以对甲苯磺酸为催化剂,利用亲水性NaA分子筛膜蒸汽渗透过程,选择性地将丙烯酸和乙醇酯化反应产物中的水原位分离出反应器,打破反应平衡限制,使反应不断向右进行,反应15 h丙烯酸转化率达到100％.
参考文献
| [1] | Jennings J F,Binning R C.Organic Chemical Reactions Involveing Liberation of Water:US,2956070[P],1960-10-11. |
| [2] | Mcleary E E,Jansen J C,Kapeijn F.Zeolite Based Films,Membranes and Membrane Reactors:Progress and Prospects[J].Micropor Mesopor Mater,2006,90(1/3):198-220. |
| [3] | Sirkar K K,Shanbhag P V,Kovvali A S.Membrane in a Reactor:A Functional Perspective[J].Ind Eng Chem Res,1999,38(10):3715-3737. |
| [4] | Morigami Y,Kondo M,Abe J,et al.The First Lage-scale Pervaporation Plant Using Tubular-type Module with Zeolite NaA Membrane[J].Sep Purif Technol,2001,25(1/3):251-260. |
| [5] | Jafar J J,Budd P M,Hughes R.Enhancement of Esterification Reaction Yield Using Zeolite A Vapour Permeation Membrane[J].J Membr Sci,2002,199(1/2):117-123. |
| [6] | ZHANG Junying.Acrylic Adhesive[M].Beijing:Chemical Industry Press,2006:26-40 (in Chinese).张军营.丙烯酸酯胶黏剂[M].北京:化学工业出版社,2006:26-40. |
| [7] | ZHANG Xiaoming,LV Gaomeng,LEI Qian,et al.Preparation of NaA Zeolite Membranes in Flowing System and the Study of Their PV Separation Performance[J].Membr Sci Technol,2010,30(1):50-53(in Chinese).张小明,吕高孟,雷骞,等.流动体系中NaA分子筛膜的制备及渗透汽化分离性能研究[J].膜科学与技术,2010,30(1):50-53. |
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