通过丝网印刷的方法在市场可获得的YSZ/NiO-YSZ半电池上印刷LSM-YSZ浆料,烧结后构成Ni-YSZ阳极支撑的SOFC试验电池.通过溶液渗透的方法,研究了La(NO3)3和La(NO3)3-Mn(NO3)2复合渗透电池性能的影响.以水分含量3%的纯氢气为燃料,未渗透电池800 ℃的峰值功率为0.202 W·cm-2,La(NO3)3溶液渗透后电池800 ℃的峰值功率为0.428 W·cm-2;在渗透La(NO3)3后的电池上再用Mn(NO3)2复合渗透,电池800 ℃的峰值功率为0.92 W·cm-2,电池在800 ℃保持38 h,峰值功率可以保持在0.46 W·cm-2.
参考文献
[1] | Nomura Hiroshi;Parekh Sandeep;Robert Selman J et al.Fabrication of YSZ electrolyte for intermediate temperature solid oxide fuel cell using electrostatic spray deposition:I-a comprehensive parametric study[J].Journal of Applied Electrochemistry,2005,35:61. |
[2] | Nomura Hiroshi;Parekh Sandeep;Robert Selman J et al.Fabrication of YSZ electrolyte for intermediate temperature solid oxide fuel cell using electrostatic spray deposition:II-Cell performance[J].Journal of AppliedElectrochemistry,2005,35:1121. |
[3] | Negishi H.;Yamaji K.;Sakai N.;Horita T.;Yanagishita H.;Yokokawa H. .Electrophoretic deposition of YSZ powders for solid oxide fuel cells[J].Journal of Materials Science,2004(3):833-838. |
[4] | Jung Hwa Young;Hong Kug-Sun;Kim Hyoungchul et al.Characterization of thin-film YSZ deposited via EP-PVD technique in anode-supported OSFCs[J].Journal of the Electrochemical Society,2006,153(05):A961. |
[5] | Laukaitis G;Dudonis J;Milcius D .YSZ thin films deposited by e-beam technique[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(2):678-682. |
[6] | Kenji Kikuchi;Takuji Okaya;Wataru Hirose .Fabrication of YSZ Thin Films by Chemical Vapor Infiltration Using NiO as Oxygen Source[J].Journal of the Electrochemical Society,2003(10):C688-C692. |
[7] | Steele Brain C H;Heinzel Angelika .Materials for fuel-cell technologies[J].Nature,2001,414(15):345. |
[8] | Zhang Xinge;Ohara Satoshi;Maric Radenka et al.Ni-SDC cermet anode for medium-temperature solid oxide fuel cell with lanthanum gallate electrolyte[J].Journal of Power Sources,1999,83:170. |
[9] | Wang Fengyun;Wan Benzu;Cheng Soofin .Study on Gd3+ andSm3+ co-doped ceriabased electrolytes[J].J Solid State Electrochemistry,2005,9:168. |
[10] | Ai Na;Lu Zhe;Cheo Kongfa et al.Low temperature solid oxide fuel cells based on Sm0.2Ce0.8O1.9 films fabricated by slurry spin coating[J].Journal of Power Sources,2006,159:637. |
[11] | Dusastre V.;Kilner J.A. .Optimisation of composite cathodes for intermediate temperature SOFC applications[J].Solid state ionics,1999(1/2):163-174. |
[12] | Hwang Hae Jin;Moon Ji-Woong;Lee Seunghun et al.Electrochemical performance of LSCF-based composite cathodes for intermediate temperature SOFCs[J].Journal of Power Sources,2005,145:243. |
[13] | Shao Zongping;Haile Sossina M .A high-performance cathode for the next generation of solid-oxiee fuel cells[J].NATURE,2004,434:170. |
[14] | Liu Q L;Khor K A;Chan S H .High-performance low-temperature solidoxide fuel cell with novel BSCF cathode[J].Journal of Power Sources,2006,161:123. |
[15] | 尹艳红,李少玉,朱威,夏长荣,孟广耀.钙掺杂的氧化铈用于中温SOFCs阳极材料研究[J].中国稀土学报,2005(03):317-320. |
[16] | 黄端平,徐庆,陈文,张枫,汪碧涛.La0.6Sr0.4Co1-yFeyO3(y=0.2,0.8)复合氧化物混合导电性能研究[J].中国稀土学报,2006(04):503-506. |
[17] | Yamahara K;Jacobson CP;Visco SJ;Zhang XF;de Jonghe LC .Thin film SOFCs with cobalt-infiltrated cathodes[J].Solid state ionics,2005(3/4):275-279. |
[18] | Lu C;Sholklapper TZ;Jacobson CP;Visco SJ;De Jonghe LC .LSM-YSZ cathodes with reaction-infiltrated nanoparticles[J].Journal of the Electrochemical Society,2006(6):A1115-A1119. |
[19] | Virkar Anil V;Chen Jong;Tanner Cameron W et al.The role of electrode microstructure on activation and concentration polarizations in solid oxidefuelc ells[J].Solid State Ionicis,2000,131:189. |
[20] | Jiang SP.;Love JG. .Origin of the initial polarization behavior of Sr-doped LaMnO3 for O-2 reduction in solid oxide fuel cells[J].Solid state ionics,2001(3/4):183-190. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%