欢迎登录材料期刊网

材料期刊网

高级检索

在聚2,7-(9,9-二辛基)芴(PFO)和30%的2-(对联苯基)-5-(对叔丁基苯基)-1,3,4-(噁)二唑(PBD)主体材料中掺杂短磷光寿命的meso-四(对正葵酰氧基苯基)卟啉铂(TDPPPt),制成聚合物基发光器件.器件结构为:ITO/PEDOT:PSS/PVK/PFO+ 30% PBD:TDPPPt/Ca/Al(ITO:氧化铟锡;PE DOT:聚3,4-乙撑二氧噻吩;PSS:聚苯乙烯磺酸盐;PVK:聚乙烯基咔唑).当客体掺杂浓度≥3%时,器件给出饱和的红色发射.当驱动电压从7V升高至14 V时,器件发光色度保持不变,CIE(国际发光照明委员会)色坐标稳定在(0.66,0.28)左右.器件的最大亮度和电流效率分别为1 390 cd/m2和1.34 cd/A.在电流密度100×10-3和150×10-3 A/cm2时,电流效率分别为1.18和0.99 cd/A,器件在高电流密度下具有良好的稳定性.

参考文献

[1] Brooks J,Babayan Y,Lamansky S,et al.Synthesis and Characterization of Phosphorescent Cyclometalated Platinum Complexes[J].Inorg Chem,2002,41:3055-3066.
[2] Lin Y Y,Chan S C,Chan M C W,et al.Photophysical,and Plectrophosphorescent Properties of Platinum(Ⅱ) Complexes Supported by Tetradentate N2O2 Chelates[J].Chem Eur J,2003,9:1263-1272.
[3] Wei X Q,Peng J B,Cheng J B,et al.High Performance Polymer Electrophosphorescent Ddvices with tert-Butyl Group Modified Iridium Complexes as Emitters[J].Adv Funct Mater,2007,17:3319-3325.
[4] Park S Y,Kang J W,Kang D M,et al.Efficient,Color Stable White Organic Light-Emitting Diode Based on High Energy Level Yellowish-Green Dopants[J].Adv Mater,2008,20:1957-1961.
[5] Jakka Kavitha,Sheng-Yuan Chang,Yun Chi,et al.In Search of High-Performance Platinum(Ⅱ) Phosphorescent Materials for the Fabrication of Red Electroluminescent Devices[J].Adv Funct Mater,2005,15 (2):223-229.
[6] Baldo M A,O'Brien D F,Forrest S,et al.High Efficient Phosphorescent Emission from Organic Elenctroluminescent Devices[J].Nature,1998,395:151-154.
[7] XIE Yuqing,GUO Jianhua,PENG Junbiao,et al.High Efficiency Red-pho Sphorescent 6CPt Electroluminescence[J].Acta Phys Sin,2005,54(7):3424-3428(in Chinese).谢玉卿,郭建华,彭俊彪,等.掺咔唑取代卟啉铂的高效聚合物红色磷光发射[J].物理学报,2005,54(7):3424-3428.
[8] GUO Jianhua,WU Ying,YE Kaiqi,et al.Electroluminescent Property of Tetrakis (phenyl) Porphyrin Platinum(Ⅱ)[J].J Mol Sci,2005,21 (1):1-5 (in Chinese).郭建华,吴英,叶开其,等.四苯基卟啉铂电致发光性能的研究[J].分子科学学报,2005,21(1):1-5.
[9] Masamichi I,Fumiaki I,Naoki A,et al.Enhancement of External Quantum Efficiency of Red Phosphorescent Organic Light-Emitting Devices with Facially Encumbered and Bulky Pt(Ⅱ) Porphyrin Complexes[J].Adv Funct Mater,2006,16:515-519.
[10] Jakka Kavitha,Sheng-Yuan Chang,Yun Chi,et al.In Search of High-Performance Platinum(Ⅱ) Phosphorescent Materials for the Fabrication of Red Electroluminescent Devices[J].Adv Funct Mater,2005,15(2):223-229.
[11] MA Changqi,WANG Xuesong,ZHANG Baowen,et al.Progress in Red Emitters for Organic Light-Emitting Diodes[J].Prog Chem[J],2004,16(3):463-473 (in Chinese).马昌期,王雪松,张宝文,等.有机电致发光红色发光材料研究进展[J].化学进展,2004,16(3).463-473.
[12] Kwong R C,Lamansky S,Thompson M E.Organic Light-Emitting Devices Based on Phosphorescent Hosts and Dyes[J].Adv Mater,2000:1234-1138.
[13] Raymond C,Sibley S,Dubovy T,et al.Efficient Saturated Red Organic Light Emitting Devices Based on Phosphorescent Platinum(Ⅱ) Porphyrins[J].Chem Mater,1999,11(12):3709-3713.
[14] WU Jun,ZHONG Guolun,SUN Jianzhong.Research Progress in Electroluminescent Properties of Porphyrins[J].Bull Sci Technol,2007,23(3):308-313 (in Chinese).吴俊,钟国伦,孙建中.卟啉类化合物电致发光性能研究进展[J].科技通讯,2007,23(3):308-313.
[15] LUO Kaijun,ZHANG Lifang,XU Lingling,et al.Synthesis and Properties of meso-Tetrakis(4-n-acyloxylphenyl) Porphyrin Platinum(Ⅱ) Complexes[J].Chinese J Appl Chem,2010,27(6):684-690(in Chinese).骆开均,张黎芳,徐玲玲,等.Meso-四(对-酰氧基苯基)卟啉铂配合物的合成和性能研究[J].应用化学,2010,27(6):684-690.
[16] ZHU Fengzhi,YANG Gang,LI Lu,et al.A New Divice Based on Pt Complex Phosphorescent Materials with Liquid Crystal[J].J Optoelectron Laser,2010,21 (6):829-832 (in Chinese).朱凤稚,杨刚,李璐,等.一种基于液晶性质的Pt配合物磷光材料电致发光器件[J].光电子·激光,2010,21(6):829-832.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%