欢迎登录材料期刊网

材料期刊网

高级检索

不相溶混合溶剂的选择性胶凝对于溶剂纯化和分离,特别是溢油处理和水体净化具有十分重要的意义.具有选择性胶凝能力的胶凝剂可以是高分子、微纳米颗粒和小分子胶凝剂.然而,相对于高分子和微纳米颗粒材料,以小分子化合物为胶凝剂的凝胶往往具有凝胶-溶胶相变可逆性,这种可逆性无疑会对凝胶体系的实际应用带来额外的好处.基于这些考虑,本文按照胶凝剂分子的结构,分类介绍此类小分子胶凝剂研究进展,并展望了相关研究的前景和可能应用.

参考文献

[1] George M,Weiss R G.Molecular Organogels.Soft Matter Comprised of Low-Molecular-Mass Organic Gelators and Organic Liquids[J].Acc Chem Res,2006,39(8):489-497.
[2] Ajayaghosh A,Praveen V K,Vijayakumar C.Organogels as Scaffolds for Excitation Energy Transfer and Light Harvesting[J].Chem Soc Rev,2008,37:109-122.
[3] Ajayaghosh A,Praveen V K.π-Organogels of Self-Assembled p-Phenylenevinylenes:Soft Materials with Distinct Size,Shape,and Functions[J].Acc Chem Res,2007,40(8):644-656.
[4] Weng W G,Jamieson A M,Rowan S J,et al.Understanding the Mechanism of Gelation and Stimuli-Responsive Nature of a Class of Metallo-Supramolecular Gels[J].J Am Chem Soc,2006,128(35):11663-11672.
[5] Ahmed S A,Sallenave X,Pozzo J,et al.Multiaddressable Self-Assembling Organogelators Based on 2H-Chromene and N-Acyl-1,ω-Amino Acid Units[J].Langnuir,2002,18 (19):7096-7101.
[6] Miljanic S,Frkanec L,Mei(/c) Z,et al.Photoinduced Gelation by Stilbene Oxalyl Amide Compounds[J].Langmuir,2005,21(7):2754-2760.
[7] Aggeli A,Bell M,Boden N,et al.Responsive Gels Formed by the Spontaneous Serf-Assembly of Peptides into Polymeric β-Sheet Tapes[J].Nature,1997,386:259-262.
[8] Engelkamp H,Middelbeek S,Nolte R J M,et al.Self-Assembly of Disk-Shaped Molecules to Coiled-Coil Aggregates with Tunable Helicity[J].Science,1999,284 (5415):785-788.
[9] Ihara H,Sakurai T,Yamada T,et al.Chirality Control of Self-Assembling Organogels from a Lipophilic L-Glutamide Derivative with Metal Chlorides[J].Langmuir,2002,18 (19):7120-7123.
[10] Wang C H,Robertson A,Weiss R G."Latent" Trialkylphosphine and Trialkylphosphine Oxide Organogelators Activated by Br(/o)nsted and Lewis Acids[J].Langmuir,2003,19(4):1036-1046.
[11] Kawano S,Fujita N,Shinkai S.A Coordination Gelator that Shows a Reversible Chromatic Change and Sol-Gel Phase-Transition Behavior upon Oxidative/Reductive Stimuli[J].J Am Chem Soc,2004,126 (28):8592-8593.
[12] Wang C,Zhang D Q,Zhu D B.A Low-Molecular-Mass Gelator with an Electroactive Tetrathiafulvalene Group:Tuning the Gel Formation by Charge-Transfer Interaction and Oxidation[J].J Am Chem Soc,2005,127 (47):16372-16373.
[13] Abdallah D J,Weiss R G.Organogels and Low Molecular Mass Organic Gelators[J].Adv Mater,2000,12(17):1237-1247.
[14] Gronwald O,Snip E,Shinkai S.Gelators for Organic Liquids Based on Self-Assembly:A New Facet of Supramolecular and Combinatorial Chemistry[J].Curr Opin Colloid Interface Sci,2002,7:148-156.
[15] Holtz J H,Asher S A.Polymerized Colloidal Crystal Hydrogel Films as Intelligent Chemical Sensing Materials[J].Nature,1997,389:829-832.
[16] Terech P,Weiss R G.Low Molecular Mass Gelators of Organic Liquids and the Properties of Their Gels[J].Chem Rev,1997,97(8):3133-3159.
[17] Estroff L A,Hamilton A D.Water Gelation by Small Organic Molecules[J].Chem Rev,2004,104(3):1201-1217.
[18] Sangeetha N M,Maitra U.Supramolecular Gels:Functions and Uses[J].Chem Soc Rev,2005,34:821-836.
