欢迎登录材料期刊网

材料期刊网

高级检索

选择带结构负电荷的蒙脱土和带微量结构负电荷的高岭土,研究了其对pb2+的吸附性能,并探讨了吸附机理.研究表明,蒙脱土和高岭土吸附pb2的动力学曲线符合准二级动力学方程,吸附等温线符合Langmuir方程.Pb2+同时以内层配合和外层配合形式吸附,其相对量与pH值有关.在pH值小于4和大于8的范围内,以内层配合物为主;而pH值在4~8范围内外层配合物比例增大.pb2+能进入蒙脱土的层间,而不能进入高岭土的层间;部分pb2+可进入黏土颗粒的微孔中被固定.蒙脱土对pb2+的吸附能力和饱和吸附量明显高于高岭土.

参考文献

[1] Berninger K,Pennanen J.Heavy Metals in Perch from Two Acidified Lakes in the Salpausselka Esker Area in Finland[J].Water Air Soil Pollut,1995,81:283-294.
[2] Krishna G B,Susmita S G.Pb (Ⅱ) Uptake by Kaolinite and Montmorillonite in Aqueous Medium:Influence of Acid Activation of the Clays[J].Colloids Surf A,2006,277:191-200.
[3] Serrano S,Garrido F.Competitive Sorption of Cadmium and Lead in Acid Soils of Central Spain[J].Geoderma,2005,124:91-104.
[4] Susmita S G,Krishna G B.Interaction of Metal Iota with Clays:Ⅰ.A Case Study with Pb(Ⅱ)[J].Appl Clay Sci,2005,30:199-208.
[5] Julide H,Resat A.Modeling of Copper(Ⅱ) and Lead (Ⅱ) Adsorption on Kaolinite-based Clay Minerals Individually and in the Presence of Humic Acid[J].J Colloid Interface Sci,2006,295:1-13.
[6] Heidmann I,Christl I,Kretzschmar R,et al.Sorption of Cu and Pb to Kaolinite-fulvic Acid Colloids:Assessment of Sorbent Interactions[J].Geochim Cosmochim,2005,69:1675-1686.
[7] Cynthia A C,Raymond N Y.Aspects of Kaolinite Characterization and Retention of Pb and Cd[J].Appl Clay Sci,2002,22:39-45.
[8] Freedman Y E,Magatz M G,Long G L,et al.Interaction of Metals with Mineral Surface in a Natural Groundwater Environment[J].Chem Geol,1994,116:111-121.
[9] Manning P G,Wang X W.The Binding of Pb,Zn,and Other Metal Ions in Suspended Riverine Particulate Matter[J].Can Mineral,1995,33:679-687.
[10] He H P,Guo J G,Xie X D,et al.Location and Migration of Cations in Cu2+ Adsorbed Montmorillonite[J].Environ Int,2001,26:347-352.
[11] Heath D,Tadros ThF.Influence of pH,Electrolyte,and Poly(vinyl alcohol) Addition on the Rheological Characteristics of Aqueous Dispersions of Sodium Montmorillonite[J].J Colloid Interface Sci,1983,93:307-315.
[12] ZHANG Naixian.Research Methods of Clay Mineral[M].Beijing:Science Press,1990(in Chinese).张乃娴.粘土矿物研究方法[M].北京:科学出版社,1990.
[13] Rodda D P,Johnson B B,Wells J D.Modeling the Effect of Temperature on Adsorption of Lead (Ⅱ) and Zinc (Ⅱ) onto Goethite at Constant pH[J].J Colloid Interface Sci,1996,184:365-377.
[14] Jiao Y N,Hou W G.Some Interface Electrochemical Properties of Kaolinite[J].Chinese J Chem,2007,25:1-10.
[15] Ucun H,Bayhan Y K,Kaya Y,et al.Biosorption of Lead(II) from Aqueous Solution by Cone Biomass of Pinus Sylvestris[J].Desalination,2003,154:233-238.
[16] Bayramoglu G,Bekta S,Arica M Y.Biosorption of Heavy Metal Ions on Immobilized White-rot Fungus Trametes Versicolor[J].J Hazard Mater,2003,B101:285-300.
[17] Daniel G S,Donald L S.The Use of XAFS to Distinguish Between Inner and Outer Sphere Lead Adsorption Complexes on Montmorillonite[J].J Colloid Interface Sci,1999,216:257-269.
[18] Papelis C,Hayes K F.Distinguishing Between Interlayer and External Sorption Sites of Clay Minerals Using X-ray Absorption Spectroscopy[J].Colloids Surf,1996,107:89-96.
[19] O'Day P,Parks G A,Brown G E.Molecular Structure and Binding Sites of Cobalt(Ⅱ) Surface Complexes on Kaolinite from X-ray Absorption Spectroscopy[J].Clays Clay Miner,1994,42:337-355.
[20] Echeverri'a J,Indurain J,Churio E,et al.Simultaneous Effect of pH,Temperature,Ionic Strength and Initial Concentration on the Retention of Ni on Illite[J].Colloids Surf A,2003,218:175-187.
[21] Sposito G.The Chemistry of Soils[M].New York:Oxford University Press,1989.
[22] Rahnemaie R,Hiemstra T,Riemsdijk W H.Inner and Outer Sphere Complexation of Ions at the Goethite-solution Interface[J].J Colloid Interface Sci,2006,297:379-388.
[23] Anne M L,Kraepiel K K,Francois M M.A Model for Metal Adsorption on Montmorillonite[J].J Colloid Interface Sci,1999,210:43-54.
[24] Bradl H B.Adsorption of Heavy Metal Ions on Soils and Constituents[J].J Colloid Interface Sci,2004,277 (1):1-18.
[25] Reed B E,Cline S R.Retention and Release of Lead by a Very Fine Sandy Loam:1.Isotherm Modeling[J].Sep Sci Technol,1994,29:1529-1551.
[26] Kim Y,Kirkpatrick R J,Cygan R T.133Cs NMR Study of Cesium on the Surfaces of Kaolinite and Illite[J].Geochim Cosmochim Acta,1996,60:4059-4074.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%