OH center dot formed in TiO2 aqueous suspensions by photocatalytic reaction and the influence of H2O2 and some ions[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(8):3247-3254. |
| [35] | Xiang Q J;Yu J G;Wong P K .[J].Journal of Colloid and Interface Science,2011,357:163. |
| [36] | Yu X X;Liu S W;Yu J G .[J].Applied Catalysis B:Environmental,2011,104:12. |
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