阐述了形成大双折射液晶化合物的结构因素和含炔键大双折射液晶化合物的主要研究成果.迄今研究发现:二芳基取代的乙炔类(PTP)液晶双折射范围在0.25~0.49;双烷基联苯炔(PPTP)类液晶双折射范围在0.32~0.5;双苯二乙炔类(PTTP、PTDTP、PTPTP)液晶双折射范围在0.35~0.67;三联苯乙炔苯类液晶化合物双折射值约为0.54;含氰基或异硫氰基的苯炔类液晶双折射范围在0.25~0.79;稠环基苯乙炔类液晶双折射在0.36~0.79.含炔键苯类液晶材料具有较大的双折射值和实用价值.
参考文献
[1] | Dabrowski R,Przemyslaw K,Jakub H.High birefringence liquid crystals[J].Crystals,2013,3(3):443-482.,2013. |
[2] | 陈兵,徐寿颐.大光学各向异性液晶材料[J].化学世界,2002(01):43-45,42. |
[3] | 尚洪勇,张建立,刘鑫勤,韩耀华,梁晓.多氟二苯乙炔类负性液晶化合物的合成[J].液晶与显示,2009(05):650-655. |
[4] | 张然,彭增辉,刘永刚,等.高△n低黏度液晶的合成及性能研究[J].液晶与显示,2009,24(6):789-793.Zhang R,Peng Z H,Liu Y G,et al.Study on Synthesis and properties of high △n and low viscosity liquid crystal[J].Chinese Journal of Liquid Crystal and Displays,2009,24(6):789-793.(in Chinese),2009. |
[5] | 吴诗聪.显示及光通讯用高△n液晶[J].现代显示,2001,30(4):49-53.Wu S C.High △n liquid crystal display and optical communication[J].Advanced Display,2001,30(4):49-53.(in Chinese),2001. |
[6] | Gregory J C,Alexander J S,Kenneth J T,et al.Synthesis,transition temperatures,and optical properties of compounds with simple phenyl units linked by double bond,triple bond,ester or propiolate linkages[J].Journal of Materials Chemistry,2000,10(7):1555-1563.,2000. |
[7] | Gray G W,Mosley A.Mesomorphic transition temperatures for the homologous series of 4-n-alkyl-4'-cyanotolanes and other related compounds[J].Mol.Cryst.Liq.Cryst.,1976,37(1):213-231.,1976. |
[8] | 孙亮,张智勇,游红军,戴志群,未本美,宣丽,彭增辉.含氟联苯乙炔液晶化合物的合成及其低温性能[J].液晶与显示,2010(06):784-791. |
[9] | 韩耀华,赵利峰,丁兴立,杜增深,杨月会.2,3,4-三氟苯乙炔类液晶的合成[J].液晶与显示,2010(04):473-476. |
[10] | 刘鑫勤,韩耀华,吕文海,等.2,3,2',3'-四氟二苯乙炔衍生物、其组合物、其制备方法及其用途:中国,CN 1911888A[P].2007-02-14.Liu X Q,Han Y H,Lv H W,et al.2,3,2',3'-PTFE two acetylene derivative,its composition,preparation methodand application:China,CN 1911888A[P].2007-02-14.(in Chinese),2007. |
[11] | 彭增辉,刘永刚,姚丽双,曹召良,穆全全,鲁兴海,胡立发,宣丽.二苯乙炔基异硫氰酸酯的合成与液晶性质研究[J].液晶与显示,2011(04):427-431. |
[12] | Dabrowski R,Dziaduszek J,Ziólek A,et al.Low viscosity,high birefringence liquid crystalline compounds and mixtures[J].Opto-Electron.Rev.,2007,15(1):47-51.,2007. |
[13] | Spadlo A,Da.browski R,Filipowicz M,etal.Synthesis,mesomorphic and optical properties of 4-alkyl-3,5-difluoro4-isothiocyanatotolanes and 4-alkylphenyl-3,5-difluoro-4-isothiocyanatotolanes[C].The 16th Conference on Liquid Crystals (Chemistry,Physics and Applications),Stare Jablonki,Poland 2005:53-58.,2005. |
[14] | Spadlo A,Drzewi(n)ski J,Da.browski R,etal.Synthesis and mesomorphic properties of fluoro-and chloro-substituted isothiocyanatotolanes[C].The 15th Conference on Liquid Crystals,2004:19-25.,2004. |
[15] | Spadlo A,Dabrowski R,Dziaduszek J,et al.Liquid crystalline materials with high birefringence[J].J.Opt.Technol.,2005,72(9):659-661.,2005. |
[16] | Spadlo A,Da.browski R,Filipowicz M,etal.Synthesis,mesomorphic and optic properties of isothiocyanatotolanes[J].Liq.Cryst.,2003,30(2):191-198.,2003. |
[17] | Dabrowski R,Kula P,Herman J.Synthesis of new high birefringence liquid crystals[EB].Military University of Technology,Warsaw,Unpublished Work,2013.,2013. |
[18] | 韩耀华,丰景义,赵利峰,张芳苗,殷科,梁志安.含氟苯乙炔类液晶的合成[C].2012中国平板显示学术会议论文集,2012:426-431. |
[19] | 张芳苗,韩耀华,尚洪勇,张晶梅,钤秀丽.含氟联苯乙炔类液晶的合成[J].液晶与显示,2010(04):510-514. |
[20] | 徐海彬,张宏伟,吴凤,等.具有大的光学各向异性的液晶组合物及液晶显示原件:中国,CN 201210075853[P].2012-03-20.Xu H B,Zhang H W,Wu F,et al.Liquid crystal composition with large optical anisotropy and liquid crystal display:China,CN 201210075853[P].2012-03-20.(in Chinese),2012. |
