介绍了熔盐电解固态氧化物制备金属(FFC法)的基本原理,并综述了利用FFC法制备难熔金属及合金的最新进展,分析了FFC法的优点及目前存在的主要问题,指出如果FFC法的电解速度和电流效率得以提高,电解固态氧化物直接制备金属及合金将具有很好的工业化前景.
参考文献
[1] | 胡忠武,李中奎,张清,张廷杰,张军良,殷涛.难熔金属及其合金单晶的发展[J].稀有金属材料与工程,2007(02):367-371. |
[2] | 阳喜元,袁晓俭,胡望宇.难熔金属热学性能的研究现状[J].稀有金属材料与工程,2005(09):1349-1351. |
[3] | 胡忠武.难熔金属合金的加工技术及其新应用[J].稀有金属快报,2003(03):23-24. |
[4] | 尹中荣,马元,郑杰,王秦,李泉旺,李凤玲,张希先.应用于稀有及难熔金属的真空高温炉研制[J].稀有金属,2003(01):72-76. |
[5] | 刘建民,鲁雄刚,李谦,陈朝轶,程红伟,吕小旸,周国治.熔盐电解制备难熔金属的现状与展望[J].稀有金属快报,2006(09):1-6. |
[6] | Kroll W J .The preduction of ductile titanium[J].Transactions of the Electrochemical Society,1940,78:35. |
[7] | Fray D J;Farthing T W;Chem G Z .Removal of oxygen from metal oxides and solid solutions by electrolysis in a fused salt[P].WO 199964638,1999-12-16. |
[8] | Derek J. Fray .Emerging molten salt technologies for metals production[J].JOM,2001(10):26-31. |
[9] | D. J. Fray;G. Z. Chen .Reduction of titanium and other metal oxides using electrodeoxidation[J].Materials Science and Technology: MST: A publication of the Institute of Metals,2004(3):295-300. |
[10] | Michael Freemantle .Titanium Extracted Directly From TiO_2[J].Chemical and engineering news: "news edition" of the American Chemical Society,2000(39):12-13. |
[11] | Chen G Z;Fray D J;Farthing T W .Cathodic deoxygenatinn of the alpha case on titanium and alloys in molten calcium chloride[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,2001,32B:1041. |
[12] | George Z. Chen;Derek J. Fray .Voltammetric Studies of the Oxygen-Titanium Binary System in Molten Calcium Chloride[J].Journal of the Electrochemical Society,2002(11):E455-E467. |
[13] | Chen G Z;Fray D J;Farthing T W .Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride[J].NATURE,2000,407:361. |
[14] | K.S. Mohandas;D.J. Fray .FFC CAMBRIDGE PROCESS AND REMOVAL OF OXYGEN FROM METAL-OXYGEN SYSTEMS BY MOLTEN SALT ELECTROLYSIS: AN OVERVIEW[J].Transactions of the Indian Institute of Metals,2004(6):579-592. |
[15] | 汪的华,陈政.熔盐电化学创新研究--武汉大学电化学研究中心熔盐电化学研究工作简介[J].电化学,2005(02):119-124. |
[16] | Suzuki R O;Teranuma K;Ono K .Calciothermic reduction of titanium oxide and in-situ electrolysis in molten CaCl2[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,2003,34B:287. |
[17] | Suzuki RO;Inoue H .Calciothermic reduction of titanium oxide In molten CaCl2[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,2003,34B:277. |
[18] | Ono K;Suzuki R O .A new concept for producing Ti sponge:calciothennic reduction[J].Journal of the Minerals,Metals & Materials Society,2002,54(02):59. |
[19] | Ryosuke O. Suzuki .Direct Reduction Processes for Titanium Oxide in Molten Salt[J].JOM,2007(1):68-71. |
[20] | Ratchev I;Bliznyukov S;Olivares R;Watts R O.Mechanism of elactrolytic reduction of titanium dioxide in solid state in molten calcium chloride-bsoed salts[A].Warrendale,PA:The Minerals Metals & Materials Society,2004:209. |
[21] | Liu M F;Guo Z C;Lu W C .An investigation into electrochemical reduction of TiO2 pellet[J].Transactions of the Institution of Mining and Metallurgy Section C,2005,114:C87. |
