利用胶棉膜作为活性模板,制备出方解石型碳酸钙组装球,在其表面上将镍进行原位还原反应,首次成功获得了碳酸钙/镍复合导电材料,通过TEM、XRD、FT-IR和TG-DTA等测试技术对产物结构及性能进行了表征,并将产物应用于抗静电领域,制备成的抗静电涂料与用纯镍粉制备的涂料具有同等抗静电性能(电阻率为1.2×10<'6>Ω·cm),并可以节省60%的镍.该复合材料在导电和抗静电等领域具有应用前景,能够节省对镍的消耗.
参考文献
| [1] | ZHAO Lina,ZHAO Xu,REN Suxia,et al.In Situ Synthesis and Surface Modification of Calcium Carbonate[J].Acta PhysChim Sin,2009,25:47-52(in Chinese).赵丽娜,赵旭,任素霞,等.碳酸钙的原位合成及表面改性[J].物理化学学报,2009,25:47-52. |
| [2] | ZHANG Xifeng,CHENG Xiaonong,YIN Hengbo,et al.Preparation of Ni Nanoerystals with Different Morphologies by Liquor-phase Reduction[J].Chinese J Nonferrous Met,2007,17:1701-1704(in Chinese).张锡凤,程晓农,殷恒波,等.液相化学还原法制备不同形貌的多晶纳米镍[J].中国有色金属学报,2007,17:1701-1704. |
| [3] | Liu J K,Luo C X,Lu Y,et al.Facile Synthesis and Optical Property of Core/shell Chromate Nanoreds[J].J Dispers Sci Technol,2008,29:209 -212. |
| [4] | Wang J,Long Y,Zhang Y,et al.Preparation of Highly Luminescent CdTe/CdS Core/shell Quantum Dots[J].Chem Phys Chem,2009,10:680-685. |
| [5] | Zhang M,Liu J,Miao R,et al.Preparation and Characterization of Fluorescence Probe from Assembly Hydroxyapatite Nanocompesit[J].Nanoscale Res Lett,2010,(5):675-679. |
| [6] | Zhao W,Zhang Q Y,Zhang J P.Preparation and Characterization of Core-shell PS/Ni Composite Microspheres[J].Polym Compos,2009,30:1098-1102. |
| [7] | Chen D,Liu S,Li J J.Polymer-assisted Sol-gel Synthesis and Characterization of Zn<,2>SiO<,4>:Eu<'3+> Powders[J].J Alloys Compd,2009,475:494 -500. |
| [8] | Chen D,Lim J J,Shi C S.Properties of Core-shell Ni-Au Nanoparticles Synthesized Through a Redox-transmetalation Method in Reverse Microemulsion[J].Chem Mater,2007,19:3399-3405. |
| [9] | Zhu W,Wang G Z,Hong X.One-step Fabrication of Ni/TiO<,2> Core/shell Nanorod Arrays in Anodic Aluminum Oxide Membranes[J].J Phys Chem C,2009,113:5450-5454. |
| [10] | Zhou W,Zheng K,He L.Ni/Ni<,3>C Core-shell Nanochains and its Magnetic Properties:One-step Synthesis at Low Temperature[J].Nano Lett,2008,8:1147-1152. |
| [11] | Shen X Q,Jing M X,Li W X.Fabrication of Fe-,Ni-and FeN--coated Al<,2>O<,3> Core-shell Microspheres by Heterogeneous Precipitation[J].Powder Technol,2005,160:229-233. |
| [12] | Sun X C,Toledo J A,Cui Z L.DNA biosensor with high Sensitivity Amplified by Gold Nanoparticles[J].J Nanopart Res,2001,3:325-328. |
| [13] | Liu J,Wu Q,Ding Y.Synthesis,Characterization,and Growth Mechanism of Tellurium Nanotube[J].Cryst Growth Des,2005,5:445-449. |
| [14] | JIN Dalai,YUE Linhai,XU Zhude.Infared and Raman Analysis of Spherical CaCO<,3> Composite[J].Chinese J Inorg Chem,2004,20:715-720.(in Chinese).金达莱,岳林海,徐铸德.球形碳酸钙复合物的红外、拉曼光谱分析研究[J].无机化学学报,2004,20:715-720. |
| [15] | TAO Xiaojun,LI Zhiwei,CHEN Hongjie,et al.A New Approach to Synthesize Nickel Nanoparticles[J].Acta Phys-Chim Sin,2005,21:569-572(in Chinese).陶小军,李志伟,陈洪杰,等.一种制备镍纳米颗粒的新方法[J].物理化学学报,2005,21:569-572. |
| [16] | DU Shiguo,YAN Jun,ZHANG Tonglai,et al.Preparation of Coatings Using Alkyd and Copper Powder[J].Paint Coat Ind,2004,34(12):19-21 (in Chinese).杜仕国,闫军,张同来,等.醇酸树脂铜粉复合导电涂料的研制[J].涂料工业,2004,34(12):19-21. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%