考察了采用聚苯乙烯马来酸酐高分子作为分散剂,用三种分散设备制备超细炭黑水基分散体系的研磨过程,然后采用黄原胶对分散体系增稠,测定了增稠后炭黑水基体系的粒径分布、黏度曲线特征和分散稳定性.实验结果表明采用密闭循环式研磨机,炭黑分散体粒径D99可达到2 μm以下.粒径分布主要与采用的研磨介质大小有关.0.4 mm的氧化锆珠比0.8 mm的氧化锆珠能够得到更小的粒径分布.增稠后炭黑水基分散体系体现假塑性和触变性黏度.在高速离心加速度为2 300×g条件下离心7 h,分散体系不发生沉降,具有极好的动力学稳定性.
参考文献
[1] | 田安丽,蔡玉青,房宽峻,张霞.SMA共聚物的合成及对超细颜料水性体系的分散作用[J].高分子材料科学与工程,2005(06):102-105,109. |
[2] | MCCOVICK;TAMMY A .Aqueous pigmented ink formulation containing polymeric-encapsulated pigments binder and smectite clay particle[P].EP 1426422.6,2004-04-09. |
[3] | Zhou Y;Yu D;Wang CL;Chen SL .Effect of ammonium salt of styrene-maleate copolymer on the rheology of quinacridone red pigment dispersion[J].Journal of Dispersion Science and Technology,2004(2):209-215. |
[4] | 房宽峻,付少海,张霞,田安丽,王潮霞.数字喷墨印花技术及其进展[J].印染,2004(24):48-51. |
[5] | SHAOHAI F;KUANJUN F .Preparation of ultrafine pigment dispersion and effect on ζ-potentials[J].Journal of Dispersion Science and Technology,2006,27:971-974. |
[6] | J.G.R BINNER;A.M. McDERMOTT .Rheological characterisation of ammonium polyacrylate dispersed, concentrated alumina suspensions[J].CERAMICS INTERNATIONAL,2006(7):803-810. |
[7] | C.L.Barrie;P.C.Griffiths;R.J.Abbott;I.Grillo;E.Kudryashov;C.Smyth .Rheology of aqueous carbon black dispersions[J].Journal of Colloid and Interface Science,2004(1):210-217. |
[8] | HARDING N E;IELPI L;CLEARY J M.Genetics and biochemistry xanthan gum produciton by xanthomonas campestris,food biothnology microorganisms[M].New york:VCH Publishers,1995 |
[9] | MOORHOUSE R;WALKINSHAW M D;ARNOTT S.Xanthan gum-molecular conformation and interactions,extracellular microbial polysaccharides[A].Washington,DC,1977 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%