二维六方p6mm有序介孔 WO3-TiO2复合材料的制备及其可见光光催化性能

催化学报 , 2012, 33(2): 308-316. doi: 10.3724/SP.J.1088.2012.10841

二维六方p6mm有序介孔 WO3-TiO2复合材料的制备及其可见光光催化性能

黄燕 ^1, , 李可心 ^2, , 颜流水 ^3, , 戴玉华 ^4, , 黄智敏 ^5, , 薛昆鹏 ^6, , 郭会琴 ^7, , 熊晶晶 ^8,

1.南昌航空大学环境与化学工程学院,生态诊断修复与污染阻断技术省级重点实验室,江西南昌330063

2.南昌航空大学环境与化学工程学院,生态诊断修复与污染阻断技术省级重点实验室,江西南昌330063

3.南昌航空大学环境与化学工程学院,生态诊断修复与污染阻断技术省级重点实验室,江西南昌330063

4.南昌航空大学环境与化学工程学院,生态诊断修复与污染阻断技术省级重点实验室,江西南昌330063

5.南昌航空大学环境与化学工程学院,生态诊断修复与污染阻断技术省级重点实验室,江西南昌330063

6.南昌航空大学环境与化学工程学院,生态诊断修复与污染阻断技术省级重点实验室,江西南昌330063

7.南昌航空大学环境与化学工程学院,生态诊断修复与污染阻断技术省级重点实验室,江西南昌330063

8.南昌航空大学环境与化学工程学院,生态诊断修复与污染阻断技术省级重点实验室,江西南昌330063

基金项目: 南昌航空大学博士启动基金(EA201002219) 江西省科技支撑计划(2010BSB03100) 国家自然科学基金(20765003;21165013) 江西省自然科学基金(2010GZH0112)

关键词：三氧化钨 , 二氧化钛 , 有序介孔材料 , 光催化 , 罗丹明B , 2,4-二氯苯氧乙酸

Preparation of 2D Hexagonal p6mm Ordered Mesoporous WO3-TiO2 Composite Materials and Their Visible-Light Photocatalytic Activity

以非离子型表面活性剂为模板剂,采用蒸发诱导自组装法制备了一系列不同WO3含量的有序介孔WO3-TiO2复合材料,并表征了其孔结构、形貌、孔隙率、光谱性质及组成.结果表明,该材料呈二维六方p6mm对称和锐钛矿晶相结构；与无序WO3-TiO2复合材料相比,其比表面积(152～154 m2/g)更大,孔径更均一(5.3 nm),且比纯TiO2的带隙宽度(3.0 eV)更窄.将该WO3-TiO2样品用于可见光光催化降解水相中罗丹明B和2,4-二氯苯氧乙酸的反应中,发现WO3含量适当的有序介孔WO3-TiO2样品的光催化活性比无序的样品和纯TiO2的更高.

