燃料电池Pt基核壳结构电催化剂的最新研究进展

催化学报 , 2012, 33(2): 222-229. doi: 10.3724/SP.J.1088.2012.10947

燃料电池Pt基核壳结构电催化剂的最新研究进展

张海艳 ^1, , 曹春晖 ^2, , 赵健 ^3, , 林瑞 ^4, , 马建新 ^5,

1.华东理工大学资源与环境工程学院,上海200237;同济大学新能源汽车工程中心,上海201804

2.同济大学新能源汽车工程中心,上海201804;同济大学汽车学院,上海201804

3.华东理工大学资源与环境工程学院,上海200237;同济大学新能源汽车工程中心,上海201804

4.同济大学新能源汽车工程中心,上海201804;同济大学汽车学院,上海201804

5.华东理工大学资源与环境工程学院,上海200237;同济大学新能源汽车工程中心,上海201804;同济大学汽车学院,上海201804

基金项目: 节能与环保汽车创新引智基地"111计划"(B08019) 高等学校博士学科点专项科研基金(20070247055) 同济大学青年优秀人才基金(2006KJ022) 上海市重点学科建设项目(B303)

关键词：燃料电池 , 铂基催化剂 , 核壳结构 , 氧气还原反应 , 欠电位沉积法

Recent Development of Pt-Based Core-Shell Structured Electrocatalysts in Fuel Cells

综述了用于燃料电池的Pt基核壳结构电催化剂的制备方法和表征方法的最新研究进展.首先,详细介绍了核壳结构催化剂的制备方法,主要包括胶体法、电化学法和化学还原法等.其中胶体法的应用最为广泛,制备过程简单易控;电化学法和化学还原法在最近几年得到了迅速发展,并有望用于核壳结构电催化剂的批量化生产.其次,简单阐述了核壳结构电催化剂特用的表征方法.其中高角度环形暗场-扫描透射电子显微镜是近年来发展的一种新技术,它利用暗场强度与原子序数的比例关系可以有效地表征核壳电催化剂的特殊结构.最后,总结了存在的问题并展望了可能的发展方向.

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