欢迎登录材料期刊网

材料期刊网

高级检索

利用磁控溅射设备,Mg0.04Zn0.96O陶瓷靶材,以高纯的氮气与氩气混合气体作为溅射气体,在石英衬底上沉积获得了N掺杂p型Mg0.07Zn0.93O薄膜,薄膜的电阻率为21.47 Ω·cm,载流子浓度为8.38×1016 cm 3,迁移率为3.45 cm2/(V·s).研究了该薄膜的结构与光学性能.实验结果显示,其拉曼光谱中出现了位于272和642 cm 1左右与No相关的振动模.低温光致发光光谱中,可以观察到位于3.201,3.384和3.469 eV的3个发光峰,其中位于3.384 eV的发光峰归因为导带电子到缺陷能级的复合发光,而位于3.469 eV的发光峰归因为受主束缚激子(A0X)的辐射复合,这说明该N掺杂MgZnO薄膜的空穴载流子主要来自No受主的贡献.

参考文献

[1] Bagnall D M;Chen Y F;Zhu Z.Optically pumped lasing of ZnO at room temperature[J].Applied Physics Letters,199770(17):2230-2232.
[2] Tang Z K;Wong G K L;Yu P.Room temperature ultraviolet laser emission from self assembled ZnO microcrystallite thin films[J].Applied Physics Letters,199872(25):3270-3272.
[3] Look D C.Recent advances in ZnO materials and devices[J].MATERIALS SCIENCE & ENGINEERING B,200180(1-3):83-87.
[4] 范希武.宽带Ⅱ-Ⅵ族半导体及其低维度结构的生长和光学性质研究进展[J].发光学报,200223(04):317-329.
[5] 庞海霞;刘长珍;谢安.热处理温度对片状ZnO晶体结构和光学性质的影响[J].液晶与显示,201227(02):158-162.
[6] 苏晶;刘玉荣;莫昌文.ZnO基薄膜晶体管有源层制备技术的研究进展[J].液晶与显示,201328(03):315-322.
[7] 王玉超;吴天准;苏龙兴.高质量ZnO及BeZnO薄膜的发光性质[J].发光学报,201334(08):1035-1039.
[8] 申德振;梅增霞;梁会力.氧化锌基材料、异质结构及光电器件[J].发光学报,201435(01):1-60.
[9] Lien S T;Li H C;Yang Y J.Atmospheric pressure plasma jet annealed ZnO films for MgZnO/ZnO heterojunctions[J].Journal of Physics D:Applied Physics,201346(07):075202.
[10] 赵鹏程;张振中;姚斌.通过交替生长气氛调控N掺杂ZnO薄膜电学特性[J].发光学报,201435(04):399-403.
[11] 魏志鹏;吴春霞;吕有明.Mgx Zn1 xO合金制备及MgZnO/ZnO异质结构的光学性质[J].发光学报,200627(05):831-833.
[12] Ohtomo A;Kawasaki M;T Koida.Mgx Zn1 x O as a Ⅱ-Ⅵ wide gap semiconductor alloy[J].Applied Physics Letters,199872(19):2466-2468.
[13] Choopun S;Vispute R D;Yang W.Realization of band gap above 5.0 eV in metastable cubic-phase Mgx Zn1 xO alloy films[J].Applied Physics Letters,200280(09):1529-1531.
[14] Kong J Y;Li L;Yang Z.Ultraviolet light emissions in MgZnO/ZnO double heterojunction diodes by molecular beam epitaxy[J].Journal of Vacuum Science and Technology B:Microelectronics and Nanometer Structures,201028(03):C3D10-C3D12.
[15] Wei Z P;Yao B;Zhang Z Z.Formation of p type MgZnO by nitrogen doping[J].Applied Physics Letters,200689(10):102104.
[16] Cong C X;Yao B;Xing G Z.Control of structure,conduction behavior,and band gap of Zn1 xMgxO films by nitrogen partial pressure ratio of sputtering gases[J].Applied Physics Letters,200689(26):262108.
[17] Xing G Z;Yao B;Cong C X.Effect of annealing on conductivity behavior of undoped Zinc Oxide prepared by Rf magnetron sputtering[J].Journal of Alloys and Compounds,2008457(1-2):36-41.
[18] 高丽丽;徐莹;张淼.Mg含量对MgZnO薄膜光学性质的影响[J].液晶与显示,201429(03):350-354.
[19] Barnes T M;Olsonandand K;Wolden C A.On the formation and stability of p-type conductivity in nitrogen-doped zinc oxide[J].Applied Physics Letters,200586(11):112112-1121-3.
[20] Decremps F;Pellicer P J;Saitta A M.High pressure Raman spectroscopy study of Wurtzite ZnO[J].Physical Review B:Condensed Matter,200265(09):092101.
[21] Gao L L;Yao B;Liu B.Effects of Mg concentration on solubility and chemical state of N in N-doped MgZ-nO alloy[J].Journal of Chemical Physics,2010133(20):204501.
[22] Wei Z P;Yao B;Wang X H.Photoluminescence and acceptor level state of p-type nitrogen doped MgZnO films[J].Journal of Materials Research,200722(10):2791-2795.
[23] Zhang X T;Liu Y C;Zhi Z Z.Temperature dependence of excitonic luminescence from anocrystalline ZnO films[J].Journal of Lumin,200299:149-154.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%