合成了顺丁烯二酸酐改性双酚A环氧丙烯酸酯水性光固化树脂和Eu0.6Gd0.4(TTA)3Pen稀土配合物荧光粉, 通过复配, 制备了发红色荧光的稀土配合物水性荧光防伪油墨, 并研究了配合物含量对荧光强度的影响. 结果表明, 涂膜的荧光强度随Eu0.6Gd0.4(TTA)3Phen含量的增加而增强, 发光强度与铕含量不成线性关系. 当铕的含量达到0.14%, 涂膜在紫外光 (365 nm)照射下, 能发出明亮的红色荧光.
参考文献
[1] | 李文连.稀土有机配合物发光研究的新进展[J].化学通报(印刷版),1991(08):1. |
[2] | 林秦,符连社,梁玉军,郑佑轩,林君,张洪杰.新型稀土芳香羧酸类配合物的合成及其光致和电致发光性质[J].中国稀土学报,2003(01):19-22. |
[3] | 刘天府,汪中明,周志芬,林华宽,朱守荣,徐猛,陈荣悌.稀土离子与2,9-二甲基-1,10-菲罗啉的α-氨甲基吡啶衍生物的二元配合物的稳定性研究[J].中国稀土学报,2003(05):495-498. |
[4] | 李建科.聚合物发光材料[J].高等学校化学学报,1996(12):1952. |
[5] | 汪联辉;章文贡.含稀土聚合物的进展[J].高分子通报,1995(02):104. |
[6] | Lu Hong;Li Gaofen;Fang Shibi et al.Fluorescence properties of polymer-rare earth ion complexes.Ⅱ.Poly(acrylic acide-co-acrylamide)-rare-earth ion complexes[J].Journal of Applied Polymer Science,1990,30(06):1389. |
[7] | Xu Wenying;Wang Yuesheng;Zheng Dagang et al.Synthesis and characterization of polymers containing rare earth metals[J].Journal of Macromolecular Science:Chemistry,1988,A25:1397. |
[8] | Xu Wenying;Pei Zhonghua;Zheng Dagang et al.Fluorescence properties of europium and terbium triundecylenate-containing polymers and solutions[J].Journal of Macromolecular Science:Chemistry,1990,A27(9-11):1109. |
[9] | Banks E;Okamoto Y;Ueba Y .Synthesis and characterization of rare earth metal-containing polymers-1. Fluorescence properties of ionomers containing Dy+3,Er+3,Eu+3,andSm+3[J].Journal of Applied Polymer Science,1980,25(03):359. |
[10] | Du Chenxia;Xu Yan;MA Lin et al.Synthesis and fluorescent properties of europium-polymer complexes containing naphthoate ligand[J].Journal of Alloys and Compounds,1998,265:81. |
[11] | 赵莹,杨丽敏,张莉,周维金,吴瑾光,鲍春丽,王笃金,徐端夫.含三价铕荧光络合物与聚甲基丙烯酸甲酯的发光材料[J].高分子学报,2000(04):393-396. |
[12] | 王则民,徐祖辉,傅楚瑾,曹锦荣,陈志荣.耐候光转换无滴农膜的转光效应研究[J].上海师范大学学报(自然科学版),2000(02):53-58. |
[13] | 田君,尹敬群.稀土紫外荧光防伪油墨的制备[J].精细化工,1999(02):31-32. |
[14] | Zhang Renjie;Liu Hongguo;Yang Kongzhang et al.Fabrication and fluorescence characterization of the LB films of luminous rare earth complexes Eu(TTA)3Phen and Sm(TTA)3Phen[J].Thin Solid Films,1997,295:228. |
[15] | Zhang Renjie;Liu Hongguo;Yang Kongzhang et al.Influence of several compounds on the fluorescence of rare earth complexes Eu(TTA)3Phen and Sm(TTA)3Phen in LB films[J].Thin Solid Films,1997,302:223. |
[16] | 罗云婷,赵爱华,吴承佩.紫外光固化掺铕(Eu3+)聚氨酯膜的制备与性能[J].稀土,2001(01):9-12. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%