制备了新型二氧化双环戊二烯环氧树脂(DCPDE)/聚氨酯(PU)互穿聚合物网络(DCPDE/PU IPNs).采用红外光谱法对互穿聚合物网络的结构进行了表征.对不同固化体系的热稳定性、力学性能和涂膜的微观形貌进行了研究.研究结果表明:互穿聚合物网络的形成,提高了二氧化双环戊二烯环氧树脂的弯曲强度、附着力和耐冲击性.固化剂的加入改进了聚氨酯/环氧树脂互穿网络的耐热性能.增韧改性后的环氧树脂比改性之前的环氧树脂呈现明显的两相结构.
参考文献
[1] | BENJAMIN PHILLIPS;CHARLESTON CHARLES W .Polymerizable compositions containing dicyclopentadiene dioxide and polycarboxylic acid and resins prepared therefrom[P].US 2962469,1960-11-29. |
[2] | JIA Qingming,ZHENG Maosheng,SHEN Renjie,CHEN Hongxiang.The glass transition temperature and microstructure of polyurethane/epoxy resin interpenetrating polymer networks nanocomposites[J].科学通报(英文版),2006(03):293-298. |
[3] | Vlad S.;Vlad A.;Oprea S. .Interpenetrating polymer networks based on polyurethane and polysiloxane[J].European Polymer Journal,2002(4):829-835. |
[4] | Mahesh KPO;Alagar M;Jothibasu S .A comparative study on the preparation and characterization of aromatic and aliphatic bismaleimides-modified polyurethane-epoxy interpenetrating polymer network matrices[J].Journal of Applied Polymer Science,2006(6):3592-3602. |
[5] | K. P. O. Mahesh;M. Alagar;S. Ananda Kumar .Mechanical, thermal and morphological behavior of bismaleimide modified polyurethane-epoxy IPN matrices[J].Polymers for advanced technologies,2003(2):137-146. |
[6] | Mu-Shih Lin;Ming-Wei Wang;Lon-An Cheng .Photostabilization of an epoxy resin by forming interpenetrating polymer networks with bisphenol-A diacrylate[J].Polymer Degradation and Stability,1999(3):343-347. |
[7] | Mahesh KPO.;Alagar M. .Preparation and characterization of chain-extended bismaleimide modified polyurethane-epoxy matrices[J].Journal of Applied Polymer Science,2003(10):1562-1568. |
[8] | Yang YS.;Mortaigne B.;Lafontaine E. .CURING STUDY OF DICYCLOPENTADIENE RESIN AND EFFECT OF ELASTOMER ON ITS POLYMER NETWORK[J].Polymer: The International Journal for the Science and Technology of Polymers,1997(5):1121-1130. |
[9] | GING HO HSIUEA;HSIAO FEN WEIB;SING JEN SHIAOB .Chemical modification of dicyclopentadiene based epoxy resins to improve compatibility and thermal propertiesPolymer[J].Degradation and Stability,2001,73(02):309-318. |
[10] | 李绍雄;朱吕民.聚氨酯树脂[M].南京:江苏科学技术出版社,1992:26-29. |
[11] | 孙以实.环氧树脂增韧改性新技术[J].高分子学报,1988(02):101. |
[12] | D.Ratna .Phase separation in liquid rubber modified epoxy mixture. Relationship between curing conditions, morphology and ultimate behavior[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(9):4209-4218. |
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