利用微波等离子体化学气相沉积法,在Si(100)衬底上制备了碳纳米球薄膜.利用拉曼光谱和场发射扫描电子显微镜研究了薄膜的结构以及表面形貌,表明碳纳米球薄膜是由约2~3μm长、100 nm宽的无定形碳纳米片相互缠绕、交织成球状而构成的.在高真空系统中测量了碳纳米球薄膜的场发射特性,结果表明,碳纳米球薄膜具有良好的场发射特性,阈值电场为3.1 V/μm,当电场增加到10 V/μm时,薄膜的场发射电流密度可达到60.7 mA/cm2.通过三区域电场模型合理地解释了碳纳米球薄膜在低电场、中间电场和高电场区域的场发射特性.
参考文献
[1] | lijima S.Helical microtubules of graphitic carbon[J].Nature,1991,354(6348):56-58. |
[2] | Wong E W,Sheehan P E,Lieber C M.Nanobeam,echanics:elasticity,strength,and toughness of nanorods and ranotubes[J].Science,1997,277(5334):1971-1975. |
[3] | Berber S,Kwon Y K,Tománek D.Unusually high thermal conductivity of carbon nanotubes[J].Phys.Rev.Lett.,2000,84(20):4613-4616. |
[4] | Ge M,Sattler K.Observation of fullerene cones[J].Chem.Phys.Lett.,1994; 220(3-5):192-196. |
[5] | Obraztsov A N,Zakhidov A A,Volkov A P,et al.Non-classical electron field emission from carbon materials[J].Diamond Relat Mater.,2003,12 (3-7):446-449. |
[6] | Li J J,Gu C Z,Wang Q,et al.Field emission from high aspect ratio tubular carbon cones grown on gold wire[J].Appl.Phys.Lett.,2005,87(14):143107(1-3). |
[7] | Wang J Y,Teraji T,Ito T.Fabrication of wrinkled carbon nano-films with excellent field emission characteristics[J].Diamond Relat Mater.,2005,14(11-12):2074-2077. |
[8] | 游玉香,苏艺菁,叶芸,等.碳纳米管场致发射平面背光源[J].液晶与显示,2010,25(4):527-530. |
[9] | Gu G R,Iro T.Field emission properties of nano-structured carbon films with carbon needles deposited on Si using high-power-density microwave-plasma CVD method[J].Diamond Relat Mater.,2008,17(4-5):817-821. |
[10] | Yang X X,Fang G J,Liu N S,et al.Synthesis and field emission properties of carbon nanotubes grown in ethanol flame based on a photoresist-assisted catalyst annealing process[J].Appl Surf Sci.,2009,255(18):7905-7911. |
[11] | Liu P,Liu L,Wei Y,et al.Enhanced field emission from imprinted carbon nanotube arrays[J].Appl.Phys.Lett.,2006,89(7):073101(1-3). |
[12] | Wei Y,Jiang K L,Liu L et al.Vacuum-breakdown-induced needle-shaped ends of multiwalled carbon nanotube yarns and their filed emission applications[J].Nano Lett.,2007,7(12):3792-3797. |
[13] | Bai X,Wang M,Zhang G,et al.Filed emission of individual carbon nanotubes on tungsten tips[J].J.Vac Technol B,2007,25(2):561-565. |
[14] | Zhou G,Kawazoe Y.Application of single-walled carbon nanotube body to unique emitter:a first-principles study[J].Chem.Phys.Lett.,2001,350(5):386-392. |
[15] | Zhang Y B,Lau S P,Huang L,etal.Carbon nanotubes synthesized by biased thermal chemical vapor deposition as an electron source in an x-ray tube[J].Appl.Phys.Lett.,2005,86(12):123115(1-3). |
[16] | Srivastava S K,Vankar V D,Rao D V S,et al.Enhanced field emission characteristics of nitrogen-doped carbon nanotube films grown by microwave plasma enhanced chemical vapor deposition process[J].Thin Solid Films,2006,515(4):1851-1856. |
[17] | Gu G R,Ito T.Enhanced field emission characteristics of thin-Au-coated nano-sheet carbon films[J].Chin.Phys.B,2009,18(10):4547-4551. |
[18] | Gu G R,Li Y A,Ito T.Influence of Ti coatings on field emission characteristics of nano-sheet carbon films[J].Vacuum,2010,85(4):531-534. |
[19] | Zhang Y B,Lau S P,Huang L,et al.Carbon nanotubes grown on cobalt-containing amorphous carbon composite films[J].Diamond Relat.Mater.,2006,15(1):171-175. |
[20] | Wang J J,Zhu M Y,Outlaw R A,et al.Free-standing subnanometer graphite sheets[J].Appl.Phys.Lett.,2004,85(7):1265-1267. |
[21] | Wang J Y,Ito T.Improved field emission characteristics of nano-structured carbon films deposited on polycrystalline CVD diamond[J].Diamond Relat.Mater.,2007,16(2):364-368. |
[22] | Mao D S,Wang X,Liu X H,et al.Effect of annealing on electron field emission properties of hydrogen-free amorphous carbon films[J].Diamond Rel0at Mater,2000,9 (11):1876-1880. |
[23] | 顾广瑞,吴宝嘉,金逢锡,等.石英管型MWPCVD法制备的纳米针状结构碳膜的场发射特性[J].液晶与显示,2007,22(5):535-540. |
[24] | Child C D.Discharge from hot CaO[J].Phys.Rev.,1911,32(5):492-511. |
[25] | Langmuir I.The effect of space charge and initial velocities on the potential distribution and thermionic current between parallel plane electrodes[J].Phys.Rev.,1923,21(4):419-435. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%