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以咪唑类离子液体1-癸基-3-甲基咪唑三氟磺酰亚胺盐[C10mim][ NTf2]为萃取剂,研究了其对硝酸溶液中铈(Ⅳ)的萃取行为,分别考察了萃取时间、料液浓度、硝酸浓度、离子液体咪唑环上烷基链长、无机盐浓度和温度对萃取过程的影响.热力学计算表明,萃取过程是自发的放热过程.推测可能的萃取机理是阴离子交换机理.对萃取液进行了反萃考察,在硫酸浓度为1.0 mol/L时,反萃率为85.1%.

参考文献

[1] QIN Chunling,GUAN Xinxin,WANG Ru,et al.An Impregnation Method of CeO2 Contanining Fused Iron Catalyst for Synthetic Ammonia Production[J].Chinese J Appl Chem,1997,14(6):60-62(in Chinese).秦春玲,关新新,王茹,等.新法浸铈氨合成催化剂[J].应用化学,1997,14(6):60-62.
[2] HE Chongheng,ZHU Ming,JIN Guolin,et al.Effects of Cerium Oxide on the Oxidation Activity and Thermal Stability of Pd/Al2O3 Catalysts[J].Chinese J Appl Chem,2004,21 (2):154-158(in Chinese).赫崇衡,朱明,金国林,等.氧化铈对Pd催化剂氧化活性和热稳定性的影响[J].应用化学,2004,21(2):154-158.
[3] Ates A,Gautier A,Leroy B,et al.Mild and Chemoselective Catalytic Deprotection of Ketals and Acetals Using Cerium(Ⅳ) Ammonium Nitrate[J].Tetrahedron,2003,56(43):8989-8999.
[4] Hedrick J B,Sinha S B.Cerium-based Polishing Compounds:Discovery to Manufacture[J].J Alloys Compd,1994,207/208:377-382.
[5] Eguchi K.Ceramic Materials Containing Rare Earth Oxides for Solid Oxide Fuel Cell[J].J Alloys Compd,1997,250:486-491.
[6] Li D Q,Wang Z H,Zeng G F.The Mechanism of Extraction of Ce(Ⅳ) from Sulphuric Acid Solution by Primary Amine N1923[J].J Nud Radio-Chem,1984,6(3):153.
[7] El-Nadi Y A.Influence of Alcohols on the Extraction of Cerium(Ⅳ) by Aliquat336 in Kerosene[J].Int J Miner Process,2007,82:14-22.
[8] Siekierski S.Extraction from Solutions of Perchloric Acid by Tributyl-phosphate Ⅰ:Partition Coefficients for Zirconium,Thorium,Cerium,Promethium and Yttrium[J].J lnorg Nucl Chem,1959,12(1/2):129.
[9] Zhang Z F,Li H F,Guo F J,et al.Synergistic Extraction and Recovery of Cerium(Ⅳ) and Fluorin from Sulfuric Solutions with Cyanex 923 and Di-2-ethylhexyl Phosphoric Acid[J].Sep Purif Technol,2008,63(2):348-352.
[10] Luo X H,Huang X W,Zhu Z W,et al.Synergistic Extraction of Cerium from Sulfuric Acid Medium Using Mixture of 2-Ethylhexyl Phosphonic Acid Mono 2-Ethylhexyl Ester and Di-(2-ethyl hexyl) Phosphoric Acid as Extractant[J].J Rare Earths,2009,27(1):119-122.
[11] Zhao J M,Sun X B,Li W,et al.Interfacial Behavior of DEHEHP and the Kinetics of Cerium(Ⅳ) Extraction in Nitrate Media[J].J Colloid Interface Sci,2006,294(2):429-435.
[12] Zhao J M,Zuo Y,Li D Q,et al.Extraction and Separation of Cerium(Ⅳ) from Nitric Acid Solutions Containing Thorium (Ⅳ) and Rare Earths(Ⅲ) by DEHEHP[J].J Alloys Compd,2004,374(1/2):438-441.
[13] Zuo Y,Liu Y,Chen J,et al.The Separation of Cerium(Ⅳ) from Nitric Acid Solutions Containing Thorium(Ⅳ) and Lanthanides(Ⅲ) Using Pure[C8mim]PF6 as Extracting Phase[J].Ind Eng Chem Res,2008,(47):2349-2355.
[14] Dietz M L,Dzielawa J A.Ion-exchange as a Mode of Cation Transfer into Room-temperature Ionic Liquids Containing Crown Ethers:Implications for the “greenness” of lonic Liquids as Diluents in Liquid-liquid Extraction[J].Chem Commun,2001,20:2124-2125.
[15] Cocalia V A,Jensen M P,Holbrey J D,et al.Identical Extraction Behavior and Coondination of Trivalent or Hexavalent fElement Cations Using Ionic Liquid and Molecular Solvents[J].Dalton Trans,2005,11:1966-1971.
[16] Dietz M L,Stepinski D C.A Ternary Mechanism for the Facilitated Transfer of Metal Ions into Room Temperature Ionic Liquids(RTILs):lmplications for the “greenness” of RTILs as Extraction Solvents[J].Green Chem,2005,7:747-750.
[17] XIA Changbin,HUANG Niandong,HE Xiangzhu.Spectrophotometric Determination of Trace Cerium in Fly As h with Decoloring Reaction of Arsenazo Ⅲ[J].Metallurgical Anal,2004,24(4):49-51 (in Chinese).夏畅斌,黄念东,何湘柱.偶氮胂Ⅲ褪色光度法测定粉煤灰中微量铈[J].冶金分析,2004,24(4):49-51.
[18] WANG Youshao,BAO Borong.Extraction of U(Ⅵ),Th(Ⅳ) and HNO3 in Nitric Acid Medium with N,N,N',N'-Tetrabutyladipicamide[J].Nucl Tech,1998,21 (12):709-713(in Chinese).王友绍,包伯荣.N,N,N',N'-四丁基已二酰胺在硝酸介质中萃取铀、钍及硝酸的研究[J].核技术,1998,21(12):709-713.
[19] Kumar J R,Lee H I,Lee J Y,et al.Comparison of Liquid-liquid Extraction Studies on Platinum(Ⅳ) from Acidic Solutions Using Bis(2,4,4-trimethylpentyl) Monothiophosphinic Acid[J].Sep Purif Technol,2008,63:184-190.
[20] Liu F,Yang Y Z,Lu Y M.Extraction of Germanium by the AOT Microemulsion with N235 System[J].Ind Eng Chem Res,2010,49(20):10005-10008.
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