建立了测定润滑剂中10种全氟有机化合物的高效液相色谱-串联质谱(HPLC-MS/MS)分析方法.不同类型的润滑剂样品经溶剂提取后,采用弱阴离子交换柱和石墨化碳柱净化,经C18色谱柱分离后进行HPLC -MS/MS多反应监测模式下的定性及定量分析.10种全氟有机化合物的方法检出限为0.001 ～0.005 mg/kg;在低、中、高的3个添加水平范围内的平均回收率在79.05％～106.26％;日内精密度均小于10％,日间精密度均小于20％.
参考文献
| [1] | ZHAO Chunxia,XU Kaqiu,TANG Congming.Study of Fluorine Carbon Surface-active Agent[J].Sichuan Chem Ind,2004,3(7):13-16(in Chinese).赵春霞,徐卡秋,唐聪明.氟碳表面活性剂研究[J].四川化工,2004,3(7):13-16. |
| [2] | HU Cunli,ZHONG Laifu.Progress of Toxicological Study on PFOS and PFOA[J].Chinese J Ind Med,2006,19(6):354-358(in Chinese).胡存丽,仲来福.全氟辛烷磺酸和全氟辛酸毒理学研究进展[J].中国工业医学杂志,2006,19(6):354-358. |
| [3] | Ericson I,Marti-cid R,Nadal M,et al. Human Exposure to Perfluorinated Chemicals through the Diet:Intake of Perfluorinated Compounds in Foods from the Catalan(Spain) Market[J].J Agric Food Chem,2008,56:1787-1794. |
| [4] | Kuklenyik Z,Needham L L,Calafat A M.Measurement of 18 Perfluorinated Organic Acids and Amides in Human Serum Using On-Line Selid-Phase Extraction[J].Anal Chem,2005,77 (18):6085-6091. |
| [5] | Berger U,Haukas M.Validation of a Screening Method Based on Liquid Chromatography Coupled to High-resolution Mass Spectrometry for Analysis of Perfluoroalkylated Substances in Biota[J].J Chromatogr A,2005,1081:210-217. |
| [6] | Holmster K,Berger U.Tissue Distribution of Perfluorinated Surfactants in Common Guillemot(Uria aalge) from the Baltic Sea[J].Environ Sci Technol,2008,42(16):5879-5884. |
| [7] | Harada K,Nakanishi S,Sasaki K,et al.Particle Size Distribution and Respiratory Deposition Estimates of Airborne Perfluorooctanoate and Perfluorooctanesulfonate in Kyoto Area,Japan[J].Bull Environ Contam Toxicol,2006,76:306-310. |
| [8] | Yamashita N,Kannan K,Taniyasu S,et al.Analysis of Perfluorinated Acids at Parts-Per-Quadrillion Levels in Seawater Using Liquid Chromatography-Tandem Mass Spectrometry[J].Environ Sci Technol,2004,38(21):5522-5528. |
| [9] | Washington J W,Henderson W M,Ellington J J,et al.Analysis of Perfluorinated Carboxylic Acids in Soils:Ⅱ.Optimization of Chromatography and Extraction[J].J Chromatogr A,2008,1181:21-32. |
| [10] | Sinelair E,Kannan K.Mass Loading and Fate of Perfluoroalkyl Surfactants in Wastewater Treatment Plants[J].Environ Sci Technol,2006,40 (5):235-246. |
| [11] | LU Lijun,ZHANG Daihui,HAN Dachuan,et al.Determination of PFOS and PFOA in Cosmetic[C].The Report of the Proceeding in the Quality Testing,2008:64-73 (in Chinese).卢利军,张代辉,韩大川,等.液相色谱-串联质谱法测定化妆品中PFOS类化合物[C].质检专业技术创新高级研修班论文集,2008:64-73. |
| [12] | Begley T H,White K,Honigfort P,et al.Perfluorochemicals:Potential Sources and Migration from Food Packaging[J].Food Addit Contam Part A,2005,22(10):1023-1031. |
| [13] | Marilyn Stadalius,Paul Connolly,Karen L Empereur. A Method for the Low-level (ng· g-1) Determination of Perfluorooctanoate in Paper and Textile by Liquid Chromatography with Tandem Mass Spectrometry[J].J Chromatogr A,2006,1123:10-14. |
