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涂料工业 , 2010, 40(5): 74-79. doi: 10.3969/j.issn.0253-4312.2010.05.021

光引发剂的研究现状及进展

朱俊飞 1, , 龚灵 2, , 樊彬 3, , 李梦炜 4, , 赵倩 5, , 钱超 6, , 陈新志 7,

1.浙江大学化工系,杭州,310027;浙江寿尔福化学有限公司,浙江缙云,321400

2.浙江大学化工系,杭州,310027

3.浙江寿尔福化学有限公司,浙江缙云,321400

4.浙江大学化工系,杭州,310027

5.浙江大学化工系,杭州,310027

6.浙江大学化工系,杭州,310027

7.浙江大学化工系,杭州,310027

基金项目:   浙江省自然科学基全(Y4090045)   国家科技支撑计划(2007BA134B07)   浙江大学第十二期SRTP(3337)   浙江省自然科学基金杰出青年目队(R4090358)   国家自然科学基金(20776127)  

关键词： 紫外光固化 , 芳香重氮盐 , 芳香酮 , 酰基膦氧化物 , 芳香鎓盐 , 双光子

Research Status and Progress of Photoinitiator

紫外光固化技术由于其节能环保等优点被广泛应用于涂料、油墨、胶粘剂等各领域.光引发剂是紫外光固化体系中重要的组成部分,其开发和发展对紫外光固化产品的进步有着重要影响.本文总结了传统光引发剂的分类、主要性能以及合成方法,并指出了光引发剂的发展方向,介绍了各种新型光引发剂的优点和特性以及制备方法.

