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介绍了磷酸氧钒锂(α-LiVOPO4、β-LiVOPO4和αⅠ-LiVOPO4)电极材料的结构和电化学性能;综述了现有的LiVOPO4电极材料的合成方法(包括高温固相法,化学还原法,溶胶-凝胶法,溶剂热法,离子交换法等)及其改性研究现状.最后对其未来的发展趋势进行了展望.

参考文献

[1] Yamada A;Chung S C;Hinokuma K.Optimized LiFePO4 for Lithium Battery Cathodes[J].Journal of the Electrochemical Society,2001148(03):224-229.
[2] Huang H;Yin S C;Nazar L F.Approaching Theoretical Capacity of LiFePO4 at Room Temperature at High Rates[J].Electrochemical and Solid-State Letters,20014(10):170-172.
[3] Takahashi M;Tobishima S I;Takei K J.Reaction Behavior of LiFePO4 as a Cathode Material for Rechargeable Lithium Batteries[J].Solid State Ionicis,2002148:283-289.
[4] Hsu K F;Tsaya S Y;Hwang B G.Synthesis and Characterization of Nano-sized LiFePO4 Cathode Materials Prepared by a Citric Aacid-based Sol gel Route[J].Journal of Materials Chemistry,200414:2690-2695.
[5] Gaberscek M;K zmaa M;Jamnika J.Electrochemical Kinetics of Porous,Carbon-decorated LiFePO4 Cathodes:Separation of Wiring Effects from Solid State Diffusion[J].Physical Chemistry Chemical Physics,20079:1815-1820.
[6] Mba J M A;Masquelier C;Suard E.Synthesis and Crystallographic Study of Homeotypic LiVPO4 F and LiVPO4 O[J].CHEMISTRY OF MATERIALS,201224(06):1223-1234.
[7] Li Y Z;Zhou Z;Gao X P.A Novel Sol-gel Method to Synthesize Nanocrystalline LiVPO4F and Its Electrochemical Li Intercalation Performances[J].Journal of Power Sources,2006160(01):633-637.
[8] Zhou F;Zhao X M;Dahn J R.Reactivity of Charged LiVPO4 F with 1 M LiPF6 EC:DEC Electrolyte at High Temperature as Studied by Accelerating Rate Calorimetry[J].ELECTROCHEMISTRY COMMUNICATIONS,200911(03):589-591.
[9] Pan A Q;Liu J;Zhang J G.Nano-structured Li3V2 (PO4) 3/Carbon Composite for High-rate Lithium-ion Batteries[J].ELECTROCHEMISTRY COMMUNICATIONS,201012:1674-1677.
[10] Zhu J F;Yang R S;Wu K L.Synthesis of Li3V2 (PO4)3/Reduced Ggraphene Oxide Cathode Material with High-rate Capability[J].IONICS,201319:577580.
[11] Tang A P;Wang X Y;Liu Z M.Electrochemical Behavior of Li3V2 (PO4)3/C Composite Cathode Material for Lithiumion Batteries[J].Materials Letters,200862(10/11):1646-1648.
[12] Azmi B M;Ishihara T;Nishiguchi H.Vanadyl Phosphates of VOPO4 as a Cathode of Li Ion Rechargeable Batteries[J].Journal of Power Sources,2003119-122:273-277.
[13] Azmi B M;Ishihara T;Nishiguchi H.Cathodic Performance of VOPO4 with Various Crystal Phases for Li Ion Rechargeable Battery[J].Electrochimica Acta,200248(02):165-170.
[14] Ganbicher J;Mercier T L;Chahre Y.Li/β-VOPO4:A New 4V System for Lithium Batteries[J].Journal of the Electrochemical Society,1999146(12):4375-4379.
[15] Hameed A S;Nagarathinam M;Reddy M V.Synthesis and Electrochemical Studies of Layer-structured Metastable α Ⅰ-LiVOPO4[J].Journal of Materials Chemistry,201222:7206-7213.
[16] Saravanan K;Lee H S;Kuezma M.Hollow α-LiVOPO4 Sphere Cathodes for High Energy Li-ion Battery Application[J].Journal of Materials Chemistry,201121:10042-10050.
[17] Kerr T A;Gaubicher J;Nazar L F.Highly Reversible Li Insertion at 4 V in ε-VOPO4/α-LiVOPO4 Cathodes[J].Electrochemical and Solid-State Letters,20003(10):460-462.
[18] 何则强;梁凯;熊利芝.AlPO4包覆对LiVOPO4电化学性能的影响[J].材料导报B,201125(04):61-64.
[19] Song Y;Zavalij P Z;Whittingham M S.ε-VOPO4:Electrochemical Synthesis and Enhanced Cathode Behavior[J].Journal of the Electrochemical Society,2005152(04):721-728.
