随着人们环保意识的提高,镀锌钢板表面无铬钝化处理已成为发展方向.目前无铬钝化主要分为单一钝化和复合钝化,而单一的无铬钝化无法达到铬酸盐钝化效果,相比而言,协同的复合钝化已经取得较为理想的效果.本文综述了镀锌钢板表面无铬钝化中的有机/无机协同钝化的研究现状,主要介绍了有机硅烷协同无机物钝化、有机磷/钼酸盐协同钝化和树脂基无机掺杂钝化三种协同钝化技术和工艺,并展望了无铬钝化技术的发展趋势.
参考文献
| [1] | FERREIRA M G S;DUARTE R G;MONTEMOR M F et al.Silanes and rare earth salts as chromate replacers for pre-treatments on glvanised steel[J].Eleetreehimica Acta,2004,49(17,18):2 927-2 935. |
| [2] | M. F. Montemor;M. G. S. Ferreira .Cerium salt activated nanoparticles as fillers for silane films: Evaluation of the corrosion inhibition performance on galvanised steel substrates[J].Electrochimica Acta,2007(24):6976-6987. |
| [3] | 吴海江,卢锦堂,陈锦虹.热镀锌钢表面硅烷膜耐蚀性能的初步研究[J].腐蚀与防护,2006(01):14-17. |
| [4] | 吴海江,卢锦堂,孔纲.热镀锌钢表面铈盐与硅烷处理后的耐蚀性能[J].腐蚀与防护,2007(07):353-356. |
| [5] | 徐斌,满瑞林,倪网东,胡豫,曹晓燕,颜莎,史燕.镀锌钢板表面硅烷、铈盐复合膜的制备及耐腐蚀性能研究[J].涂料工业,2007(12):46-50. |
| [6] | 徐斌 .镀锌钢板无铬钝化研究[D].长沙:中南大学,2008. |
| [7] | Montemor M.F.;Simoes A.M. .The corrosion performance of organosilane based pre-treatments for coatings on galvanised steel[J].Progress in Organic Coatings: An International Review Journal,2000(1):17-26. |
| [8] | 印仁和,张磊,董晓明,姬学彬,张新胜,曹为民,石新红.钢板电镀锌表面聚苯胺膜硅烷改性的研究[J].金属学报,2007(04):404-408. |
| [9] | CAREY W S;RAAB M .Metal surface treatment composition for treating zinc-coated metal surface,galvanized steel or zinc -aluminum alloy steel comprises phosphomethylated polyamine[P].US 090818 2A1,2006-05-04. |
| [10] | SONG Y K;MANSFELD F .Development of a molybdate-phosphate-zilane-allieate (MPSS) coating process for eleetrngalvanized steel[J].Corrosion Science,2006,48(01):154-164. |
| [11] | 陈旭俊;徐越;马仁川 等.乙酸胺钼酸盐的缓蚀作用与机理[J].中国腐蚀与防护学报,1995,15(04):279-282. |
| [12] | 王济奎;方景礼 .镀锌层表面有机膦合钼聚多酸盐转化膜的研究[J].应用化学,1996,13(05):73-75. |
| [13] | 龚洁;徐端芬;陈旭俊 等.有机钼酸盐MDTA对碳钢的缓蚀作用和机理[J].腐蚀与防护,1999,20(02):62-66. |
| [14] | 郝建军,安成强,刘常升.磷钼杂多酸钝化工艺研究[J].材料保护,2005(07):28-30. |
| [15] | 宫丽,卢燕平.热镀锌钢板钼酸盐钝化膜的改性及耐蚀性[J].钢铁研究学报,2007(03):88-92. |
| [16] | BUXTON D P;RILEY P J .Anti-corrosion treatment for gelvanised steel-using aq.soln.of complex of metal oxoion in conjunction with heteroion,and film forming,acid-tolerant resin[P].WO 14117 2A1,1995-05-26. |
| [17] | HAGER H E;BLOHOWIAK K Y;JONES J H et al.Chiomate-free protective coating[P].EP 0792922,1997-09-03. |
| [18] | 陈锦虹,卢锦堂,许乔瑜,孔纲.镀锌层上有机物无铬钝化涂层的耐蚀性[J].材料保护,2002(08):29-31. |
| [19] | 宫丽,卢燕平.纳米硅溶胶/丙烯酸复合防蚀薄膜的研究[J].材料保护,2005(01):17-19. |
| [20] | 宫丽,卢琳,卢燕平.薄型无铬有机复合涂层钢板耐蚀性的研究[J].材料保护,2008(02):68-71. |
| [21] | RAJENDRAN S;APPARAO B V;PALKNISWAMY N .Synergistic and antogonistic effects existing among polyacrylamide,pheny] phosphonate and Zn2+ on the inhibition of corrosion of mild steel in a neutral aqueous environment[J].Electrochimica Acta,1998,44(02):533-537. |
| [22] | PEULTIER J;ROCCA E;STEINMETZ J .Zinc carboxylating:a new conversion treatment of zinc[J].Corrosian Science,2003,45(08):1 703-1 716. |
| [23] | 李燕,陆柱,吴羡蓉.钨酸盐与苯并三氮唑协同缓蚀机理的探讨[J].华东理工大学学报(自然科学版),2002(01):66-70. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%