欢迎登录材料期刊网

材料期刊网

高级检索

采用溶胶-凝胶法制备了SiO2水溶胶,并用三甲基甲氧基硅烷进行疏水改性,通过一步浸泡法将改性后SiO2水溶胶修饰到棉花上制备出改性棉花,用接触角测定仪和扫描电子显微镜对制备的改性棉花进行了表征,二次蒸馏水及酸、碱液滴在改性棉花上的接触角均大于150°,表明制备的改性棉花具有超疏水性和耐酸碱性.改性棉花对柴油展示了高达8.3 g/g的饱和吸附量,在5次重复使用中,吸附能力和接触角均可维持在4.0 g/g和大于150°水平.在油水混合物吸附研究中,改性棉花吸水量仅是未改性棉花吸水量的1/45,表明改性棉花对油具有很好的选择性.吸附了柴油后的改性棉花经过简单挤压,即可直接回收吸附的柴油和释放出改性棉花,从而实现了改性棉花的重复使用.

参考文献

[1] Bozeman B.The 2010 BP Gulf of Mexico Oil Spill:Implications for Theory of Organizational Disaster[J].Technol Soc,2011,33 (3/4):244-252.
[2] Leschine T M.Oil Spills and the Social Amplification and Attenuation of Risk[J].Spill Sci Technol Bull,2002,7(1/2):63-73.
[3] Long Y M,Chen Y Z,Yang F,et al.Triphenylamine-Functionalized Magnetic Microparticles as a New Adsorbent coupled with High Performance Liquid Chromatography for the Analysis of Trace Polycyclic Aromatic Hydrocarbons in Aqueous Samples[J].Analyst,2012,137 (11):2716-2722.
[4] Liu Q,Shi J B,Sun J T,et al.Graphene and Graphene Oxide Sheets Supported on Silica as Versatile and High-Performance Adsorbents for Solid-Phase Extraction[J].Angew Chem Int Ed,2011,50(26):5913-5917.
[5] Luo X B,Zhan Y C,Huang Y N,et al.Removal of Water-soluble Acid Dyes from Water Environment Using a Novel Magnetic Molecularly Imprinted Polymer[J].J Hazard Mater,2011,187 (1/3):274-282.
[6] Toyoda M,Inagaki M.Sorption and Recovery of Heavy Oils by Using Exfoliated Graphite[J].Spill Sci Technol Bull,2003,8(5/6):467-474.
[7] Okiel K,El-Sayed M,El-kady M Y.Treatment of Oil-Water Emulsions by Adsorption onto Activated Carbon,Bentonite and Deposited Carbon[J].Egypt J Pet,2011,20(2):9-15.
[8] Wu B,Zhou M H.Sorption of Styrene from Aqueous Solutions with Oil Absorptive Resin[J].J Environ Manage,2009,90(1):217-221.
[9] ZHOU Cong,CHEN Shuo,ZHU Weitao,et al.Preparation an Application of Super-hydrophobic Filter Paper[J].Chinese J Appl Chem,2012,29(3):297-303(in Chinese).周聪,陈硕,朱卫桃,等.超疏水滤纸的制备与应用[J].应用化学,2012,29(3):297-303.
[10] Wang S H,Li M,Lu Q H.Filter Paper with Selective Absorption and Separation of Liquids that Differ in Surface Tension[J].ACS Appl Mater Interfaces,2010,2(3):677-683.
[11] FENG Haifeng,JIANG Zhongyi,LI Duo,et al.Pervaporation Separation of Benzene/Water Mixture by Modified PDMS Membrane[J].ChineseJ Appl Chem,2003,20(10):932-935(in Chinese).冯海锋,姜忠义,李多,等.疏水改性PDMS渗透蒸发膜分离苯/水体系[J].应用化学,2003,20(10):932-935.
[12] Zhu Q,Pan Q M,Liu F T.Facile Removal and Collection of Oils from Water Surfaces Through Superhydrophobic and Superoleophilic Spongs[J].J Phys Chem C,2011,115 (35):17464-17470.
[13] Choi S J,Kwon T H,Im H,etal.A Polydimethylsiloxane (PDMS) Sponge for the Selective Absorption of Oil from Water[J].ACS Appl Mater Interfaces,2011,3(12):4552-4556.
[14] Liang H W,Guan Q F,Chen L F,et al.Macroscopic-Scale Template Synthesis of Robus Carbonaceous Nanofiber Hydrogels and Aerogels and Their Applications[J].A ngew Chem Int Ed,2012,51 (21):1-6.
[15] Arbatan T,Fang X Y,Shen W.Superhydrophobic and Oleophilic Calcium Carbonate Powder as a Selective Oil Sorbent with Potential Use in Oil Spill Clean-ups[J].Chem Eng J,2011,166(2):787-791.
[16] Yidirim Erbil H,Levent Demirel A,Avci Y,et al.Transformation of a Simple Plastic into a Superhydrophobic Surface[J].Science,2003,299(5611):1377-1380.
[17] Hoefnagels H F,Wu D,De With G,et al.Biomimetic Superhydrophobic and Highly Oleophobic Cotton Textiles[J].Langmuir,2007,23 (26):13158-13163.
[18] Gao Q W,Zhu Q,Guo Y L.Formation of Highly Hydrophobic Surfaces on Cotton and Polyester Fabrics Using Silica Sol Nanoparticles and Nonfluorinated Alkylsilane[J].Ind Eng Chem Res,2009,48 (22):9797-9803.
[19] Xu L H,Zhuang W,Xu B,et al.Fabrication of Superhydrophobic Cotton Fabrics by Silica Hydrosol and Hydrophobization[J].Appl Surf Sci,2011,257(13):5491-5498.
[20] ZHUANG Wei,XU Lihui,XU Bi,et al.Application of Modified SiO2 Hydrosol to Superhydrophobic Finish of Cotton Fabrics[J].J Text Res,2011,32(9):89-94(in Chinese).庄伟,徐丽慧,徐壁,等.改性SiO2水溶胶在棉织物超疏水整理中的应用[J].纺织学报,2011,32(9):89-94.
[21] Nystrom D,Lindqvist J,Ostmark E,et al.Superhydrophobic and Self-Cleaning Bio-Fiber Surfaces via ATRP and Subsequent Postfunctionalization[J].ACS Appl Mater Interfaces,2009,1(4):816-823.
[22] Xi W J,Qiao Z M,Zhu C L,et al.The Preparation of Lotus-like Super-Hydrophobic Copper Surfaces by Electroplating[J].Appl Surf Sci,2009,255 (9):4836-4839.
[23] ZHAN Huiying.Measuring Oil Content in Waste Water Using UV-spectrum[J].JGansu Lianhe Univ(Nat Sci),2007,21(1):65-69(in Chinese).展惠英.紫外分光光度法测定废水中油的含量[J].甘肃联合大学学报(自然科学版),2007,21(1):65-69.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%