采用NaOH沉淀法去除胜坨油田T28区污水含有的亚铁离子(Fe2+),使配制的聚合物溶液黏度增加,通过红外光谱仪(IR)、荧光光谱仪及扫描电子显微镜(SEM)对Fe2+的降黏机理进行了分析.结果表明,采用NaOH沉淀法处理Fe2含量为5.9 mg/L的污水,控制pH =9,聚合物溶液的黏度可由19.17 mPa·s提高到92.50 mPa·s.Fe2+使聚合物大分子发生断链,分子间的缔合作用减弱,破坏了分子链间形成的空间网络结构,导致溶液黏度显著降低;当用NaOH处理Fe2+后形成了Fe(OH)2沉淀而析出,同时使聚合物分子链间形成致密的空间网络结构.
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