参考文献

[1]	Thompson T L;Yates J T .[J].Chemical Reviews,2006,106:4428.
[2]	Lü K;Xu Y M .[J].Journal of Physical Chemistry B,2006,110:6204.
[3]	Parkin IP;Palgrave RG .Self-cleaning coatings[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(17):1689-1695.
[4]	Yu H G;Lee S C;Yu J G;Ao C H .[J].Journal of Molecular Catalysis A:Chemical,2006,246:206.
[5]	Wang SH;Hou WS;Wei LQ;Jia HS;Liu XG;Xu BS .Antibacterial activity of nano-SiO2 antibacterial agent grafted on wool surface[J].Surface & Coatings Technology,2007(3):460-465.
[6]	Li J X;Xu J H;Dai W L;Li H X Fan K N .[J].Applied Catalysis B:Environmental,2008,82:233.
[7]	Puddu, V;Mokaya, R;Puma, GL .Novel one step hydrothermal synthesis of TiO2/WO3 nanocomposites with enhanced photocatalytic activity[J].Chemical Communications,2007(45):4749-4751.
[8]	蒋晶晶,龙明策,吴德勇,蔡伟民.氟改性纳米TiO2的制备及其光催化降解甲基橙机理[J].物理化学学报,2011(05):1149-1156.
[9]	丛野,秦云,李轩科,董志军,袁观明,崔正威.二氧化钛涂覆多壁碳纳米管的制备及可见光催化活性[J].物理化学学报,2011(06):1509-1515.
[10]	陈闪山,朱银华,李伟,刘维佳,李力成,杨祝红,刘畅,姚文俊,陆小华,冯新.含TiO2（B）介孔氧化钛材料的制备、特性和应用[J].催化学报,2010(06):605-614.
[11]	Shibata H;Ogura T;Mukai T;Ohkubo T Sakai H Abe M .[J].Journal of the American Chemical Society,2005,127:16396.
[12]	Fukuda K;Ebina Y;Shibata T;Aizawa T;Nakai I;Sasaki T .Unusual crystallization behaviors of anatase nanocrystallites from a molecularly thin titania nanosheet and its stacked forms: Increase in nucleation temperature and oriented growth[J].Journal of the American Chemical Society,2007(26):202-209.
[13]	Li H X;Bian Z F;Zhu J;Huo Y N Li H Lu Y F .[J].Journal of the American Chemical Society,2007,129:4538.
[14]	Yu JC;Li GS;Wang XC;Hu XL;Leung CW;Zhang ZD .An ordered cubic Im3m mesoporous Cr-TiO2 visible light photocatalyst[J].Chemical communications,2006(25):2717-2719.
[15]	Mitoraj D;Kisch H .[J].Angewandte Chemie International Edition,2008,47:9975.
[16]	Wu G;Wang J;Thomas D F;Chen A .[J].Langmuir,2008,24:3503.
[17]	Junin C;Thanachayanont C;Euvananont C;Inpor K;Limthongkul P .Effects of precipitation, sol-gel-synthesis conditions, and drying methods on the properties of nano-TiO2 for photocatalysis applications[J].European journal of inorganic chemistry,2008(6):974-979.
[18]	Yang X;Wang Y H;Xu L L;Yu X D Guo Y H .[J].Journal of Physical Chemistry C,2008,112:11481.
[19]	Yang X;Ma F Y;Li K X;Guo Y N Hu J L Li W Huo M X Guo Y X .[J].Journal of Hazardous Materials,2010,175:429.
[20]	Wang WW;Zhu YJ;Yang LX .ZnO-SnO2 hollow spheres and hierarchical nanosheets: Hydrothermal preparation, formation mechanism, and photocatalytic properties[J].Advanced functional materials,2007(1):59-64.
[21]	Kumar A;Jain A K .[J].Journal of Molecular Catalysis A:Chemical,2001,165:265.
[22]	Zong X;Yan HJ;Wu GP;Ma GJ;Wen FY;Wang L;Li C .Enhancement of photocatalytic H-2 evolution on CdS by loading MOS2 as cocatalyst under visible light irradiation[J].Journal of the American Chemical Society,2008(23):7176-7177.
[23]	Marci G;Augugliaro V;Lopez-Munoz M J;Martin C Palmisano L Rives V Schiavello M Tilley R J D Venezia AM .[J].Journal of Physical Chemistry B,2001,105:1026.
[24]	Kostedt WL;Ismail AA;Mazyck DW .Impact of heat treatment and composition of ZnO-TiO2 nanoparticles for photocatalytic oxidation of an azo dye[J].Industrial & Engineering Chemistry Research,2008(5):1483-1487.
[25]	Shchukin D G;Caruso R A .[J].Advanced Functional Materials,2003,13:789.
[26]	Bian Z F;Zhu J;Wang S H;Gao Y Qian X F Li H X .[J].Journal of Physical Chemistry C,2008,112:6258.
[27]	Ke D N;Liu H J;Peng T Y;Liu X Dai K .[J].Materials Letters,2008,62:447.
[28]	刘阳,王晟,王驹,许章炼,陈文兴,蒋杰,韦坚红.WO_3/TiO_2纳米棒复合材料的制备及其光催化活性[J].催化学报,2010(04):485-489.
[29]	Schmidt W .[J].ChemCatChem,2009,1:53.
[30]	Li K X;Hu J L;Li W;Ma F Y Xu L L Guo Y H .[J].Journal of Materials Chemistry,2009,19:8628.
[31]	Taguchi A;Schüth F .[J].Microporous and Mesoporous Materials,2005,77:1.
[32]	Ohno T;Nowinska K;Formanniak R;Kaleta W Waclaw A .[J].Applied Catalysis A:General,2003,256:115.
[33]	高冠道,李婧,张爱勇,安晓红,周蕾.仿生光催化剂的优化制备、介孔特性表征及其在催化降解苯酚废水中的应用[J].物理化学学报,2010(09):2437-2442.
[34]	Wang SJ;Zhang XT;Cheng G;Jiang XH;Li YC;Huang YB;Du ZL .Study on electronic transport properties of WO3TiO2 nanocrystalline thin films by photoassisted conductive atomic force microscopy[J].Chemical Physics Letters,2005(1/3):63-67.
[35]	Lu YD;Yuan MJ;Liu Y;Tu B;Xu CH;Liu BH;Zhao DY;Kong JL .Photoelectric performance of bacteria photosynthetic proteins entrapped on tailored mesoporous WO3-TiO2 films[J].Langmuir: The ACS Journal of Surfaces and Colloids,2005(9):4071-4076.
[36]	Higashimoto S;Sakiyama M;Azuma M .[J].Thin Solid Films,2006,503:201.
[37]	Yuan M J;Shah Z;Tian B Z;Tu B Yang P Y Zhao D Y .[J].Microporous and Mesoporous Materials,2005,78:37.
[38]	Wang S J;Cheng G;Jiang X H;Li Y C Huang Y B Du Z L .[J].Applied Physics Letters,2006,88:212108.
[39]	Jia H P;Wan I L .[J].Chemistry of Materials,2006,18:847.
[40]	Cheng LF;Zhang XT;Liu B;Wang HZ;Li YC;Huang YB;Du ZL .Template synthesis and characterization of WO3/TiO2 composite nanotubes[J].Nanotechnology,2005(8):1341-1345.
[41]	Chen S F;Chen L;Gao S;Cao G Y .[J].Powder Technology,2005,160:198.
[42]	Li K X;Guo Y N;Ma F Y;Li H C Chen L Guo Y H .[J].Catalysis Communications,2010,11:839.
[43]	Li K X;Yang X;Guo Y N;Ma F Y Li H C Chen L Guo Y H .[J].Applied Catalysis B:Environmental,2010,99:364.
[44]	Wan Y;Shi Y;Zhao D.[J].Chemical Communications,2007:897.
[45]	Akurati KK;Vital A;Dellemann JP;Michalow K;Graule T;Fetti D;Baiker A .Flame-made WO3/TiO2 nanoparticles: Relation between surface acidity, structure and photocatalytic activity[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2008(1):53-62.
[46]	Zhao D;Huo Q;Feng J;Chmelka B F Stucky G D .[J].Journal of the American Chemical Society,1998,120:6024.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网