以环氧树脂为基体通过丙烯酸类单体的接枝聚合改性,而后在侧链中引入甲基丙烯酸缩水甘油酯(GMA),以后乳化的方式制得在光引发剂作用下可以光固化的水性环氧树脂涂料,成功地对中相对分子质量环氧树脂进行改性,制得低VOC的性能优良的产品.并在制备光固化水性环氧乳液的过程中通过正交试验的方法对各个条件不同所引起的漆膜的性能作了分析,并对乳液分布均匀性进行了表征.最后得到综合性能优良的紫外光固化水性环氧树脂涂料.
参考文献
| [1] | 王文君,邹应全.光固化涂料的应用进展[J].信息记录材料,2004(01):27-30. |
| [2] | LUKEY C A.Thermoset coatings[J].Encyclopedia of Materials:Science and Technology,2008:9209-9215. |
| [3] | 何勇,聂俊.水性光固化材料[J].涂料技术与文摘,2007(06):1-5,62. |
| [4] | Chattopadhyay DK;Panda SS;Raju KVSN .Thermal and mechanical properties of epoxy acrylate/methacrylates UV cured coatings[J].Progress in Organic Coatings: An International Review Journal,2005(1):10-19. |
| [5] | PAUL ELIAS.Growth and use of UV/EB technology in the American markets[A].Yokohama,Japan |
| [6] | 金养智.水性光固化涂料[J].涂料工业,2006(06):54-58,61. |
| [7] | Do HS;Park JH;Kim HJ .UV-curing behavior and adhesion performance of polymeric photoinitiators blended with hydrogenated rosin epoxy methacrylate for UV-crosslinkable acrylic pressure sensitive adhesives[J].European Polymer Journal,2008(11):3871-3882. |
| [8] | Joe Miller .Waterborne UV Technologies[J].Industrial Paint & Powder,2004(4):21-26. |
| [9] | Shanq-Tzen Chang;Pqi-Lung Chou .Photo-discoloration of UV-curable acrylic coatings and the underlying wood[J].Polymer Degradation and Stability,1999(3):435-439. |
| [10] | PHOTOINITATION.Photo polymerization and Photocuring[M].New York:Hanser Publishers,1997 |
| [11] | 叶尚仲.我国UV固化涂料发展迅速[J].上海涂料,2005(09):32-33. |
| [12] | UKACHI T;OTAKA T;SHINOHARA N.Radiation curing technology progress and its industrial applications in Japan[A].上海 |
| [13] | GARRATT P G;KLIMESCH K F .Radiation curable waterborne Coatings[J].Polymers Paint Colour Joumal,1994,184(4343):30-32. |
| [14] | 艾照全,周雪松.紫外光固化水性涂料综述[J].涂料技术与文摘,2007(02):1-4. |
| [15] | 叶寒,陈松,李效玉.自乳化型环氧树脂接枝丙烯酸复合乳液的制备[J].涂料工业,2006(11):1-4. |
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