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以异佛尔酮二异氰酸酯(IPDI)、聚氧化丙烯二醇(N220)等为原料,羟基化的环氧大豆油(HESO)为改性剂,2,2-二羟甲基丙酸(DMPA)为亲水扩链剂制备出阴离子型聚氨酯-丙烯酸酯乳液,并以此乳液配制水性木器涂料.对乳胶粒子的粒径分布进行了测试,探讨了HESO和乙二胺(EDA)含量对乳液、涂膜性能及乳胶粒子粒径的影响.实验发现,HESO含量为4%-6%,EDA含量为0.8%-1.0%时,乳液外观好,涂膜的耐介质性和耐黄变性优异.

参考文献

[1] MOHAMMAD MIZANUR RAHMAN;EUM-YOUNG KIM;Jl YUN KWON et al.Cross-linking reaction of waterborne polyurethane adhesives containing different amount of ionic groups with hexamethoxymethyl melamine[J].International Journal of Adhesion and Adhesives,2007,28(1-2):47-54.
[2] M.M.El-Molla .Synthesis of polyurethane acrylate oligomers as aqueous UV-curable binder for inks of ink jet in textile printing and pigment dyeing[J].Dyes and Pigments,2007(2):371-379.
[3] Rath SK;Ishack AM;Suryavansi UG;Chandrasekhar L;Patri M .Phase morphology and surface properties of moisture cured polyurethane-urea (MCPU) coatings: Effect of catalysts[J].Progress in Organic Coatings: An International Review Journal,2008(4):393-399.
[4] Kim IH.;Shin JS.;Cheong IW.;Kim JI.;Kim JH. .Seeded emulsion polymerization of methyl methacrylate using aqueous polyurethane dispersion: effect of hard segment on grafting efficiency[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2002(1/3):169-176.
[5] Hans-Jurgen Adler;Karsten Jahny;Bettina Vogt-Birnbrich .Polyurethane macromers-new building blcoks for acrylic hybrid emulsions with outstanding performance[J].Progress in Organic Coatings: An International Review Journal,2001(4):251-257.
[6] Sung-Il Lee;Soo-Chang Yu;Youn-Sik Lee .Degradable polyurethanes containing poly(butylene succinate) and poly(ethylene glycol)[J].Polymer Degradation and Stability,2001(1):81-87.
[7] KATARZYNA GORNA;STEFAM POLOWINSKI;SYLWESTER GOGOLEWSKI .Synthesis and characterization of biodegradable poly (ε-caprolactone methane (s).I.effects of the polyol molecular weight,catalyst,and chain extender on the molecular and physical characteristics[J].Journal of POLYMER SCIENCE PART A:POLYMER CHEMISTRY,2002,40(05):156-170.
[8] HU Guowen,SHEN Huifang,FIU Heqing,CHEN Huanqin.Influence of Initiator on Synthesis and Properties of Polyurethane-acrylate Hybrid Emulsion[J].武汉理工大学学报(材料科学版)(英文版),2008(01):41-45.
[9] 胡国文,沈慧芳,杨清峰,陈焕钦.聚氨酯-丙烯酸酯复合乳液的合成与表征[J].华南理工大学学报(自然科学版),2007(06):64-70.
[10] 胡国文,黄洪,傅和青,沈慧芳,陈焕钦.MMA/BA共聚物改性的水性聚氨酯的合成与表征[J].化工学报,2007(07):1851-1856.
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