[20] Lii K H;Li C H;Cheng Y.Hydrothermal Synthesis,Structure,and Magnetic Properties of a New Polymorph of Lithium Vanadyl(Ⅳ) Orthophosphate:β-LiVOPO4[J].Journal of Solid State Chemistry,199195(02):352-359.
[21] Barker J;Saidi M Y;Swoye J L.Electrochemical Properties of Beta-LiVOPO4 Prepared by Carbothermal Reduction[J].Journal of the Electrochemical Society,2004151(06):796-800.
[22] Launay M;Boucher F;Gressier P.A DFT Study of Lithium Battery Materials:Application to the β-VOXO4 Systems (X =P,As,S)[J].Journal of Solid State Chemistry,2003176:556-566.
[23] Dupré N;Wallez G;Gaubicher J.Phase Transition Induced by Lithium Insertion in α Ⅰ-and α Ⅱ-VOPO4[J].Journal of Solid State Chemistry,2004177:2896-2902.
[24] Allen C J;Jia Q Y;Chinnasamy C N.Synthesis,Structure and Electrochemistry of Lithium Vanadium Phosphate Cathode Materials[J].Journal of the Electrochemical Society,2011158(12):1250-1259.
[25] Paul B J;Mathew V;Do G X.Enhanced Storage Capacities in Carbon-coated Triclinic-LiVOPO4 Cathode with Porous Structure for Li-Ion Batteries[J].Electrochem Lett,20121(04):63-65.
[26] Nagamine K;Honma T;Komatsu T.Selective Synthesis of Lithium Ion-conductive β-LiVOPO4 Crystals via Glass-ceramic Processing[J].Journal of the American Ceramic Society,200891(12):3920-3925.
[27] Nagamine K;Honma T;Komatsu T.Fabrication of LiVOPO4/Carbon Composite via Glass-ceramic Processing[J].Material Science and Engineering,201121:1-5.
[28] Tang A P;He Z Q;Shen J.Synthesis and Characterization of LiVOPO4 Cathode Material by Solid State Method[J].Adv Mater Res,2012554-556:436-439.
[29] Dupré N;Gaubicher J;Angenault J.Electrochemical Performance of Different Li-VOPO4 Systems[J].Journal of Power Sources,200197/98:532-534.
[30] Ren M M;Zhou Z;Gao X P.LiVOPO4 Hollow Microspheres:One-pot Hydrothermal Synthesis with Reactants as Selfsacrifice Templates and Lithium Intercalation Performances[J].J Phys Chem C,2008112:13043-13046.
[31] Tang A P;Shen J;Hu Y J.Electrochemical Performance of α-LiVOPO4/Carbon Composite Material Synthesized by Sol-gel Method[J].Journal of the Electrochemical Society,2013161(01):10-13.
[32] Calero D L;Bruque S;Miuela.G.Topotactic Litium Exchange in the Precursor Catalyst VOHPO4· 0.5H2O:The Crystal Structure of LiVOPO4·0.5H2O[J].Journal of Solid State Chemistry,1993103:481-489.
[33] Azmi B M;Ishihara T;Nishiguchi H.LiVOPO4 as a New Cathode Materials for Li-ion Rechargeable Battery[J].Journal of Power Sources,2005146:525-528.
[34] Azmi B M;Ishihara T;Nishiguchi H.Optimized LiVOPO4 for Cathodes in Li-ion Rechargeable Batteries[J].IONICS,200511(5/6):402-405.
[35] Xiong L Zi;He Z Q.A New Rheological Phase Route to Synthesize Nano-LiVOPO4 Cathode Material for Lithium Ion Batteries[J].ACTA PHYSICO-CHIMICA SINICA,201026(03):573-577.
[36] Park J S;Myung S T.LiVOPO4 as a Negative Electrode Material for Rrechargeable Lithium Batteries[A].San Francisco,2013
[37] Dompablo M E A;Rozier P;Morcrette M.Electrochemical Data Transferability within Liy VOXO4 (X =Si,Ge0.5 Si0.5,Ge,Si0.5 As0.5,Si0.5 P0.5,As,P) Polyoxyanionic Compounds[J].CHEMISTRY OF MATERIALS,200719:2411-2422.
[38] Ren M M;Zhou Z;Su L W.LiVOPO4:A Cathode Material for 4 V Lithium Ion Batteries[J].Journal of Power Sources,2008189(01):786-789.
[39] Azmi M B;Man Z;Maitra S.Electrochemical Performance of Cathode LiVOPO4 Doped with Mo and W[J].Transactions of the Indian Ceramic Society,201372(02):108-112.
[40] 熊利芝;刘文萍;蒋剑波.LiMn1-xVxOPO4的制备与电化学性能[A].成都,2012:29.
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