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  4. 活性/可控自由基细乳液聚合的研究及工业化进展

涂料工业 , 2012, 42(5): 75-79. doi: 10.3969/j.issn.0253-4312.2012.05.020

活性/可控自由基细乳液聚合的研究及工业化进展

杨蓓蓓 1, , 王成乐 2, , 杨文龙 3, , 张建安 4, , 吴明元 5, , 吴庆云 6, , 杨建军 7,

1.安徽大学化学化工学院与安徽省绿色高分子材料重点实验室,合肥230039

2.安徽大学化学化工学院与安徽省绿色高分子材料重点实验室,合肥230039

3.安徽大学化学化工学院与安徽省绿色高分子材料重点实验室,合肥230039

4.安徽大学化学化工学院与安徽省绿色高分子材料重点实验室,合肥230039

5.安徽大学化学化工学院与安徽省绿色高分子材料重点实验室,合肥230039

6.安徽大学化学化工学院与安徽省绿色高分子材料重点实验室,合肥230039

7.安徽大学化学化工学院与安徽省绿色高分子材料重点实验室,合肥230039

基金项目:   国家自然科学基金(21044006;51173001)   安徽大学博士科研启动经费项目(33190129)   安徽省自然基金(11040606M59)  

关键词： 活性/可控自由基聚合 , 细乳液 , 工业化

Research and Commercialization Progress of Controlled/ Living Radical Polymerization for Miniemulsion System

综述了活性/可控自由基细乳液聚合方法的研究进展,主要包括稳定自由基细乳液聚合、原子转移自由基细乳液聚合和可逆加成-断裂链转移自由基细乳液聚合3种“活性”/可控自由基聚合方法,介绍了近年来这些领域的工业化进程,并指出了该体系的发展与不足.

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