通过高温固相法合成了Dy3+,Tm3+单掺杂的四硼酸锌(ZnB4O7)磷光体,测定了室温下这2个磷光体经60Co γ-射线辐照后的三维热释光谱.从三维热释光谱可以观察到:这2个磷光体的主发光峰均位于218℃;ZnB4O7:Tm3+磷光体的主热释光峰的发射波长为366、453、475、651和754 nm,ZnB4O7∶Dy3+磷光体的主热释光峰的发射波长为480、573、665和755 nm,分别为稀土离子Tm3+和Dy3+的特征跃迁发射.对于Tm3+掺杂的ZnB4O7磷光体,热释光发射强度较高,在辐射剂量学领域有潜在的应用.利用峰形法,评估了ZnB4 O7∶Tm3磷光体在218℃时发光峰的动力学参数,其陷阱深度E为1.64 eV,频率因子为3.42×1016 s-1,遵循二级动力学.
参考文献
[1] | Mckeever S W S.Thermoluminescence of Solid[M].CAI Gangang,WU Fang,WANG Suoting,Trans.Beijing:Atomic Energy Press,1993:12-19 (in Chinese).McKeever S W S著.固体热释光[M].蔡干钢,吴方,王所亭,译.北京:原子能出版社,1993:12-19. |
[2] | Prokic M.Lithium Borate Solid TL Detectors[J].Radiat Meas,2001,33(4):393-396. |
[3] | Zeng Q,Pei Z,Wang S,et al.Luminescent Properties of Divalent Samarium-Doped Strontium Hexaborate[J].Chem Mater,1999,11 (3):605-611. |
[4] | Anishia S R,Jose M T,Annalakshmi O,et al.Dosimetric Properties of Rare Earth Doped LiCaBO3 Thermoluminescence Phosphors[J].J Lumin,2010,130(l0):1834-1840. |
[5] | Jiang L H,Zhang Y L,Li C Y,et al.Thermoluminescence Studies of LiSrBO3∶ RE3 + (RE =Dy,Tb,Tm and Ce)[J].Appl Radiat Isotopes,2010,68(1):196-200. |
[6] | Liu L Y,Zhang Y L,Hao J Q,et al.Thermoluminescence Studies of Rare Earth Doped Sr2 Mg(BO3)2 Phosphor[J].Mater Leu,2006,60 (5):639-642. |
[7] | LIU Liyan,LI Chengyu,HAO Jingquan,et al.Effect of Single-and Co-dopant on TL of Sr2 Mg(BO3)2 Phosphor[J].Acta Chim Sin,2009,67(11):1201-1204(in Chinese).刘丽艳,李成宇,郝景权,等.单掺杂与共掺杂离子对Sr2Mg(B03)2磷光体热释发光的影响[J].化学学报,2009,67(11):1201-1204. |
[8] | Liu L,Zhang Y,Hao J,et al.Thermoluminescence Studies of LiBa2 Bs O10∶ RE3 + (RE =Dy,Tb and Tm)[J].J Phys Chem Solids,2007,68(9):1745-1748. |
[9] | Jiang L H,Zhang Y L,Li C Y,et al.Thermoluminescence Properties of Ce3 +-Doped LiSr4 (BO3) 3 Phosphor[J].Mater Lett,2007,61 (29):5107-5109. |
[10] | Kar S,Verma S,Bartwal K S.Optical and Thermoluminescence Characteristics of Gamma Irradiated Mn Doped Li2B4O7 Single Crystals[J].Physica B,2010,405(20):4299-4302. |
[11] | Lochab S P,Pandey A,Sahare P D,et al.Nanocrystalline MgB4 O7 ∶ Dy for High dose Measurement of Gamma Radiation[J].Phys Status Solidi A,2007,204(7):2416-2425. |
[12] | Bahl S,Pandey A,Lochab S P,et al.Synthesis and Thermoluminescence Characteristics of Gamma and Proton Irradiated Nanocrystalline MgB4 O7 ∶ Dy,Na[J].J Lumin,2013,134:691-698. |
[13] | MA Weijiang,TANG Qiang,ZHANG Chunxiang,et al.Thermoluminescent Spectra of MgB4 O7 Doped with Mn and Dy[J].Nucl Tech,2010,33:31-34.(in Chinese).马卫江,唐强,张纯祥,等.掺BY与Mn的硼酸镁热释光发光谱[J].核技术,2010,33(1):31-34. |
