自行合成枯丁苯氧基碘代酞菁铟反饱和吸收化合物,将其添加到聚甲基丙烯酸甲酯(PMMA)基质中,分别采用浇铸聚合、注射成型、提拉成膜3种成型方法制备出酞菁铟/PMMA反饱和吸收材料.测试了3种不同成型方法材料的紫外-可见光谱与反饱和吸收特性,通过测试发现在酞菁铟掺杂比例相同的条件下,注射成型及提拉成膜材料样品的起始阈值、箝位值、动态范围大大高于浇铸成型材料样品,注射成型材料样品的反饱和吸收性能与提拉成膜材料比较基本相当,但是材料的稳定性、力学性能比薄膜材料有很大提高,更接近于实用化.
参考文献
| [1] | Fan F R;Faulkner L R .Photovoltaic effects of metalfree and zinc phthalocyanines I.Dark electrical properties of rectifying cells[J].Journal of Chemical Physics,1978,69:3334. |
| [2] | Pakhomov L G;Zakamov V R;Pakhomov G L .Electrical measurements on two-layer phthalocyanine films[J].Journal of Materials Science,2005,40(02):3279. |
| [3] | Boguslavskii EG;Prokhorova SA;Nadolinnyi VA .Evolution of ordered films of copper phthalocyanine according to EPR data[J].Journal of structural chemistry,2005(6):1014-1022. |
| [4] | Varghese AC;Menon CS .Conduction in magnesium phthalocyanine thin films with aluminium electrodes[J].The European physical journal, B. Condensed matter physics,2006(4):465-468. |
| [5] | Perry J W;Mansour K;Marder S R .Enhanced reverse saturable absorption and optical limiting in heavy-atom-substituted phthalocyanines[J].Optics Letters,1994,19(09):625. |
| [6] | Mansour K;Alvarez D .Dynamics of optical limiting in heavy-atom substituted pphthalocyanines[J].Spie,1993,1853:1321. |
| [7] | Belousov V P;Belousova I M;Gavronskaya E A .Broardband optical limiters based on fullerene-containing media with a fast nonlinear response in the visible region[J].Journal of Optical Technology,1999,66(08):713. |
| [8] | 刘大军,段潜,王舫,王立杰.烷氧基酞菁铅类反饱和吸收化合物的制备及性质研究[J].中国激光,2005(07):969-972. |
| [9] | LIU Dajun,ZHOU Fenguo,LV Xiaoxing,WANG Lijie.Preparation & Properties Research of Two Indium Phthalocyanine Materials[J].武汉理工大学学报（材料科学版）英,2005(04):132-134. |
| [10] | 刘大军,周奋国,段潜,吕小星,王立杰.酞菁类反饱和吸收材料的制备及性能测试[J].兵工学报,2005(05):712-715. |
| [11] | Milgrom L R.The Colors of Life:an Introduction to the Chemistry of Porphyrins and Related Compounds[M].New York:oxford University Press,1997:191. |
| [12] | 杨小兵,丁松涛,王安邦,李小银,杨裕生.一种铟酞菁染料的吸收光谱及其光褪色现象研究[J].中国激光,2003(03):271-274. |
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