金属有机骨架及其复合材料在分离领域中的应用进展

色谱 , 2016, 34(12): 1176-1185. doi: 10.3724/SP.J.1123.2016.08018

金属有机骨架及其复合材料在分离领域中的应用进展

张晓琼 ^1, , 汪彤 ^2, , 王培怡 ^3, , 姚伟 ^4, , 丁明玉 ^5,

1.北京市劳动保护科学研究所,城市有毒有害易燃易爆危险源控制技术北京市重点实验室,北京100054;清华大学化学系,北京100084

2.北京市劳动保护科学研究所,城市有毒有害易燃易爆危险源控制技术北京市重点实验室,北京100054

3.北京市劳动保护科学研究所,城市有毒有害易燃易爆危险源控制技术北京市重点实验室,北京100054

4.北京市劳动保护科学研究所,城市有毒有害易燃易爆危险源控制技术北京市重点实验室,北京100054

5.清华大学化学系,北京,100084

基金项目: 国家科技支撑计划课题项目(2015BAK16B00) Financial Project of Beijing(.PXM2016_178304_000026,PXM2016_178304_000027) 国家自然科学基金创新团队项目(21621003,北京市科委科研项目(D161100002116001) 国家自然科学基金项目(21575076) 北京市财政项目(PXM2016_178304_000026,PXM2016_178304_000027).National Science and Technology Support Plan(2015BAK16B00) National Natural Science Foundation of Innovation Team Project(21621003) Beijing Municipal Science and Technology Research Project(D161100002116001) National Natural Science Foundation of China(21575076)

关键词：金属有机骨架 , 复合材料 , 分离 , 综述

Application of metal-organic frameworks and their composites in separation

Keywords： metal-organic frameworks (MOFs) , composites , separation , review

金属有机骨架(MOFs)是一类由无机金属离子与有机配体自组装形成的新型有机-无机杂化多孔材料,因具有比表面积超高、结构多样、热稳定性良好、孔道尺寸和性质可调等优势,在分离领域表现出重要的应用价值.然而,采用传统方法制备的MOFs多为粒径在微米或亚微米尺度的晶体,且颗粒形貌不规则,因此限制了MOFs在样品前处理和色谱固定相等领域的应用和发展.构建基于MOFs的复合材料是弥补MOFs应用缺陷的一项有效措施,有望在保留MOFs优越的分离特性的同时,引入基体材料的特定性能.该文简要综述了近年来MOFs及其复合材料在吸附、样品前处理和色谱固定相等分离领域中的应用进展,并对MOFs在分离科学中的应用前景做出展望.

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