参考文献

[1] 肖思煜.紫外光固化涂料的发展状况[J].广州化工,2005(05):31-33.
[2] CASATELL M .Energy-cured inks & coatings a bright spot in tough times[J].Ink Maker,2004,82(04):12,14-17.
[3] 刘红波,林峰.紫外光固化材料的研究热点[J].现代涂料与涂装,2008(09):38-41.
[4] 周晓燕,马家举,江棂.紫外光固化涂料的组成及研究[J].化工新型材料,2003(07):20-23.
[5] PAPPAS S P .Photochemical aspects of uv curing[J].Progress in Organic Coatings,1974,2(04):333-347.
[6] HODNETT E M;ROSS W W .Condensations of aldehydes and ke-tones catalyzed by potassium cyanide[J].Proceedings of The Oklahoma Academy of Science,1951,32:69-71.
[7] 吕洪舫;刘宗林;赵爱式 .安息香缩合反应的改进[J].化学试剂,1995,17(06):378.
[8] Hildebrand F;Kuhl S;Pohl M;Vasic-Racki D;Muller M;Wandrey C;Lutz S .The production of (R)-2-hydroxy-1-phenyl-propan-1-one derivatives by benzaldehyde lyase from Pseudomonas fluorescens in a continuously operated membrane reactor[J].Biotechnology and Bioengineering,2007(5):835-843.
[9] Davis JH.;Forrester KJ. .Thiazolium-ion based organic ionic liquids (OILs). Novel OILs which promote the benzoin condensation.[J].Tetrahedron letters: The International Journal for the Rapid Publication of Preliminary Communications in Organic Chemistry,1999(9):1621-1622.
[10] Ken-ichi Iwamoto;Hitomi Kimura;Masaaki Oike .Methylene-bridged bis(benzimidazolium) salt as a highly efficient catalyst for the benzoin reaction in aqueous media[J].Organic & biomolecular chemistry,2008(5):912-915.
[11] 陈强,袁之(氵木禾),吴海霞.安息香的超声波催化合成[J].上海化工,2005(02):19-21.
[12] ETLIS V S;SHOMINA F N .Favorable method for the synthesis of benzoin methyl ether[J].Zhurnal Prikladnoi Khimii(Sankt-Peter-burg Russian Federation),1987,60(08):1897-1899.
[13] DAVIS F A;HAQUE M S;PRZESLAWSKI R M .Asymmetric synthesis of the methyl and benzyl ethers of erythro -α,β-diphenyl -β-hydroxyethanol and erythro-α,β-diphenyl -β-hydroxyethyl amine from (+)-(S)-benzoin[J].Journal of Organic Chemistry,1989,54(08):2021-2024.
[14] 李勋.新型紫外光敏剂安息香双甲醚[J].精细与专用化学品,2001(06):21-21.
[15] 廖劲松,钟荣,唐星华,柯城.1-（对甲氧基-苯乙酮基）-3-甲基咪唑六氟磷酸盐的合成及其性质[J].江西化工,2008(01):41-43.
[16] 陈平,翟玉春.磷钨酸催化合成对甲氧基苯乙酮[J].石油化工,2007(09):919-923.
[17] Katherine J. Schafer;Joel M. Hales;Mihaela Balu;Kevin D. Belfield;Eric W. Van Stryland;David J. Hagan .Two-photon absorption cross-sections of common photoinitiators[J].Journal of Photochemistry and Photobiology, A. Chemistry,2004(2/3):497-502.
[18] PRETOT R;VAN DER SCHAAF P A;KUGLER R et al.Process for preparing aromatic thioether ketones by treatment of aromatic thioethers with acylating agents in the presence of (supported) het-eropoly acids[P].WO,2006034966,2006-04-06.
[19] 薛教钊;王全娣;祁国珍 .硫杂蕙酮类光引发荆的合成[J].华东理工大学学报,1993,19(03):310-315.
[20] BERC C .Process for the preparation of thioxanthones[P].US,20030229233,2003-11-12.
[21] Tasdelen MA;Kiskan B;Yagci Y .Photoinitiated free radical polymerization using benzoxazines as hydrogen donors[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2006(18):1539-1544.
[22] VISCONTI M;CATTANEO M;U BASSI G .Esacure TZT-an effective method of surface curing[J].Polymers Paint Colour Journal,1997,187(4392):25-26.
[23] 谭智勇,谢川.新型光引发剂--酰基膦氧化物[J].信息记录材料,2000(04):35-38.
[24] DECKER C .Photoinitiated crosslinking polymerization[J].Progress in Polymer Science,1996,21(04):565-593.
[25] BECK E;KEIL E;LOKAI M et al.Acylphosphine oxides as photoinitiators for pigmented coatings[J].Modern Paint and Coatings,1998,88(03):36-40.
[26] PRICE L N .Free radical and cationic photoinitiators in ultraviolet light curable coatings[J].Journal of Coatings Technology,1995,67(849):27-34.
[27] 郑耀臣,魏无际.光固化涂料用光引发剂的进展[J].涂料工业,2002(01):31-35.
[28] Kasapoglu F.;Onen A.;Bicak N.;Yagci Y. .Photoinitiated cationic polymerization using a novel phenacyl anilinium salt[J].Polymer: The International Journal for the Science and Technology of Polymers,2002(8):2575-2579.
[29] JAMES V.CRIVELLO;MARCO SANGERMANO .Visible and Long-Wavelength Photoinitiated Cationic Polymerization[J].Journal of Polymer Science, Part A. Polymer Chemistry,2001(3):343-356.
[30] 冯汉保;洪啸吟.涂料化学[M].北京:科学出版社,2005
[31] TIMMONS S F;SAWADA H;WILUNGHOFF S T et al.Cyclo-pentadienyliron complex salt,process for preparing the same and photopolymerizable composition containing the same[P].US,5354784 A,1994-11-10.
[32] COFFIELD T H;CANDEL V;CLOSSON R D .Cyclopentadienyl aromatic sandwich complexes of manganese and iron[J].Journal of the American Chemical Society,1957,79:5826.
[33] NESMEYANOV A N;LESHCHEVA I F;USTYNYUK Y A et al.Nuclear magnetic resonance spectra of arenecyclopentadienyliron compounds[J].Journal of Organometallic Chemistry,1970,22(03):689-696.
[34] KEIPERT S J .Methods for preparation of cyclopenladienyliron(Ⅱ) arenes[P].US,5059701,1991-10-22.
[35] 于美文.全息记录材料及其应用[M].北京:高等教育出版社,1997
[36] 李晓娜,张育川,张默君.可见光光敏体系的研究进展[J].信息记录材料,2001(02):23-30.
[37] 甘志伟,莫健华,黄树槐.绿光激光器引发光敏树脂光固化的研究[J].高分子材料科学与工程,2004(06):207-209.
[38] 肖浦,聂俊.水溶性自由基光引发剂及其研究现状[J].涂料技术与文摘,2008(04):2-5,8.
[39] 吕九琢,徐亚贤,袁光,戴玉华.紫外线固化涂料用光敏引发剂的研究进展[J].石油化工高等学校学报,2001(02):44-49.
[40] KUANG W .Water soluble metal carboxylate photoinitiator and photopo-lymerizable composition[P].WO,2007044184 A1,2007-04-19.
[41] REILLY L W .Water soluble Michler's ketone analogs in combined photoinitiator composition and polymerizable composition[P].US,4576975 A,1986-03-18.
[42] 林教清;王金娣;祁国珍 .新型水性硫杂蕙酮类光引发剂的合成及性质[J].应用化学,1999,16(05):25-28.
[43] 何勇,聂俊.水性光固化材料[J].涂料技术与文摘,2007(06):1-5,62.
[44] 李晓红,马家举.大分子光引发剂的研究进展[J].山西化工,2007(06):22-26.
[45] Angiolini L.;Carlini C.;Corelli E.;Fouassier JP. Morletsavary F.;Caretti D. .PHOTOSENSITIZER/PHOTOINITIATOR INTERACTIONS IN COPOLYMERIC SYSTEMS BEARING SIDE-CHAIN THIOXANTHONE AND ALPHA-MORPHOLINO ACETOPHENONE MOIETIES[J].Polymer: The International Journal for the Science and Technology of Polymers,1995(21):4055-4060.
[46] Wang HY;Wei J;Jiang XS;Yin J .Highly efficient sulfur-containing polymeric photoinitiators bearing side-chain benzophenone and coinitiator amine for photopolymerization[J].Journal of Photochemistry and Photobiology, A. Chemistry,2007(1):106-114.
[47] 钱鹰,黄维,路志锋,孟康,吕昌贵,崔一平.多分枝咔唑衍生物的双光子吸收和双光子荧光性质[J].东南大学学报（英文版）,2008(02):234-237.
[48] Peter Galajda;Pal Ormos .Rotors produced and driven in laser tweezers with reversed direction of rotation[J].Applied physics letters,2002(24):4653-4655.
[49] 郭福全,谢富春,胡治元,余东升.含咔唑基的双光子引发剂光聚合制备微器件[J].化学推进剂与高分子材料,2008(05):40-43.
[50] 陈光需,吴恒富,骆俊山,孔林,吴杰颖.一种D-π-A型咔唑类衍生物的合成[J].合成化学,2008(04):431-433.
[51] 梁英红,钟增培,李娜.具有双光子吸收的咔唑类分子的设计、合成及光谱特性[J].有机化学,2004(12):1577-1582.
[52] 张居舟,崔春梅,周虹屏,杨家祥,吴杰颖,田玉鹏,陶绪堂,蒋民华.两种新型咔唑类双光子光聚合引发剂的合成与光学性质[J].功能材料,2005(10):1624-1628.
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