[22] | Schwendt C;Fray D J .Determination of the kinetic pathway in the electrochemical reduction of titanium dioxide in molten calcium chloride[J].Electrochimica Acta,2005,51:66. |
[23] | 胡小锋,许茜,李海滨,马青梅,任东琦.熔盐电脱氧法制备金属Ti的最新研究进展[J].材料导报,2006(08):101-103,106. |
[24] | 吴全兴.钛冶炼新工艺的最新动向[J].稀有金属快报,2006(05):43-45. |
[25] | [OL].http://www.bhpbilliton,com/bbContentRepository/Presentations/BHPBillitonPresentationITAScottsdaleSept05.pdf |
[26] | [OL].http://www.metalysis,com/downloads/Metalysis-Company-Profile2006.pdf |
[27] | [OL].http://www.metalysis,com/news,htm |
[28] | Jackson M.Titanium-21 century[J].Materials World,2007(05):32. |
[29] | Chen G Z;Gordo E;Fray D J .Direct electrolytic preparation of chromium powder[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,2004,35:223. |
[30] | Gordo E;Chen G Z;Fray D J .Toward optimization of electrolytic reduction of solid chromium oxide to chromium powder in molten chloride salts[J].Electrochimica Acta,2004,49:2195. |
[31] | Yan X Y;Fray D J .Ehctrochemical studies on reduction of solid Nb2O5 in molten CaCl2-NaCJ entectc[J].Journal of the Electrochemical Society,2005,152(01):D12. |
[32] | Yan X Y;Fray D J .Using electro-deoxidation to synthesize niobium sponge from solid Nb2O5 in alkali-alkaline-earth metal chloride melts[J].Journal of Materials Research,2003,18:346. |
[33] | 胡小锋,许茜.CaCl2-NaCl熔盐电脱氧法制备金属Ta[J].金属学报,2006(03):285-289. |
[34] | Wang D H;Qiu G H;Jin X B;Hu X H,Chen G Z .Electrochemical metaliization d solid terbium oxide[J].Angewandte Chemie,2006,118:2444. |
[35] | Ma M;Wang D H;Weng W G;Hu X H,JIn X B,Chen G Z .Extraction of titanium from different titania precursors by the FFC Cambridge process[J].Journal of Alloys and Compounds,2006,420:37. |
[36] | Jin X B;Gao P;Wang D H;Hu X H,Chen G Z .Electrochemical preparation of silicon and its alloys from solid oxides in molten calcium chloride[J].Angewandte Chemie International Edition,2004,43:733. |
[37] | Xian W;Jin X B;Deng Y;Wang D H,Hu X H,Chen G Z .Electrochemically driven three-phase interlines into insulator com-pounds:dectroreducton of solid SiO2 in molten CaCl2[J].ChemPhysChem:A European Journal of Chemical Physics and Physical Chemistry,2006,7(08):1750. |
[38] | Xian W;Jin X B;Deng Y;Wang D H,Chen G Z .Threephase interlines electrochemically driven into insulator compounds:a penetration modal and its verification by electroreduction of solid AgCl[J].Chemistry-A European Journal,2007,13:604. |
[39] | Jieng K;Hu X H;Ms M;Wang D H,Qiu G H,Jin X B,Chen G Z .Perovskitization-assistod elactrochemical reduction of Solid TiO2 in molten CaCl2[J].Angewandte Chemie International Edition,2006,45:428. |
[40] | 邱国红,汪的华,金先波,胡晓宏,陈政.Cr2O3粉末在CaCl2熔盐中直接电化学还原的金属通腔电极研究[J].电化学,2006(03):304-309. |
[41] | 朱用,马猛,汪的华,蒋凯,胡晓宏,金先波,陈政.熔盐电还原固态混合氧化物低能耗制备TiNi合金[J].科学通报,2006(16):1966-1970. |
[42] | 刘美凤,卢世刚,阚素荣,李国勋.熔盐电解直接制备钛镍合金的研究[J].稀有金属,2007(04):573-576. |
