用同一方法制备了Ir含量相同而载体TiO2-晶体结构不同的TiO2-载Ir(Ir/TiO2)催化剂,研究了TiO2-晶体结构对Ir/TiO2催化剂对氨氧化的电催化性能的影响,发现具有金红石结构的TiO2-载Ir(Ir/TiO2-R)催化剂对氨氧化的电催化性能远好于具有锐钛矿型结构的TiO2-载Ir(Ir/TiO2-A)催化剂.物理化学和电化学的表征揭示了Ir/TiO2-R催化剂对氨氧化的电催化性能好的可能原因归结于Ir纳米粒子在TiO2-R上的均匀分布.
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