欢迎登录材料期刊网

材料期刊网

高级检索

通过在镍氢电池Ni(OH)2正极中复合添加稀土氧化物Lu2O3和Er2O3,研究了稀土氧化物的复合添加对Ni(OH)2正极高温性能的影响.充放电循环实验表明复合添加不同含量的Lu2O3和Er2O3都能够不同程度地提高正极高温充电效率.在55,60,65 ℃下,添加2.5%Lu2O3+1.5%Er2O3的正极充电效率最高.循环伏安测试表明,复合添加2.5%Lu2O3+1.5%Er2O3能够较为明显的提高Ni(OH)2正极在高温环境下的析氧副反应电位,进而提高了电极在高温环境下的充电效率.

参考文献

[1] 倪佩;陈延禧 .添加剂及其对正极的作用机理[J].电池,1997,27(01):35.
[2] Furukawa K;Tanaki T;Nakagowa H et al.Hydrogen absorbing electrode,nickel electrode and alkaline storage battery[P].US 6136473,2000-10-24.
[3] Masahiko Oshitani;Masaharu Watada;Kaori Shodai;Mitsuhiro Kodama .Effect of Lanthanide Oxide Additives on the High-Temperature Charge Acceptance Characteristics of Pasted Nickel Electrodes[J].Journal of the Electrochemical Society,2001(1):A67-A73.
[4] Oshitani M;Sasaki Y;Takashima K .Development of a nickel electrode having stable performance at various charge and diacharge rates over a wide temperature range[J].Journal of Power Sources,1984,12(3-4):219.
[5] 米欣,叶茂,阎杰,魏进平,高学平.外掺Y2O3对镍氢电池正极高温性能的影响[J].中国稀土学报,2004(01):119-124.
[6] 米欣,姜长印,阎杰,高学平,万春荣.球型Ni(OH)2表面包覆Y(OH)3及其高温充放电性能[J].无机化学学报,2004(02):164-168.
[7] Bernard P;Gabrielli C;Keddam M et al.Ac quartz crystal microbalance applied to the studies of the nickel hydroxide behavior in alkaline solutions[J].Electrochimica Acta,1991,36(3-4):743.
[8] Bernard P;Gabrielli C;Keddam M et al.Ac quartz crystal microbalance applied to the studies of the nickel hydroxide behavior in alkaline solutions[J].Electrochimica Acta,1991,36(3-4):743.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%