| [14] | YU Xuxia,ZHANG Kehe,ZHANG Pangsheng,et al.Determination of PFOS in the Down and Feather Filled Products[J].China Fiber Inspection,2010,(1):61-63 (in Chinese).俞旭霞,张克和,张逢生,等.羽绒制品中全氟辛烷磺酰基化合物(PFOS)的检测[J].中国纤检,2010,1月(下):61-63. |
| [15] | Mawn M P,Mckay R G,Ryan T W,et al.Determination of Extractable Perfluorooctanoic Acid(PFOA) in Water,Sweat Simulant,Saliva Simulant,and Methanol from Textile and Carpet Samples by LC/MS/MS[J].Analyst,2005,130:670-678. |
| [16] | LU Lijun,ZHOU Xiao,HAN Dachuan,et al.Determination of PFOS in the Textile and Leather[J].Text Auxil,2009,26 (10):50-53 (in Chinese).卢利军,周晓,韩大川,等.液相色谱串联质谱法测定纺织品和皮革中PFOS含量[J].印染助剂,2009,26(10):50-53. |
| [17] | Dinglasan-Panlilio M J A,Mabury S A.Significant Residual Fluorinated Alcohols Present in Various Fluorinated Materials[J].Environ Sci Technol,2006,40 (5):1447-1453. |
| [18] | Kannan K,Corsolini S,Falandysz J,et al.Perfluorooctanesulfonate and Related Fluorochemicals in Human Blood from Several Countries[J].Environ Sci Technol,2004,38 (17):4489-4495. |
| [19] | European Union.Directive 2006/122/EC of the European Parliament and of the Council of 12 December 2006 Amending for the 30th time Council Directive 76/769/EEC on the Approximation of the Laws.Regulations and Administrative Provisions of the Member States Relating to Restrictions on the Marketing and Use of Certain Dangerous Substances and Preparations(perfluorooctane sulfonates)[S].Strasbourg:European Union,2006. |
| [20] | Ballesteros-Gómez A,Rubio S,Van Leeuwen S.Tetrahydrofuran-water Extraction,in-lne Clean-up and Selective Liquid Chromatography/Tandem Mass Spectrometry for the Quantitation of Perfluorinated Compounds in Fod at the Low Picogram Per Gran Level[J].J Chromatogr A,2010,1217(24):5913-592l. |
| [21] | Taniyasu S,Kannan K,So M K,et al.Analysis of Fluorotelomer Alcohols,Fluorotelomer Acids,and Short-and Long-chain Perfluorinated Acids in Water and Biota[J].J Chromatogr A,2005,1093:89-97. |
| [22] | Powley C R,Buck R C.Matrix-effect Free Analytical Methods for the Determination of Perfluorinated Carboxylic Acids in Biological Matrices:Proceedings of Fluoros Conference Toronto(Mabury S Ed.)[C].Canada 2005,ANA022. |
| [23] | ZHANG Ping,SHI Yali,CAI Yaqi,et al. Determination of Perfluorinated Compounds in Water Samples by High Performance Liquid Chromatography-Electrospray Tandem Mass Spectrometry[J].Chinese J Anal Chem,2007,35 (7):969-972(in Chinse).张萍,史亚利,蔡亚岐,等.高效液相色谱-串联质谱联用技术测定环境水样中的全氟化合物[J].分析化学,2007,35(7):969-972. |
| [24] | Corcia A D,Marches S,Samperi R.Evaluation of Graphitized Carbon Black as a Selective Adsorbent for Extracting Acidic Organic Compounds from Water[J].J Chromatogr 4,1993,642(1/2):163-174. |
| [25] | Reagen W K,Ellefson M E,Kannan K,et al.Comparison of Extraction and Quantification Methods of Perfluorinated Compounds in Human Plasma,Serum,and Whole Blood[J].Anal Chim Acta,2008,628(2):214-221. |
| [26] | Furdui V I,Crozier P W,Reiner E J,et al.Trace Level Determination of Perfluorinated Compounds in Water by Direct Injection[J].Chemosphere,2008,73:24-30. |
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