欢迎登录材料期刊网

材料期刊网

高级检索

高固含量体系相对于传统的固体环氧树脂-聚酰胺体系来说存在着3个不足点:涂膜的柔韧性差、表干时间长以及使用寿命短.本研究以传统的固体环氧树脂-聚酰胺作为参考,讨论了胺类扩链剂对高固含量体系物理机械性能、表干时间以及使用寿命的影响,同时分析了高固含量体系中常用的苯甲醇、单官能度缩水甘油醚和石油树脂对环氧高固含量体系性能的影响.最后,本研究选择N,N' -二甲基-1,6-己二胺作为高固含量体系的扩链剂,其在固化剂中的用量为20%,最终得到的高固含量涂料具备良好的综合性能.

参考文献

[1] 虞兆年.涂料工艺[M].北京:化学工业出版社,1997
[2] 刘国杰.现代涂料工艺新技术[M].北京:中国轻工业出版社,2000
[3] P. A. Serensen;S. Kiil;K. Dam-Johansen .Anticorrosive coatings: a review[J].JCT research,2009(2):135-176.
[4] 王健;刘会成;刘新.防腐蚀涂料与涂装工艺[M].北京:化学工业出版社,2006
[5] Frederick H. Walker;Michael Cook;Gamini Vedage .Dimethyl secondary amine chain extenders: a conceptual approach to in situ generation of advanced epoxy resins for rapid cure, low VOC coatings[J].JCT research,2009(3):283-313.
[6] Frederick A. Pfaff .Growing more ductile epoxies: an essential work of fracture study[J].JCT research,2007(2):151-159.
[7] 李桂林.环氧树脂与环氧涂料[M].北京:化学工业出版社,2003
[8] Rodriguez MT;Gracenea JJ;Garcia SJ;Saura JJ;Suay JJ .Testing the influence of the plasticizers addition on the anticorrosive properties of an epoxy primer by means of electrochemical techniques[J].Progress in Organic Coatings: An International Review Journal,2004(2):123-131.
[9] N.N.Volkova;V.P.Tarasov;L.N.Erofeev .The Kinetics of Thermal Degradation and the Structure of Bisphenol-A Epoxy Binder Modified by Active Plasticizer[J].Polymer science, Series B. Rapid communications reviews,2006(3/4):96-100.
[10] Marsella JA.;Starner WE. .Acceleration of amine/epoxy reactions with N-methyl secondary amines[J].Journal of Polymer Science, Part A. Polymer Chemistry,2000(5):921-930.
[11] LEONARD BUCKLEY;DAVID ROYLANCE .Kinetics of a sterically hindered amine-cured epoxy resin system[J].Polymer Engineering and Science,1982,22(03):154-159.
[12] WISANRAKKIT G;GILLHAM J K .The glass transition temperature (Tg) as an index of chemical conversion for a high-T amine epoxy system chemical and diffusion-controlled reaction kinetics[J].Journal of Applied Polymer Science,1990,41(11-12):2885-2929.
[13] MARC T ARONHIME;JOHN K GILLHAM .Time-temperature transformation (TTT) cure diagram of thermosetting polymeric systems[J].Advances in Polymer Science,1986,78:83-113.
[14] M.T.Rodrfguez;S.J.Garda;R.Cabello;J.J.Suay .Effect of Plasticizer on the Thermal,Mechanical,and Anticorrosion Properties Of an Epoxy Primer[J].JCT research,2005(7):557-564.
[15] Maurice J. Marks;R. Vernon Snelgrove .Effect of Conversion on the Structure-Property Relationships of Amine-Cured Epoxy Thermosets[J].ACS applied materials & interfaces,2009(4):921-926.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%