制备复合合金是改善贮氢合金性能的一条有效途径.本文对国内外各种多元以及多相稀土复合贮氢材料的研究现状进行了综合评述,主要涉及了AB5-AB2型复合贮氢合金和镁基-AB5型纳米复合贮氢合金的进展.阐述了各种复合材料的组成,微观结构以及电化学性能等,并展望了今后复合贮氢材料的研究方向为应用基础性的研究,如复合作用机制、对热力学性能的影响等方面的研究.
参考文献
[1] | 王仲民,彭成红,欧阳柳章,李祖鑫,朱敏.纳米化对Mg2Ni/MmNi5-x(CoAlMn)x复合储氢合金电极特性的影响[J].金属学报,2002(02):189-192. |
[2] | Seo Chan Yeo;Choi Seueg Jun;Choic J;Park Choong-Nyeon Lee Paul S Lee Jai-Young .Effect of Ti and Zr addition the characteristics of AB5-type hydride electrode for Ni/MH secondary battery[J].International Journal of Hydrogen Energy,2003,28(03):317. |
[3] | Seo Chan Yeo;Choi Seueg Jun;Choic J;Park Choong-Nyeon Lee Jai-Young .Effect of V and Zr on the electrochemical properties of La-based AB5-type metal hydride electrodes[J].Journal of Alloys and Compounds,2003,351(1-2):255. |
[4] | 韩树民,赵敏寿,吴耀明,郑炀曾.利用球磨制备AB2-AB5复合贮氢合金及其电极性能和微观结构研究[J].无机化学学报,2003(03):262-266. |
[5] | Han Shumin;Zhang Zhong;Zhao Shoumin;Zheng Yangzeng .Electrochemical characteristics and microstructure of Zr0.9Ti0 9Ni0 1Mn0 6V0 3-LaNi5 composite hydrogen storage alloys[J].International Journal of Hydrogen Energy,2006,31(05):563. |
[6] | Han Shumin;Zhao Minshou;Zhang Zhong;Zheng Yangzeng Jing Tanfu .Effect of AB2 alloy addition on the phase structures and electrochemical characteristics of LaNi5 hydride electrode[J].Journal of Alloys and Compounds,2005,392(1-2):268. |
[7] | 韩树民,赵敏寿,张忠,郑炀曾,荆天辅.熔炼法制备的AB5-AB2复合合金的晶体结构和电化学性能[J].稀有金属,2004(05):867-870. |
[8] | Lei Y Q;Wu Y M;Yang Q M;Wu J Wang Q D .Electrochemical behaviour of some mechanically alloyed MgNi-based amorphous hydrogen storage alloys[J].Zeitschrift Fur Physikalische Chemie Bd,1994,183:379. |
[9] | Raman S S Sai;Srivastava O N .Hydrogenation behaviour of the new composite storage materials Mg-x(wt%)CFMmNi5[J].Journal of Alloys and Compounds,1996,241(1-2):167. |
[10] | Terzieva M.;Peshev P.;Khrussanova M. .Hydriding and dehydriding characteristics of Mg-LaNi5 composite materials prepared by mechanical alloying[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):235-239. |
[11] | Liang G.;Huot J.;Van Neste A.;Schulz R.;Boily S. .Hydrogen absorption properties of a mechanically milled Mg-50wt%LaNi5 composite[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):302-307. |
[12] | Liang G.;Huot J. .Hydrogen storage in mechanically milled Mg-LaNi_5 and MgH_2-LaNi_5 composites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2000(1/2):261-265. |
[13] | 蒙冕武,刘心宇,成钧,周怀营.LaNi5-Mg合金的机械合金化合成与表征[J].稀有金属材料与工程,2004(12):1333-1336. |
[14] | Zhu M;Gao Y;Che X Z;Yang Y Q Chung C Y.Hydriding kinetics of nano-phase composite hydrogen storage alloys prepared by mechanical alloying of Mg and MmNi5-xCoAlMn)x[J].Journal of Alloys and Compounds,2002(330-332):708. |
[15] | 朱文辉;朱敏;罗堪昌;车晚舟 李祖鑫 .高能球磨在MmNi5-x(Co,Al,Mn)x/Mg体系中诱发的固态反应及纳米相复合储氢合金的形成[J].金属学报,1999,35(05):541. |
[16] | Zhu M;Zhu W H;Chung C Y;Che Z X Li Z X.Microstructure and hydrogen absorption properties of nano-phase composite prepared by mechanical of MmNi5-xCoAlMn)x and Mg[J].Journal of Alloys and Compounds,1999(293-295):531. |
[17] | Groos K J;Spatz P;Züttel A;Louis Schlapbach .Mechanically milled Mg composite for hydrogen storage the transition to a steady state composition[J].Journal of Alloys and Compounds,1996,240(1-2):206. |
[18] | Gross KJ.;Leroy E.;Zuttel A.;Schlapbach L.;Chartouni D. .Mechanically milled Mg composites for hydrogen storage: The relationship between morphology and kinetics[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):259-270. |
[19] | Pal K. .SYNTHESIS CHARACTERIZATION AND HYDROGEN ABSORPTION STUDIES OF THE COMPOSITE MATERIALS LA2MG17-XWT-PERCENT-LANI5[J].Journal of Materials Science,1997(19):5177-5184. |
[20] | Zhu M;Wang Z M;Peng C H;Zeng M Q Gao Y .The effect of grain refining on the discharge capacity of Mg2Ni/MmNi5-x(CoAlMn)x composite prepared by mechanical alloying[J].Journal of Alloys and Compounds,2003,349(1-2):284. |
[21] | Cui N;Luo J L .Effects of oxide additions on electrochemical hydriding and dehydring behavior of MgH2-type hydrogen storage alloy electrode in 6M KOH solution[J].Electrochimica Acta,1998,44(05):711. |
[22] | Reule H;Hirscher M;Weiβhardt A;Kronmüller H .Hydrogen desorption properties of mechanically alloyed MgH2 composite materials[J].Journal of Alloys and Compounds,2000,305(1-2):246. |
[23] | Yu XB.;Li F.;Wu Z.;Xia BJ.;Xu NX. .Enhanced electrochemical properties of ball-milled Ti-30V-15Mn-15Cr+20 wt% La(NiMnCoAl)(5) alloy electrodes[J].Physics Letters, A,2004(4):312-317. |
[24] | 赵强,薛建伟,杜志刚,李晋平.LaNi5+TiFe0.9Mn0.1合金的贮氢性能[J].太原理工大学学报,2005(05):606-608. |
[25] | Wang F X;Gao X P;Lu Z W;Ye S H Qu J Q Wu F Yuan H T Song D Y .Eelectrochemical properties of Mg-based alloys containing carbon nanotubes[J].Journal of Alloys and Compounds,2004,370(1-2):326. |
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