[19] van Esch J H,Feringa B L.New Functional Materials Based on Self-Assembling Organogels:From Serendipity towards Design[J].Angew Chem Int Ed,2000,39(13):2263-2266.
[20] de Loos M,Feringa B L,van Esch J H.Design and Application of Self-Assembled Low Molecular Weight Hydrogels[J].Eur J Org Chem,2005:3615-3631.
[21] Hirst A R,Smith D K.Two-Component Gel-Phase Materials-Highly Tunable Self-Assembling Systems[J].Chem Eur J,2005,11:5496-5508.
[22] (Z) ini(o) M,Vǒgtle F,Fages F.Cholesterol-Based Gelators[J].Top Curr Chem,2005,256:39-76.
[23] Peng J X,Xia H Y,Fang Y,et al.Water-in-oil Gel Emulsions from a Cholesterol Derivative:Structure and Unusual Properties[J].J Colloid Interface Sci,2009,336:780-785.
[24] Bhattacharya S,Krishnan-Ghosh Y.First Report of Phase Selective Gelation of Oil from Oil/Water Mixtures.Possible Implications toward Containing Oil Spills[J].Chem Commun,2001:185-186.
[25] Suzuki M,Sato T,Shirai H,et al.Powerful Low-Molecular-Weight Gelators Based on L-Valine and L-Isoleucine with Various Terminal Groups[J].New J Chem,2006,30:1184-1191.
[26] Debnath S,Shome A,Das P K,et al.Dipeptide-Based Low-Molecular-Weight Efficient Organogelators and Their Application in Water Purification[J].Chem Eur J,2008,14:6870-6881.
[27] Kar T,Debnath S,Das P K,et al.Organogelation and Hydrogelation of Low-Molecular-Weight Amphiphilic Dipeptides:pH Responsiveness in Phase-Selective Gelation and Dye Remova[J].Langmuir,2009,25(15):8639-8648.
[28] Trivedi D R,Ballabh A,Dastidar P.An Easy to Prepare Organic Salt as a Low Molecular Mass Organic Gelator Capable of Selective Gelation of Oil from Oil/Water Mixtures[J].Chem Mater,2003,15(21):3971-3973.
[29] Trivedi D R,Dastidar P,Ganguly B,et al.Structure-Property Correlation of a New Family of Organogelators Based on Organic Salts and Their Selective Gelation of Oil from Oil/Water Mixtures[J].Chem Eur J,2004,10:5311-5322.
[30] Ballabh A,Trivedi D R,Dastidar P.New Series of Organogelators Derived from a Combinatorial Library of Primary Ammonium Monocarboxylate Salts[J].Chem Mater,2006,18 (16):3795-3800.
[31] Jadhav S R,Vemula P K,John G,et al.Sugar-Derived Phase-Selective Molecular Gelators as Model Solidifiers for Oil Spills[J].Angew Chem Int Ed,2010,49:1-5.
[32] Peng J X,Liu K Q,Fang Y,et al.New Dicholesteryl-Based Gelators:Gelling Ability and Selective Gelation of Organic Solvents from Their Mixtures with Water at Room Temperature[J].New J Chem,2008,32:2218-2224.
[33] Xue M,Gao D,Fang Y.Cholesteryl Derivatives as Phase-Selective Gelators at Room Temperature[J].Tetrahedron,2009,65:3369-3377.
[34] http://www.nytimes.com/2010/05/03/ns/03 spill.html.
[35] Guterman L.News Focus Conservation Biology Conservation Biology Exxon Valdez Turns 20[J].Science,2009,323(5921):1558-1559.
[36] Crone T J,Tolstoy M.Magnitude of the 2010 Gulf of Mexico Oil Leak[J].Science,2010,330:634.
[37] Lessard R R,Demarco G.The Significance of Oil Spill Dispersants[J].Spill Sci Technol Bull,2000,6 (1):59-68.
[38] Yuan J K,Liu X G,Akbulut O,et al.Superwetting Nanowire Membranes for Selective Absorption[J].Nat Nanotechnol,2008,3:332-336.
[39] Stanley W L,Pittman A G.Process for Containing Oil Spills:US,3869385[P],1975-03-04.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%