合成了铜-氮羟基吡啶二甲酰亚胺配合物催化体系,通过元素分析与红外光谱表征确定了配合物的组成与结构.该催化体系在90℃和p(O2)=0.5 MPa的温和条件下实现了环己烯、乙苯等烃类的高效选择氧化.
参考文献
| [1] | Okamura J.;Tsuruya S.;Masai M.;Nishiyama S. .Formation of Cu-supported mesoporous silicates and aluminosilicates and liquid-phase oxidation of benzene catalyzed by the Cu-mesoporous silicates and aluminosilicates[J].Journal of molecular catalysis, A. Chemical,1998(2):133-142. |
| [2] | Tang H.;Lin MR.;Sen Y.;Shen CY. .Cobalt porphyrin-catalyzed alkane oxidations using dioxygen as oxidant[J].Inorganica Chimica Acta,2000(0):1109-1111. |
| [3] | Sheldon R A;van Bekkum H.Fine Chemicals through Heterogeneous Catalysis[M].Weinheim:Wiley-VCH Verlag GmbH,2001:1. |
| [4] | Thomas J M;Raja R;Sankar G;Bell R G .[J].Nature,1999,398:227. |
| [5] | Partenheimer W .[J].Catalysis Today,1995,23:69. |
| [6] | Kantam M L;Sreekanth P;Rao K K;Kumar T P Rao B P C Choudary B M .[J].Catalysis Letters,2002,81:223. |
| [7] | Ishii Y;Nakayama K;Takeno M;Sakaguchi S Iwahama T Nishiyama Y .[J].Journal of Organic Chemistry,1995,60:3934. |
| [8] | Einhorn C;Einhorn J;Marcadal C;Pierre J-L.[J].Chemical Communications,1997:447. |
| [9] | Nechab M;Kumar D N;Philouze C;Einhorn C,Einhorn J .[J].Angewandte Chemie International Edition,2007,46:3080. |
| [10] | Yang G;MaY;Xu J .[J].Journal of the American Chemical Society,2004,126:10542. |
| [11] | Yang G;Zhang Q;Miao H;Tong X Xu J .[J].Organic Letters,2005,7:263. |
| [12] | Tong X;Xu J;Miao H;Yang G Ma H Zhang Q .[J].Tetrahedron,2007,63:7634. |
| [13] | Tong X;Xu J;Miao H .[J].Advanced Synthesis and Catalysis,2005,347:1953. |
| [14] | Tong X;Xu J;Miao H;Gao J .[J].Tetrahedron Letters,2006,47:1763. |
| [15] | Wentzel BB.;Alsters PL.;Feiters MC.;Nolte RJM.;Donners MPJ. .N-hydroxyphthalimide/cobalt(II) catalyzed low temperature benzylic oxidation using molecular oxygen[J].Tetrahedron,2000(39):7797-7803. |
| [16] | Zhang Q;Chen C;Ma H;Miao H Zhang W Sun Z Xu J .[J].Journal of Chemical Technology and Biotechnology,2008,83:1364. |
| [17] | Zhang Q;Chen C;Xu J;Wang F Gao J Xia C .[J].Advanced Synthesis and Catalysis,2011,353:226. |
| [18] | Nawaz, S.;Isab, A.A.;Merz, K.;Vasylyeva, V.;Metzler-Nolte, N.;Saleem, M.;Ahmad, S. .Synthesis, characterization and antimicrobial studies of mixed ligand silver(I) complexes of triphenylphosphine and heterocyclic thiones: Crystal structure of bis[{(μ2-diazinane-2-thione)(diazinane-2-thione) (triphenylphosphine)silver(I) nitrate}][J].Polyhedron: The International Journal for Inorganic and Organometallic Chemistry,2011(9):1502-1506. |
| [19] | Eshtiagh-Hosseini, H.;Housaindokht, M.R.;Beyramabadi, S.A.;Tabatabaei, S.H.M.;Esmaeili, A.A.;Javan Khoshkholgh, M. .Synthesis, experimental and theoretical characterization of N,N′-dipyridoxyl (1,4-butanediamine) Schiff-base ligand and its Cu(II) complex[J].Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy,2011(3):1046-1050. |
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