根据近年来钯基氢净化材料的研究状况, 综述了添加稀土元素对钯基氢净化材料的影响. 重点从稀土元素对钯吸氢后形成α相向β相的转变、透氢性能、力学性能以及有害杂质污染的抵抗能力等4个方面进行了阐述. 说明添加稀土元素, 特别是Y可明显改善钯膜的性能, 为低廉、高效获得高纯氢提供了良好的途径.
参考文献
[1] | Hunter J B .A new hydrogen purification process[J].Platinum Metals Review,1960,4:130. |
[2] | 何纯孝.贵金属合金相图[M].北京:冶金工业出版社,1983 |
[3] | Thomson J R .The constitution of cerium-palladium alloys containing 50-100% palladium[J].Journal of the Less-Common Metals,1967,13:307. |
[4] | 何纯孝;周月华;王文娜.贵金属合金相图[M].北京:冶金工业出版社,1993 |
[5] | Rider R E;Gschneider Jr K A;Mcmasters O D .Gold-rich rare-earth-gold solid solutions[J].Transactions of the Metallurgical Society of AIME,1965,233:1488. |
[6] | Doyle M L;Harris I R .Palladium-rare earth alloys[J].Platinum Metals Review,1988,32:134. |
[7] | GSCHNEIDER JR K A;Mcmasters O D;Alexander D G et al.Crystallography of the silver-rich rare-earth-silver intermetallic compounds[J].Acta Crystallographica,1970,B26:1224. |
[8] | 陈藜莉;张康候 .Nd-Pd(Nd≤50%)二元相图[J].金属学报,1991,27(01):B017. |
[9] | 文飞,宁远涛,赵怀志.微量稀土元素对钯的组织结构之影响[J].贵金属,1992(03):10-16,41. |
[10] | Worsham Jr J E;Wilkinson M K;Shull C G .Neutron-diffraction observations on the palladium-hydrogen and palladium-deuterium systems[J].Journal of Physics and Chemistry of Solids,1957,3:303. |
[11] | Alefeld G;Volk J.Hydrogen in Metals,Topics in Applied Physics[M].New York: Springer-Verlag,1978:135. |
[12] | Tae-Hyum Yang;Su-ll Pyum;Young-Gi Yoon .Hydrogen transport through Pd electrode current transient analysis[J].Electrochimica Acta,1997,42:1701. |
[13] | Hunter J B .Silver-palladium film for separation and purification of hydrogen[P].US:2773561,1956. |
[14] | Wise M L H;Farr J P G;Harris I R .X-ray studies of the α/β miscibility gaps of some palladium solid solution-hydrogen systems[J].Journal of the Less-Common Metals,1975,41:115. |
[15] | Sakamoto Y;Chen F L;Furukawa M et al.Permeability and diffusivity of hydrogen in palladium-rich Pd-Y(Gd)-Ag ternary alloys[J].Journal of Alloys and Compounds,1992,185:191. |
[16] | Harris I R;Norman M .Observations on the lattice spacings of some α Pd-X solid solutions and some Pd3X phases[J].Journal of THE LESS-COMMON METALS,1970,22:127. |
[17] | Hughes D T;Harris I R .Hydrogen diffusion membranes based on some palladium-rare-earth solid-solution alloys[J].Zeitschrift für Physikalische Chemie,1979,117:185. |
[18] | Wileman R;Harris I R .A proposed method of hydrogen isotope separation using palladium alloy membranes[J].Journal of the Less-Common Metals,1983,89:407. |
[19] | Fort D;Farr J P G;Harris I R .A comparison of palladium-silver and palladium-yttrium alloys as hydrogen separation membranes[J].Journal of the Less-Common Metals,1975,39:293. |
[20] | 夏长荣,郭晓霞,汪学军,陈初生,彭定坤,孟广耀.Pd-Y合金膜的MOCVD研制[J].高等学校化学学报,2000(01):14-17. |
[21] | 李银娥;李土江 .氢气净化用PdY合金的热处理工艺及其透氢性能[J].中国有色金属学报,1998,8(zk):250. |
[22] | Sakamoto Y;Chen F L;Kinari Y .Permeability and diffusivity of hydrogen through Pd-Y-In(Sn,Pb) alloy membranes[J].Journal of Alloys and Compounds,1994,205:205. |
[23] | Wise E M.Palladium Recovery,Properties and Uses[M].New York:Academic Press,1968 |
[24] | 宁远涛,文飞.稀土元素对钯的力学性能的影响[J].贵金属,1994(01):32-42. |
[25] | Doyle M L;Harris I R .Alloying and strengthening effects of rare earths in palladium[J].Platinum Metals Review,1988,32:130. |
[26] | Hirst M J R;Wised L H;Fort J P G Farr.[J].Journal of the Less-Common Metals:193. |
[27] | Hughes D T;Harris I R .The influence of lattice order on the thermal expansion and magnetic susceptibility behaviour of some palladium-cerium solid solution alloys[J].Journal of the Less-Common Metals,1980,76:119. |
[28] | Hughes D T;Evans J;Harris I R .The influence of order on hydrogen diffusion in the solid solution alloys Pd-5.75%Ce and Pd-8%Y[J].Journal of the Less-Common Metals,1980,74:255. |
[29] | Shu J;Grandjean B P A;Ghali E et al.Simultaneous deposition of Pd and Ag on porous stainless steel by electroless plating[J].Journal of Membrane Science,1993,77:181. |
[30] | Amano M;Komaki M;Nishimura C .Hydrogen permeation characteristics of palladium-plated V-Ni alloy membranes[J].Journal of the Less-Common Metals,1991,173:727. |
[31] | Amano M;Nishimura C;Komaki M .Effects of high concentration CO and CO2 on hydrogen permeation through the palladium membrane[J].Materials Transactions,1990,31:404. |
[32] | Sakamoto F;Kinari Y;Chen F L et al.Hydrogen permeation through palladium alloy membranes in mixture gases of 10% nitrogen and ammonia in the hydrogen[J].International Journal of Hydrogen Energy,1997,22(04):369. |
[33] | Fort D;Harris I R .The physical properties of some palladium alloy hydrogen diffusion membrane material[J].Journal of the Less-Common Metals,1975,41:313. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%