发现一种磺酰氯和叔胺反应生成N,N-二取代磺酰胺的反应类型,以1,3-二磺酰氯-4,6-二烷氧基苯和2,4,6-三(二甲氨基甲基)苯酚为原料,二氯甲烷或丙酮作溶剂,合成了4个芳磺酰胺类化合物.通过IR、1H NMR、元素分析和MS谱对其组成结构进行了表征.测试了它们对Ca2+、Pb2+及部分过渡金属等10种金属离子的萃取性能.结果表明,此类化合物对Ca2+有良好的选择性识别作用.
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