对钯-氢体系的物理化学性质进行了综合评述. 钯是一种面心立方(fcc)结构的吸氢金属,氢原子溶解在晶格中,占据八面体间隙位(O),形成fcc的子晶格,吸氢时晶格发生等方性膨胀;氢在钯中的扩散路径为O-T-O跃迁,存在反同位素效应;钯氢化物的氢同位素分离因子较大,并受到温度、氢浓度等因数的影响;钯-氢体系的p-c等温线表现出良好的坪台性,Pd-H和Pd-D均存在临界点,尚未确定Pd-T有无临界点;单晶钯-氢反应动力学与不同的晶面有关;钯-氚体系存在氚老化效应.
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