作为重要的催化材料, 铑催化剂具有反应条件温和、反应选择性高等特点, 已广泛应用于石油化工、医药化工、精细化工等领域. 综述了铑作为加氢、氢甲酰化、羰基合成均相催化剂的工业应用情况的同时, 还介绍了铑催化剂在新兴的不对称催化领域的选择催化性能和工业应用. 指出了影响均相和手性铑催化剂工业化的因素, 并对未来铑催化剂的工业应用进行了展望.
参考文献
| [1] | 野依良治.不对称催化：科学与机遇[J].化学通报,2002(06):363-372. |
| [2] | Osborn J A;Jardine F H;Young F H.Synthesis of some rhodium-complexes[J].Journal of the Chemical Society A:Inorganic Physical Theoretical,1966:1711. |
| [3] | 蒋麟忠.催化氢化在有机合成中的应用[M].北京:化学工业出版社,1987:388. |
| [4] | 朱兆璋;李骥联 .天然杀虫素Avermectin的结构改造产物一伊维菌素(Ivermectin)[J].农药译丛,1995,17:21. |
| [5] | 王胜国,房德仁,李海洋.烯烃氢甲酰化反应的催化技术进展[J].化工时刊,2000(03):6-11. |
| [6] | 王锦惠;王蕴林;刘光宏.羰基合成[M].北京:化学工业出版社,1987:97. |
| [7] | 蔡启瑞;彭少逸.碳一化学中的催化作用[M].北京:化学工业出版社,1995:473. |
| [8] | 中石化与BP合建世界级规模醋酸合资企业[J].甲醛与甲醇,2005,5:36. |
| [9] | 蔡启瑞;彭少逸.碳一化学中的催化作用[M].北京:化学工业出版社,1995:491. |
| [10] | 王胜国,于国清,王世文.不对称催化及其在精细化工中的应用[J].工业催化,2000(04):9-16. |
| [11] | 殷元骐;蒋耀忠.不对称催化反应进展[M].北京:科学出版社,2000:76. |
| [12] | Yasuda H .Asymmetric catalyst by [Rh(BCPM)Cl]2[J].Progress in Polymer Science,2000,25:573. |
| [13] | Saki N;Mano S;Takaya H .(R,S)-BINAphos-Rh catalysis[J].Journal of the American Chemical Society,1993,115:7033. |
| [14] | Bergens S H;Noheda P;Whelan J;Bosnich B .Rhodium-catalyst in asymmetric synthesis of pantolatone[J].Journal of the American Chemical Society,1992,114:2121. |
| [15] | Alper H;Crudder C;Khumtaveeporn K.Turnover number in asymmetric catalysis[J].Journal of the Chemical Society,Chemical Communications,1995:1199. |
| [16] | 李月明;范青华;陈新滋.不对称催化反应-催化剂的回收与再利用[M].北京:化学工业出版社,2003:39. |
| [17] | Candeias NR;Gois PMP;Afonso CAM .Rh(II) catalysed intramolecular C-H insertion of diazo substrates in water: a simple and efficient approach to catalyst reuse[J].Chemical communications,2005(3):391-393. |
| [18] | 韩英锋,杨定乔,徐峰,董建霞.铑催化不对称氢化反应的研究进展[J].化工时刊,2004(11):1-7. |
| [19] | Joel M.Hawkins;Timothy J.N.Watson .Asymmetric Catalysis in the Pharmaceutical Industry[J].Angewandte Chemie,2004(25):3224-3228. |
| [20] | Jerphagon T;Renaud J;Bruneau C .Chrial monodentate phosphorus ligands for rhodium-catalyzed asymmetric hydrogenation[J].Tetrahedron:Asymmetry,2004,15:2101. |
| [21] | Dieguez M;Pamies O;Claver C .Recent advances in Rh-catalyzed asymmetric hydroformylation using phosphite ligands[J].Tetrahedron, Asymmetry: The International Journal for Repid Publication on all Aspects of Asymmetry in Orgainc, Inorganic, Organometallic, Physical and Bio-Organic Chemistry,2004(14):2113-2122. |
| [22] | Chen B;Dingerdissen U;Krauter JGE;Rotgerink HGJL;Mobus K;Ostgard DJ;Panster P;Riermeier TH;Seebald S;Tacke T .New developments in hydrogenation catalysis particularly in synthesis of fine and intermediate chemicals[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2005(1):17-46. |
| [23] | Hans-Ulrich Blaser;Benoit Pugin;Felix Spindler .Progress in enantioselective catalysis assessed from an industrial point of view[J].Journal of Molecular Catalysis(China),2005,231(01) |
| [24] | 熊晓东,王胜国.铂族金属在不对称催化中的应用[J].稀有金属,2005(03):363-367. |
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