由Ti-Cr基合金的二元相图出发,综述了Ti-Cr基合金的储氢性能,并重点介绍了多元合金化对其储氢性能的影响.合金TiCr1.8中存在BCC和Laves相,吸氢量随温度的升高而有所下降.Zr取代合金中的部分Ti使合金的晶胞参数增大,同时合金的吸氢量增加,平台压力降低,平台区变短.V取代合金中的部分Cr也使合金的吸氢量增加,吸放氢过程中的滞后效应增加.Fe,Mn,Cu,Ni对合金的性能也有一定影响.相同的退火时间下,TiCrV合金的吸氢量随退火温度的升高而增加.
参考文献
[1] | JOHNSON J R .Reaction of hydrogen with the high temperature (C14) form of TiCr2[J].Journal of the Less-Common Metals,1980,73:345. |
[2] | Johnson JR;Reilly JJ;Reidinger F .On the existence of F.C.C. TiCr1.8H5.3[J].Journal of the Less-Common Metals,1982,88:107. |
[3] | Cho SW.;Nakamura Y.;Enoki H.;Akiba E. .Hydrogen isotope effects in Ti1.0Mn0.9V1.1 and Ti1.0Cr1.5V1.7 alloys[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):253-260. |
[4] | Bououdina M.;Akiba E.;Enoki H. .The investigation of the Zr1-yTiy(Cr1-xNix)(2)-H-2 system 0.0 <= y <= 1.0 and 0.0 <= x <= 1.0 phase composition analysis and thermodynamic properties[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(2):290-300. |
[5] | Boschung E.;Chartouni D.;Schlapbach L.;Zuttel A. .Hydriding properties of the Zr(Cr0.5Ni0.5)(alpha) (1.75 <=alpha <= 3.5) alloy system[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):294-298. |
[6] | Akika E;Iba H .Hydrogen absorption by Laves phase related BCC solid solution[J].Intermetallics,1998,6:461. |
[7] | He Yuding;Qu Xuanhui;Huang Boyun et al.Microstructure and mechanical property of Laves phase TiCr2-based alloys[J].The Chinese Journal of Nonferrous Metals,1998,8(04):115. |
[8] | Chen K C;Allen S M;Livingston J D .Factors affecting the room-temperature mechanical properties of TiCr2 based Lavesphase alloys[J].Materials Science and Engineering,1998,A242:162. |
[9] | Yukawa H.;Morinaga M.;Nakatsuka K. .Design of hydrogen storage alloys in view of chemical bond between atoms[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2000(1/2):75-80. |
[10] | Morinaga M;Yukawa H;Nakatsuka K et al.Roles of constituent and design of hydrogen storage alloys[J].Journal of Alloys and Compounds,2002,330-332:20. |
[11] | Klyamkin S N;Kovriga A Y;Verbetsky V N .Effect of substitution on F. C.C. and B. C.C. hydride phase formation in TiCr2-H2 system[J].International Journal of Hydrogen Energy,1999,24:149. |
[12] | Beeri O.;Gavra Z.;Johnson JR.;Mintz MH.;Cohen D. .High-pressure studies of the TiCr1.8-H-2 system Statistical thermodynamics above the critical temperature[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):113-120. |
[13] | Park J G;Jang H Y;Han S C et al.The thermodynamics properties of Ti-Zr-Cr-Mn Laves phase alloys[J].Journal of Alloys and Compounds,2001,325:293. |
[14] | Lee J Y;Kim J H;Park S I et al.Phase equilibrium of the TiCr-V ternary system in the non-burning β-Ti alloy region[J].Journal of Alloys and Compounds,1999,291:229. |
[15] | Santos D S D;Bououdina M;Fruchart D .Structure and thermodynamics properties of the pseudo-binary TiCr2_x Vx compounds with 0.0≤x≤0.2[J].Journal of Alloys and Compounds,2002,340:101. |
[16] | Osumi Y;Suzuki H;Kato A .Hydrogen storage properties of Ti1+xCr2_yMny alloys[J].Journal of the Less-Common Metals,1983,89:257. |
[17] | BeekJ A V;Kodentsov A A;Loo F J J V .Phase equilibrium in the Ni-Cr-Ti system at 850 ℃[J].Journal of Alloys and Compounds,1998,270:218. |
[18] | 陈异,蒋利军,黄倬,詹锋,秦光荣,尉秀英,苑鹏.低放氢压的Ti-Mn基Laves相贮氢合金[J].稀有金属,2001(03):215-218. |
[19] | 马建新,潘洪革,田清华,朱云峰,李寿权,陈长聘.热处理温度对AB5型MlNi 3.60C0 0.85Mn 0.40Al 0.15 贮氢电极合金微结构和电化学性能的影响[J].中国有色金属学报,2001(04):587-592. |
[20] | Wakao S;Sawa H .Effects of partial substitution and anodic oxidation treatment of Zr-V-Ni alloys on electrochemical properties[J].Journal of the Less-Common Metals,1991,172-174:1219. |
[21] | MORIWAKI Y;Gamo T;Iwaki T .Control of hydrogen equilibrium pressure for C14-type Laves phase aloys[J].Journal of the Less-Common Metals,1991,172-174:1028. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%