利用可逆加成断裂链转移自由基聚合(RAFT)的方法制备了AB型嵌段共聚物PBA-b-PDMAEA,用红外光谱(FT-IR)、核磁氢谱(~1HNMR)和凝胶渗透色谱(GPC)等方法对其结构进行了表征.以PBA-b-PDMAEA为分散剂,分别制备了PBK7、PG7、PB15:3、PR101、PR112、PR254、PY42、PY74和PY154等色浆,利用激光粒度仪(LSPSA)和透射电镜(TEM)对色浆的粒度进行了测定,结果表明PBA-b-PDMAEA作为分散剂,性能优异且通用性好,对于炭黑、无机颜料和有机颜料都适用.
AB type Block Copolymer PBA-b-PDMAEA has been synthesized by the reversible addition-fragmentation chain transfer (RAFT) polymerization. The structure was characterized by means of FTIR, ~1HNMR and GPC. Colorants of PBK7, PG7, PB15:3, PR101, PR112, PR254, PY42, PY74 and PY154 have been respectively prepared using PBA-b-PDMAEA as dispersant. The size of colorants were determined by LSPSA and TEM. The results indicated that PBA-b-PDMAEA was an excellent and universal dispersant, which was suitable for dispersing of carbon black, inorganic and organic pigments.
参考文献
| [1] | 郭宏涛,许钧强,何唯平.新型结构表面活性剂在涂料中的应用[J].涂料工业,2008(06):59-61,66. |
| [2] | SZWARC M.Living polymerization of styrene[J].Nature,1956(178):1168-1175. |
| [3] | FAUST R;KENNEDY J P .Living carbocationic polymerization demonstration of the living polymerization of isobutylene[J].Polymer Bulletin,1986,15(04):317-323. |
| [4] | WEBSTER O W;HERTLER W R;SOGAH D Y .Group-transfer polymerization:a new concept for addition polymerization with organosilicon initiators[J].Journal of the American Chemical Society,1983,105:5706-5708. |
| [5] | Wade A.Braunecker Krzysztof Matyjaszewski .Controlled/living radical polymerization:Features,developments,and perspectives[J].Progress in Polymer Science,2007(1):93-146. |
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