[21] | Haiqing X,Sebastlan G,Qiong S,et al.High birefringence and large negative dielectric anisotropy phenyl-tolane liquid crystals[J].Liquid Crystals,2007,34(12):1473-1478.,2007. |
[22] | Kula P,Aptacy A,Herman J,et al.The synthesis and properties of fluoro-substituted analogues of 4-butyl-4-【(4-butylphenyl) ethynyl】biphenyls[J].Liq.Cryst.,2013,40(4):482-491.,2013. |
[23] | Gauza S,Zhao Y,Le C T,et al.High figure-of-merit laterally fluorinated biphenyltolane-isothiocyanates[J].Mol.Cryst.Liq.Cryst.,2007,479(1):169-179.,2007. |
[24] | Herman J,Dziaduszek J,Da.browski R,et al.Novel high birefringent isothiocyanates based on quaterphenyl and phenylethynyltolane molecular cores[J].Liq.Cryst.,2013,40(9):1174-1182.,2013. |
[25] | Yasuyuki G,Kisei K.1-(4-alkylphenylethynyl)-4-(alkylphenylethynyl) benzenes,EP 0345013A2[P].1989-05-30.,1989. |
[26] | Sekine C,Fujisawa K,Iwakura K,et al.High birefringence phenylacetylene liquid crystals with low viscosity[J].Mol.Cryst.Liq.Cryst.,2001,346(1):711-718.,2001. |
[27] | Zhang Y M,Wang D,Miao Z C,et al.Novel high birefringence bistolane liquid crystals with lateral fluorosubstituent[J].Liq.Cryst.,2012,39(11):1330-1339.,2012. |
[28] | Liao Y M,Chen H L,Hsu C S,et al.Synthesis and mesomorphic properties of super high birefringence isothiocyanato bistolane liquid crystals[J].Liq.Cryst.,2007,34 (4):507-517.,2007. |
[29] | Gauza S,Wen C H,Wu S T,et al.Super high birefringence isothiocyanto biphenyl-bistolane liquid crystals[J].Jpn.J.Appl.Phys.,2004,43(11):7634-7638.,2004. |
[30] | Wua S T,Neubert M E,Dorschner T A,et al.Wide nematic range alkenyl diphenyldiacetylene liquid crystals[J].Applied Physics Letters,2000,77(7):957-959.,2000. |
[31] | 闻建勋,刘克刚,李衡峰.一种含烯氧侧链的含氟二苯乙炔液晶化合物及其制备方法:中国,CN00111985.0[P].2000-08-23.Wen J X,Liu K G,Li H F.Fluorine containing two phenylacetylene liquid crystal compound and preparation method of olifinic oxygen side chain:China,CN00111985.0[P].2000 08-23.(in chinese),2000. |
[32] | 闻建勋,李衡峰.含氟二苯乙炔类液晶化合物、制备方法及用途:中国,CN00115133.9[P].2000-11-01.Wen J X,Li H F.Fluorine containing two phenylacetylene liquid crystal compound,preparation method and application:China,CN00115133.9[P].2000-11-01.(in Chinese),2000. |
[33] | 闻建勋,刘克刚,李衡峰.含氟二苯乙炔类液晶化合物、制备方法及用途:中国,CN00125736.6[P].2001-05-02.Wen J X,Liu K G,Li H F.Fluorine containing two phenylacetylene liquid crystal compound,preparation method and application:China,CN00125736.6[P].2001-05-02.(in Chinese),2001. |
[34] | 闻建勋,戴修文,蔡良珍.双环己基含氟二苯乙炔类负性液晶、合成方法及应用:中国,CN201210585813.2[P].2013-04-03.Wen J X,Dai X W,Cai L Z.Dicyclohexyl fluorine containing two benzene acetylene negative liquid crystal,synthesis method and Application:China,CN201210585813.2[P].2013-04-03.(in Chinese),2013. |
[35] | Sukhomlinova L,Twieg R,Wu S T,et al.High birefringence fluorinated bistolane liquid crystals[EB].http://outreach.lci.kent.edu/ipp/techjournals/Vo1%2011/sukhomlinova.pdf.,2011. |
[36] | Alexander J S,Kenneth J T,John W G,et al.Synthesis,transition temperatures,and optical properties of various 2,6-disubstituted naphthalenes and related 1-benzothiophenes with butylsulfanyl and cyano or isothiocyanato terminal groups[J].Journal of Materials Chemistry,2000,10 (9):2069-2080.,2000. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%