采用过硫酸铵(APS)为氧化剂,在十二烷基苯磺酸(DBSA)微胶束中用化学氧化法制备纳米棒状和球形聚苯胺;DBSA既起乳化剂也起掺杂剂的作用,并用红外光谱(FT-IR)、紫外光谱(UV-vis)、X-射线衍射(XRD)和扫描电镜(SEM)对合成的聚苯胺进行了表征.不同的聚苯胺后处理方式对制备的聚苯胺/水性环氧树脂复合涂层电导率和聚苯胺分散有明显的影响;研究了这些涂膜的耐盐水性能.该复合涂料的表面电导率最大值为10-5S/cm,其他性能满足使用要求.
参考文献
[1] | 景遐斌,王利祥,王献红,耿延候,王佛松.导电聚苯胺的合成、结构、性能和应用[J].高分子学报,2005(05):655-663. |
[2] | Q.M. Jia;J.B. Li;L.F. Wang .Electrically conductive epoxy resin composites containing polyaniline with different morphologies[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(1/2):356-360. |
[3] | YANG X;ZHAO T;YU Y et al.Synthesis of conductive polyaniline/epoxy resin composites:doping of the interpenetrating network[J].Synthetic Metals,2004,142:57-61. |
[4] | Jang J;Bae J;Lee K .Synthesis and characterization of polyaniline nanorods as curing agent and nanofiller for epoxy matrix composite[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(11):3677-3684. |
[5] | WESSLING B;POSDORFER J .Corrosion prevention with an organic metal (polyaniline):corrosion test results[J].Electrochimica Acta,1999,44:2 139-2 147. |
[6] | Rout TK.;Jha G.;Singh AK.;Bandyopadhyay N.;Mohanty ON. .Development of conducting polyaniline coating: a novel approach to superior corrosion resistance[J].Surface & Coatings Technology,2003(1):16-24. |
[7] | Mirmohseni A.;Oladegaragoze A. .Anti-corrosive properties of polyaniline coating on iron[J].Synthetic Metals,2000(2):105-108. |
[8] | S. Sathiyanarayanan;S. Muthkrishnan;G. Venkatachari .Corrosion protection of steel by polyaniline blended coating[J].Electrochimica Acta,2006(28):6313-6319. |
[9] | Han DX;Chu Y;Yang LK;Liu Y;Lv ZX .Reversed micelle polymerization: a new route for the synthesis of DBSA-polyaniline nanoparticles[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2005(1/3):179-187. |
[10] | Tetsuo Hino;Takumi Namiki;Noriyuki Kuramoto .Synthesis and characterization of novel conducting composites of polyaniline prepared in the presence of sodium dodecylsulfonate and several water soluble polymers[J].Synthetic Metals,2006(21/24):1327-1332. |
[11] | SHREEPATHI S;HOLZE R .Spoetrochemical investigations of soluble polyaniline synthesized via new inverse emulsion pathway[J].Chemistry of Materials,2005,17:4078-4085. |
[12] | Kim BJ.;Han MG.;Im SS.;Oh SG. .Preparation of polyaniline nanoparticles in micellar solutions as polymerization medium[J].Langmuir: The ACS Journal of Surfaces and Colloids,2000(14):5841-5845. |
[13] | HABA Y;SEGAL E;NARKIS M et al.Polyaniline-DBSA/polymet blends prepared via aqueous dispersions[J].Synthetic Metals,1999,106:59-66. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%