根据燃烧理论和苯氯乙酮的化学结构,分析了焚烧法销毁苯氯乙酮的反应机理和影响焚烧销毁效果的主要因素,确定了苯氯乙酮完全燃烧的反应产物与反应方程式.通过焚烧实验研究了一燃室和二燃室温度、单次进料量、进料时间间隔对苯氯乙酮焚烧销毁效果的影响,据此优化确定了利用特种危险化学品焚烧销毁装置焚烧销毁苯氯乙酮的主要作业参数.结果表明,在过剩空气系数为2.5、单次进料量400 g、一燃室温度800℃、二燃室温度1200℃、进料时间间隔3min的条件下,利用实验设备能科学有效焚烧销毁苯氯乙酮.
参考文献
| [1] | CHEN Jisheng.Chemical & Biological Weapons and Equipment for Chemical Defence[M].Beijing:Atomic Energy Press,2003:33-34(in Chinese).陈冀胜.化学、生物武器与防化装备[M].北京:原子能出版社,2003:33-34. |
| [2] | WANG Zhenhua.The Application of Lacrimatory Police Sprayer[J].Police Technol,2010,7:76-78(in Chinese).王振华.警用催泪喷射器的实战应用[J].警察技术,2010,7:76-78. |
| [3] | CHEN Jinzhou,CHEN Haiping,WANG Xuanyu,et al.Effect and Destruction of Chemical Weapons[M].Beijing:Weapons Industry Press,2002:306-310(in Chinese).陈金周,陈海平,王玄玉,等.化学武器效应及销毁[M].北京:兵器工业出版社,2002:306-310. |
| [4] | ZHAO Guohui,CHEN Haiping,DONG Hanchang.Chemical Weapons[M].Beijing:Weapons Industry Press,1991:179-190(in Chinese).赵国辉,陈海平,董汉昌.化学武器[M].北京:兵器工业出版社,1991:179-190. |
| [5] | CUI Keqing.Combustion and Explosion Theory and Technology for Safe Engineering[M].Beijing:China Metrology Publishing House,2005:2-3 (in Chinese).崔克清.安全工程燃烧爆炸理论与技术[M].北京:中国计量出版社,2005:2-3. |
| [6] | SUN Yingjie,ZHAO Youcai.Destruction Technology of Danger Waste[M].Beijing:Chemical Industry Press,2006:116-117(in Chinese).孙英杰,赵由才.危险废物处理技术[M].北京:化学工业出版社,2006:116-117. |
| [7] | WANG Xuanyu,ZHU Xuezheng,ZHANG Hongyuan,et al.Detection and Destruction Theory and Technology for Special Danger Chemical Wastes[M].Shanghai:Shanghai Scientific and Technological Literature Publishing House,2008:32-33(in Chinese).王玄玉,诸雪征,张宏远,等.废旧特种危险化学品检测销毁理论与技术[M].上海:上海科学技术文献出版社,2008:32-33. |
| [8] | CHAI Xiaoli,ZHAO Aihua,ZHAO Youcai.Cumbustion Technology for Solid Waste[M].Beijing:Chemical Industry Press,2006:19-20(in Chinese).柴晓利,赵爱华,赵由才.固体废物焚烧技术[M].北京:化学工业出版社,2006:19-20. |
| [9] | LI Yuanyuan,LU Lidong,LIU Rui,et al.Comparative Study of the Emission Standard of Hazardous Wastes Incineration[J].Environ Sci Manage,2008,33(11):26-31(in Chinese).李媛媛,卢立栋,刘瑞,等.危险废物焚烧烟气排放标准对比研究[J].环境科学与管理,2008,33(11):26-31. |
| [10] | Bossmann S H,Oliveros E.New Evidence against Hydroxyl Radicals as Reactive Intermediates in the Thermal and Photochemically Enhanced Fenton Reactions[J].J Phys Chem A,1998,102(28):5542-5550. |
| [11] | PAN Gongpei.Higher Pyrotechnic Theory[M].Harbin:Harbin Engineering University Press,2005:28-29(in Chinese).潘功配.高等烟火学[M].哈尔滨:哈尔滨工程大学出版社,2005:28-29. |
| [12] | ZHU Ying,JIN Baosheng,WANG Xiaofang,et al.Study on Operational Parameters of Municipal Solid Waste Incinerator by Equilibrium Calculations[J].Boiler Technol,2007,38 (3):62-66 (in Chinese).朱颖,金保升,王小芳,等.平衡计算法研究城市生活垃圾焚烧炉运行参数[J].锅炉技术,2007,38(3):62-66. |
| [13] | BIE Rushan,YANG Lidan,LIU Wentie,et al.Thermodynamic Analysis of the Burning of Organic Waste Liquid in a Fluidized Bed Incinerator[J].J Eng Thermal Energy Power,2001,16(4):437-440(in Chinese).别如山,杨励丹,刘文铁,等.流化床中焚烧有机废液的热力特性分析[J].热能动力工程,2001,16(4):437-440. |
| [14] | LIU Liansheng.Combustion Theory and Technology[M].Beijing:Chemical Industry Press,2008:50-51(in Chinese).刘联胜.燃烧理论与技术[M].北京:化学工业出版社,2008:50-51. |
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