[43] | LIU Meifeng,LU Shigang,KAN Surong,LI Guoxun.Effect of electrolysis voltage on electrochemical reduction of titanium oxide to titanium in molten calcium chloride[J].稀有金属(英文版),2007(06):547-551. |
[44] | 刘美凤,郭占成.金属钛制备方法的新进展[J].中国有色金属学报,2003(05):1238-1245. |
[45] | 刘美凤,郭占成,卢维昌.TiO2直接电解还原过程的研究[J].中国有色金属学报,2004(10):1752-1758. |
[46] | 王志;袁章福;郭占成 .熔盐电解法直接制备钛合金新工艺探讨[J].有色金属,2003,55(04):32. |
[47] | 王志,袁章福,郭占成.金属钛生产工艺研究进展[J].过程工程学报,2004(01):90-96. |
[48] | 邓丽琴,许茜,李兵,翟玉春,黄振奇.电脱氧法由Nb2O5直接制备金属铌[J].中国有色金属学报,2005(04):541-545. |
[49] | Xu Q;Deng L Q;Wu Y;Ma T .A study of cathode improvemerit for electro-deoxiddation of Nb2O5 in n eutectc CaCl2-NaCl melt at 1073 K[J].Journal of Alloys and Compounds,2005,396(01):288. |
[50] | 邓丽琴,许茜,马涛,李兵,翟玉春.电脱氧法制铌用Nb2O5阴极活性的改进[J].金属学报,2005(05):551-555. |
[51] | 杜继红,奚正平,李晴宇,李争显,唐勇.掺杂的TiO2阴极对熔盐电解的影响[J].稀有金属,2007(03):336-340. |
[52] | 杜继红,奚正平,李晴宇,李争显,唐勇.电化学还原TiO2制备金属钛及反应过程的研究[J].稀有金属材料与工程,2006(07):1045-1049. |
[53] | 郭胜惠,彭金辉,张世敏,范兴祥,张利波.熔盐电解法生产海绵钛的回顾和新技术开发[J].轻金属,2002(11):51-53. |
[54] | 郭胜惠,彭金辉,张利波,范兴祥,张世敏,杨显万.海绵钛生产过程的能耗分析及新技术的提出[J].云南冶金,2002(03):114-117. |
[55] | 彭金辉,范兴祥,郭胜惠,张利波,张世敏.二氧化钛直接电解提取钛短流程绿色新技术[J].稀有金属,2002(04):290-293. |
[56] | NIE Xin-miao,DONG Ling-yan,BAI Chen-guang,CHEN Deng-fu,QIU Gui-bao.Preparation of Ti by direct electrochemical reduction of solid TiO2 and its reaction mechanism[J].中国有色金属学会会刊(英文版),2006(z1):723-727. |
[57] | Glowacki BA.;Fray DJ.;Yan XY.;Chen G. .Superconducting Nb3Sn intermetallics made by electrochemical reduction of Nb2O5-SnO2 oxides[J].Physica, C. Superconductivity and its applications,2003(1/2):242-246. |
[58] | Glowacki BA.;Yan XY.;Fray D.;Chen G.;Majoros M.;Shi Y. .Niobium based intermetallics as a source of high-current/high magnetic field superconductors[J].Physica, C. Superconductivity and its applications,2002(Pt.3):1315-1320. |
[59] | A. Jamie Mulr Wood;Robert C. Copcutt;George Z. Chen;Derek J. Fray .Electrochemical Fabrication of Nickel Manganese Gallium Alloy Powder[J].Advanced Engineering Materials,2003(9):650-653. |
[60] | Qiu GH;Wang DH;Ma M;Jin XB;Chen GZ .Electrolytic synthesis of TbFe2 from Tb4O7 and Fe2O3 powders in molten CaCl2[J].Journal of Electroanalytical Chemistry: An International Journal Devoted to All Aspects of Electrode Kinetics, Interfacial Structure, Properties of Electrolytes, Colloid and Biological Electrochemistry,2006(1):139-147. |
[61] | Qiu G H;Wang D H;Jin X B;Chen G Z .A direct electrochemical route from oxide precursors to the terbium-nickel intermetallic compound TbNi5[J].Electrochimica Acta,2006,51:5785. |
[62] | Dring K;Bhagat R;Jackson M;Dashwond R,Inman D .Direct electrochemical production of Ti-10W alloys from mixed oxide preform precursors[J].Journal of Alloys and Compounds,2006,419:103. |
[63] | Ma M;Wang DH;Hu XH;Jin XB;Chen GZ .A direct electrochemical route from ilmenite to hydrogen-storage ferrotitanium alloys[J].Chemistry: A European journal,2006(19):5075-5081. |
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