评述了中温固体氧化物燃料电池(中温SOFC)中固体电解质的研究进展,对ZrO2基、 CeO2基、 Bi2O3基和ABO3型的钙钛矿类4种电解质材料的最新进展和今后的发展趋势作了评述.对几种电解质材料的优缺点进行了分析,同时对高温电解质YSZ薄膜化技术也作了简要介绍,因此不难得出,寻求新的、优良的中温SOFC的电解质材料仍然是新世纪推动中温SOFC实用化的关键任务之一,而YSZ薄膜化技术的研究则是研究的另一个重点,且最有可能取得突破.
参考文献
[1] | Raymond George,Klaus Hassmann.燃料电池及其发展前景[J].国际电力,2001(02):24-26. |
[2] | 李瑛;王林山.燃料电池[M].北京:冶金工业出版社,2000 |
[3] | Darja Kek;Peter Panjan;Elke Wanzenberg .Electrical and microstructural investigations of cermet anode/YSZ thin film Systems[J].Journal of the European Ceramic Society,2001(10/11):1861-1865. |
[4] | 刘旭俐,马峻峰,刘文化,徐刚,李海舰,杨琳琳.固体氧化物燃料电池材料的研究进展[J].硅酸盐通报,2001(01):24-29,53. |
[5] | 任引哲,郭崇峰,彭程,张秀英,李五聚,蒋凯.稀土复合氧化物的电导及在SOFC中的应用[J].化学研究,2001(01):59-64. |
[6] | 黄昆原;韩汝琦.固体物理学[M].北京:高等教育出版社,1988:553. |
[7] | 梁广川,陈玉如,吴厚政,刘文西.燃料电池固体氧化物电解质研究进展[J].硅酸盐通报,1999(05):39-45. |
[8] | Badwal SPS. .Stability of solid oxide fuel cell components[J].Solid state ionics,2001(1):39-46. |
[9] | Badwal SPS.;Milosevic D.;Ciacchi FT. .Scandia-zirconia electrolytes for intermediate temperature solid oxide fuel cell operation[J].Solid state ionics,2000(Special Issue SI):91-99. |
[10] | Ji Yuan;Lu Zhe;Zhao Xin;He Tianmin;Su Wenhui;Liu Jiang .Study on the properties of Al_2O_3-doped (ZrO_2)_(0.92)(Y_2O_3)_(0.08) electrolyte[J].Solid state ionics,1999(3/4):277-283. |
[11] | Feighery A.J.;Irvine J.T.S. .Effect of alumina additions upon electrical properties of 8 mol.% yttria-stabilized zirconia[J].Solid state ionics,1999(1/4):209-216. |
[12] | GIBSON I R;Dransfield G P;Irvine J T S .Influence of Yttria concenration upon Electrical Properties and Susceptibility to Ageing of Yttria-stabilised Zirconias[J].Journal of the European Ceramic Society,1998,18:661. |
[13] | Chen Fanglin;Liu Meilin .Preparation of yttria-stabilised zirconia(YSZ)films on La085Sr0 15MnO3(LSM)and LSM-YSZ substrates using an electrophoretic deposition (EPD)process[J].Journal of the European Ceramic Society,2001(21):127. |
[14] | Bai W.;Rudkin RA.;Steele BCH.;Choy KL. .The process, structure and performance of pen cells for the intermediate temperature SOFCs[J].Solid state ionics,1998(Special Issue SI):259-263. |
[15] | Hobein B;Tietz F;Stover D et al.Plused laser deposition of yttria stabilized zirconia for solid oxide fuel cell applicationso[J].Journal of Power Sources,2002,105:239. |
[16] | Srivastava PK.;Duan YY.;Donelson R.;Jiang SP.;Ciacchi FT. Badwal SPS.;Quach T. .ELECTRODE SUPPORTED SOLID OXIDE FUEL CELLS - ELECTROLYTE FILMS PREPARED BY DC MAGNETRON SPUTTERING[J].Solid state ionics,1997(3/4):311-319. |
[17] | Fang Q.;Zhang JY. .Preparation of Ce1-xGdxO2-0.5x thin films by UV assisted sol-gel method[J].Surface & Coatings Technology,2002(0):100-104. |
[18] | Garcia G;Figueras A;Casado J et al.Yttria-stabilized zirconia obtained by MOCVD applications[J].Thin Solid Films,1998,317:241. |
[19] | Choy K;Bai W;Charojrochkul S et al.The development of intermediate-temperature solid oxide fuel cells for the next millennium[J].Journal of Power Sources,1998,71:361. |
[20] | Selmar de Souza;Steven J Visco;Lutgard C De Jonghe .Thin-film solid oxide fuel cell with high performance at low-temperature[J].Solid State Ionics,1997,98:57. |
[21] | Hobein B;Tietz F;Stover D et al.DC Sputtering of yttria-stabilized zirconia films for solid oxide fuel cell applications[J].Journal of the European Ceramic Society,2001,21:1843. |
[22] | Sung Pil Yoon;Jonghee Han;Suk Woo Nam et al.Perfomance of anode-supported solid oxide fuel cell with La085Sr0 15MnO3 cathode modified by sol-gel coating technique[J].Journal of Power Sources,2002,106:160. |
[23] | Wang H B;Xia C R;Meng G Y;Peng D K .Deposition and characterization of YSZ thin films by aerosol-assisted CVD[J].Materials Letters,2000,44:23. |
[24] | Ken-ichi Itoh;Osamu Matsumoto .Deposition process of metal oxide thin films by means of plasma CVD with β-diketonates as precursors[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,1999(1):29-33. |
[25] | Zhitomirsky I.;Petric A. .Electrolytic deposition of zirconia and zirconia organoceramic composites[J].Materials Letters,2000(1):1-6. |
[26] | 蒋凯;张秀英;郭崇峰 .固体氧化物燃料电池中的电解质[J].稀有金属,2001,25(02):121. |
[27] | Wang Fengyun;ChenSongying;Wang Qin .Research of Ce085Gd0 1Mg0.05O1.9 and Ce0.9Gd0.1O1.95 electrolyte[Z]. |
[28] | 吕喆,黄喜强,刘巍,贺天民,刘志国,刘江,苏文辉.碱土金属双掺杂的Ce0.9Ca0.1-xSrxO1.9中温固体电解质的性能与应用[J].中国稀土学报,2000(04):313-316. |
[29] | 吕喆,刘江,黄喜强,刘志国,刘巍,贺天民,苏文辉.SrCe0.90Gd0.10O3固体电解质燃料电池性能研究[J].高等学校化学学报,2001(04):630-633. |
[30] | 马桂林,贾定先,仇立干.BaCe0.9Y0.1O3-α固体电解质燃料电池性能[J].化学学报,2000(11):1340-1344. |
[31] | 刘志国,黄喜强,刘巍,吕?,纪媛,裴力,贺天民,苏文辉.PrGa1-xMgxO3作为燃料电池固体电解质的研究[J].高等学校化学学报,2001(08):1283-1285. |
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