[14] | CHEN Guoyun,XIN Yong,HUANG Guoqing.Synthesis of the Phosphor MgB4O7∶Tb and Its Thermoluminescence (TL) Characteristics[J].Radia Prot,2008,28(4):202-207(in Chinese).陈国云,辛勇,黄国庆.MgB4 O7∶ Tb磷光体的研制及其热释光(TL)特性[J].辐射防护,2008,28(4):202-207. |
[15] | CHEN Guoynn,TANG Qiang,ZHANG Chunxiang.Thermoluminescence Characteristics of MgB4 O7 Doped with Dy or Tb[J].Chinese JLumin,2006,27(3):313-319(in Chinese).陈国云,唐强,张纯祥.By或Tb掺杂的MgB4O7磷光体的热释光特性[J].发光学报,2006,27(3):313-319. |
[16] | Meijerink A,Blasse G,Glasbeek M.Photoluminescence,Thermoluminescence and EPR Studies on Zn4 B6O13[J].J Phys-condens Matter,1990,2(29):6303-6313. |
[17] | LI Juan,HAO Jingquan,ZHANG Chunxiang,et al.Thermoluminescence Properties of Electron Trapping Material Zn4B6O13∶Dy3+[J].Chem Res Chinese Univ,2005,26:1-4(in Chinese).李娟,郝景权,张纯祥,等.电子俘获材料Zn4B6O13∶By3+的热释光特性研究[J].高等学校化学学报,2005,26(1):14. |
[18] | Li J,Zhang C X,Tang Q,et al.Synthesis,Photoluminescence,Thermoluminescence and Dosimetry Properties of Novel Phosphor Zn(BO2) 2∶ Tb[J].J Phys Chem Solids,2007,68(2):143-147. |
[19] | Chen T,Deng J C,Wang L S,et al.Preparation and Characterization of Nano-zinc Borate by a New Method[J].J Mater Process Tech,2009,209 (8):4076-4079. |
[20] | Kaindl R,Sohr G,Huppertz H.Experimental Determinations and Quantum-chemical Calculations of the Vibrational Spectra of β-ZnB4O7 and β-CaB4O7[J].Spectrochim Acta A,2013,116:408-417. |
[21] | Jia G H,Tu C Y,Li J F,et al.Spectroscopy of G-,dAl3(BO3)4∶Tm3+ Crystal[J].JAppl Phys,2004,96(11):6262-6266. |
[22] | Tsuboi T,Murayama H,Shimamura K.Low Temperature Luminescence ofTm3+ Ions in LiYF4 Crystal[J].JAlloy Compd,2006,408/412:776-779. |
[23] | ZHANG Chunxiang,TANG Qiang,LUO Daling,et al.Thermoluminescent Spectra of MgSO4 Doped with Dy and Mn,P,Cu[J].Acta Phys Sin,2000,49(10):2072-2077 (in Chinese).张纯祥,唐强,罗达玲,等.掺稀土元素Dy和Mn,P,Cu的MgSO4的热释发光光谱[J].物理学报,2000,49(10):2072-2077. |
[24] | Dubovik M,Tolmachev A,Grinyov B,et al.Luminescence and Radiation-induced Defects in Li2 B4 O7∶Eu Single Crystals[J].Semicond Phys Quantum Electron Optoclectron,2000,3(3):420-422. |
[25] | Chen R.Glow Curves with General Order Kinetics[J].J Electrochem Soc,1969,116(9):1254-1257. |
[26] | Kitis G,Furetta C,Prokic M,et al.Kinetic Parameters of Some Tissue Equivalent Thermoluminescence Materials[J].J Phys D Appl Phys,2000,33(11):1252. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%