简要地总结了大气离子与自由基反应的研究进展和以氯苯为目标产物的气相离子-分子反应的质谱研究.根据大气层状结构图、高层大气的特点以及相关的研究结果,提出了氯苯类污染物的形成不排除是大气化学反应尤其是离子反应产物的观点.对进一步研究大气中氯苯类污染物的生成机制和控制具有重要意义.
Research on the gas-phase radical/ion chemistry was briefly summarized. Emphasis was given to the application of mass spectrometric technique to ion-molecule reactions between halocarbocations and aromatic compounds which gave rise to chlorobenzenes as one of the targeted products. That chlorobenzenes were readily formed in the mass spectrometer implied that chlorobenzenes in the atmosphere should not exclude the possibility of ion/radical chemistry reactions. The environmental significance of such reactions was also explored.
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